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4-Bromophenylacetonitrile

CAS No.
16532-79-9
Chemical Name:
4-Bromophenylacetonitrile
Synonyms
2-(4-BROMOPHENYL)ACETONITRILE;4-BROMOBENZYL CYANIDE;PARA BROMO PHENYL ACETONITRILE;PBPAN;NSC 84174;p-Bromobenzyl;4-bromocyanide;ThebenzylbroMide;P-bromoacetonitrile;4-BroMobenzylnitrile
CBNumber:
CB1185818
Molecular Formula:
C8H6BrN
Molecular Weight:
196.04
MDL Number:
MFCD00001916
MOL File:
16532-79-9.mol
MSDS File:
SDS
Last updated:2026-05-27 23:14:12
Product description Number Pack Size Price
4-Bromophenylacetonitrile 98% 124664 25g $36.6
4-Bromophenylacetonitrile 98% 124664 100g $95.3
4-Bromobenzyl Cyanide TRC-B680210-25G 25g $193
4-Bromobenzyl Cyanide TRC-B680210-250G 250g $1518
4-Bromophenylacetonitrile 98% OR017366 1g $21
More product size

4-Bromophenylacetonitrile Properties

Melting point 47-49 °C (lit.)
Boiling point 116-118°C 3mm
Density 1.49
refractive index 1.6550 (estimate)
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Sparingly), Ethyl Acetate (Sparingly)
form Crystalline Mass
color Colorless to pale brown
Water Solubility slightly soluble
BRN 1861069
Exposure limits NIOSH: IDLH 25 mg/m3
InChI 1S/C8H6BrN/c9-8-3-1-7(2-4-8)5-6-10/h1-4H,5H2
InChIKey MFHFWRBXPQDZSA-UHFFFAOYSA-N
SMILES Brc1ccc(CC#N)cc1
CAS DataBase Reference 16532-79-9(CAS DataBase Reference)
EWG's Food Scores 1
NIST Chemistry Reference Benzeneacetonitrile, 4-bromo-(16532-79-9)
EPA Substance Registry System 4-Bromobenzyl cyanide (16532-79-9)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Skull and Crossbones (GHS06)
GHS06
Signal word  Danger
Hazard statements  H301-H312+H332-H315-H319-H335-H311-H331
Precautionary statements  P261-P280-P301+P310-P305+P351+P338-P280h-P309-P310-P361
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38-20/21/22/36/37/39
Safety Statements  26-36/37/39-38-26/36/37/39
RIDADR  3276
WGK Germany  3
RTECS  AL8090000
Hazard Note  Irritant
TSCA  TSCA listed
HazardClass  6.1
PackingGroup  III
HS Code  29269090
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
REACH Registrations Active
Limited Quantities 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
1
3 0

4-Bromophenylacetonitrile price More Price(55)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 124664 4-Bromophenylacetonitrile 98% 16532-79-9 25g $36.6 2023-06-20 Buy
Sigma-Aldrich 124664 4-Bromophenylacetonitrile 98% 16532-79-9 100g $95.3 2023-01-07 Buy
TRC TRC-B680210-25G 4-Bromobenzyl Cyanide 16532-79-9 25g $193 2026-06-03 Buy
TRC TRC-B680210-250G 4-Bromobenzyl Cyanide 16532-79-9 250g $1518 2026-06-03 Buy
Apolloscientific OR017366 4-Bromophenylacetonitrile 98% 16532-79-9 1g $21 2026-06-04 Buy
Product number Packaging Price Buy
124664 25g $36.6 Buy
124664 100g $95.3 Buy
TRC-B680210-25G 25g $193 Buy
TRC-B680210-250G 250g $1518 Buy
OR017366 1g $21 Buy

4-Bromophenylacetonitrile Chemical Properties,Uses,Production

Chemical Properties

colorless to pale brown crystalline mass

Uses

4-Bromophenylacetonitrile is a chemical model used for the study and analysis of human buccal absorption of pharmaceuticals.

