ChemicalBook >> CAS DataBase List >>5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID

5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID

CAS No.
10242-10-1
Chemical Name:
5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID
Synonyms
RT 63;ASISCHEM D19360;BUTTPARK 40\07-65;5-Chlorocoumarilic acid;ASINEX-REAG BAS 12719327;5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID;5-Chloro-2-benzofurancarboxylic acid;2-Benzofurancarboxylic acid, 5-chloro-;5-Chlorobenzo[b]furan-2-carboxylic acid;5-Chlorobenzofuran-2-carboxylic Acid >
CBNumber:
CB1264793
Molecular Formula:
C9H5ClO3
Molecular Weight:
196.59
MDL Number:
MFCD00060512
MOL File:
10242-10-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 23:21:23
Product description Number Pack Size Price
5-Chlorobenzofuran-2-carboxylic Acid >98.0%(GC)(T) C2890 1g $72
5-Chlorobenzofuran-2-carboxylic Acid >98.0%(GC)(T) C2890 5g $287
5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID 97% 50626 1G $27
5-Chlorobenzo[b]furan-2-carboxylic acid ≥95% OR102841 1g $21
5-Chlorobenzo[b]furan-2-carboxylic acid ≥95% OR102841 5g $102
More product size

5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID Properties

Melting point 275°C (subl.)
Boiling point 348.8±22.0 °C(Predicted)
Density 1.502
storage temp. 2-8°C
pka 2.94±0.30(Predicted)
form powder to crystal
color White to Light yellow
λmax 301nm(EtOH)(lit.)
CAS DataBase Reference 10242-10-1(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39
HazardClass  IRRITANT
HS Code  29321900
NFPA 704
0
2 0

5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID price More Price(50)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical C2890 5-Chlorobenzofuran-2-carboxylic Acid >98.0%(GC)(T) 10242-10-1 1g $72 2026-04-30 Buy
TCI Chemical C2890 5-Chlorobenzofuran-2-carboxylic Acid >98.0%(GC)(T) 10242-10-1 5g $287 2024-03-01 Buy
AstaTech 50626 5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID 97% 10242-10-1 1G $27 2026-04-30 Buy
Apolloscientific OR102841 5-Chlorobenzo[b]furan-2-carboxylic acid ≥95% 10242-10-1 1g $21 2026-06-04 Buy
Apolloscientific OR102841 5-Chlorobenzo[b]furan-2-carboxylic acid ≥95% 10242-10-1 5g $102 2026-06-04 Buy
Product number Packaging Price Buy
C2890 1g $72 Buy
C2890 5g $287 Buy
50626 1G $27 Buy
OR102841 1g $21 Buy
OR102841 5g $102 Buy

5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID Chemical Properties,Uses,Production

Chemical Properties

Light red powder

Synthesis

DIETHYL BROMOMALONATE

685-87-0

5-Chlorosalicylaldehyde

635-93-8

5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID

10242-10-1

General procedure for the synthesis of 5-chlorobenzofuran-2-carboxylic acid from diethyl bromomalonate and 5-chlorosalicylaldehyde: 5-chlorosalicylaldehyde (10.62 g, 67.8 mmol), diethyl bromomalonate (25.3 g, 105.8 mmol), and anhydrous potassium carbonate (9.37 g, 67.8 mmol) were suspended in ethylmethyl ketone (50 mL), and the reaction was carried out at reflux. The reaction was carried out for 5 h, followed by stirring at room temperature overnight. Upon completion of the reaction, the solvent was removed by evaporation and the residue was diluted with water (500 mL) and neutralized with 1N HCl solution. The resulting suspension was extracted with ether (Et2O) and the organic phase was dried over anhydrous magnesium sulfate (MgSO4) and concentrated. The oily residue was dissolved in anhydrous ethanol (50 mL) and 10% ethanol solution of potassium hydroxide (KOH) was added. The thick suspension formed was refluxed overnight under vigorous stirring. After cooling to room temperature, the solvent was removed by evaporation and water was added. The aqueous phase was washed with ether (Et2O) and the pH was subsequently adjusted to 2 with 1 N HCl. The aqueous suspension was extracted with ethyl acetate (EtOAc), and the organic phase was dried over anhydrous magnesium sulfate (MgSO4) and concentrated to give pure 5-chlorobenzofuran-2-carboxylic acid (7.