Uses

4-Bromophenylacetonitrile has been used in the synthesis of :

  • new fluorene-based alternating polymers
  • light-emitting copolymer, poly(N 4,N 4-bis-(4-phenyl)-N 4,N 4′-bis-[4-(2-ethylhexyloxy)phenyl]-biphenyl-4,4′-diamine-co-1,2-bis(4′-phenyl)-1-(9′′,9′′-dihexyl-3-fluorenyl)ethane) using a Yamamoto coupling reaction
  • N-methyl-3,4-bis(4-(N-(1-naphthyl)phenylamino)phenyl)maleimide, a novel non-doped red organic light-emitting diode (OLED) material

General Description

4-Bromophenylacetonitrile undergoes reduction using 1,1,3,3-tetramethyldisiloxane activated by a non-toxic titanium(IV) isopropoxide to yield 4-bromophenylethylamine.

Safety Profile

Poison by intravenous route. See also BROMIDES and NITRILES. When heated to decomposition it emits very toxic fumes of Br-, NOx, and CN-.

74860-13-2
16532-79-9
Synthesis of 4-Bromophenylacetonitrile from 2-(4-bromophenyl)acetamide
Global( 418)Suppliers
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Hebei Chuanghai Biotechnology Co., Ltd
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Hebei Chuanghai Biotechnology Co,.LTD
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Jinan Finer Chemical Co., Ltd
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View Lastest Price from 4-Bromophenylacetonitrile manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Bromophenylacetonitrile pictures 2026-05-28 4-Bromophenylacetonitrile
16532-79-9
$2.00-5.00 1KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
4-Bromophenylacetonitrile pictures 2026-03-20 4-Bromophenylacetonitrile
16532-79-9
1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
4-Bromophenylacetonitrile pictures 2025-04-04 4-Bromophenylacetonitrile
16532-79-9
1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
(P-BROMOPHENYL)ACETONITRILE P-BROMOBENZYL CYANIDE 4-BROMOPHENYLACETONITRILE (p-bromophenyl)-acetonitril 1-BroMo-4-cyanoMethylbenzene 4-(CyanoMethyl)broMobenzene 4-BroMobenzylnitrile NSC 84174 ThebenzylbroMide The broMobenzene acetonitrile 4-Bromobenzyl cyanide, (4-Bromophenyl)acetonitrile Benzeneacetonitrile,4-bromo- 4-bromo-benzeneacetonitril 4-Bromobenzeneacetonitrile Acetonitrile, (p-bromophenyl)- p-Bromophenylacetonile 4-Bromophenylacetonitrile, 97+% p-Bromobenzyl 4-BROMOPHENYLACETONITRILE / 4-BROMOBENZYL CYANIDE 4-BROMOPHENYLACETONITRILE 99% 4-Bromophenylacetonitrile,99% 4-bromocyanide 4-Bromophenylacetonitrile ,98% 4-Bromophenylacetoni 4-BroMophenylacetonitrile, 99% 25GR 4-4-Bromophenylacetonitrile 4-Bromobenzyl Cyanide > PBPAN P-bromoacetonitrile 4-Bromophenylacetonitrile(Chunks or pellets) PARA BROMO PHENYL ACETONITRILE 4-Bromo Benzyl Cyanide99% 4-bromophenyllacetonirile 4-Bromophenylacetonitrile, 95% 4-Bromophenylacetonitrile - [B1779] Evocalcet impurity 55 2-(4-BROMOPHENYL)ACETONITRILE 4-BROMOBENZYL CYANIDE 16532-79-9 16532-79-7 BrC6H4CH2CN ARYL HALIDE Building Blocks C8 to C9 Organic Building Blocks Nitrogen Compounds Cyanides/Nitriles Phenyls & Phenyl-Het Nitrile Phenyls & Phenyl-Het Aromatic Nitriles blocks Bromides Carboxes Aromatics Miscellaneous Reagents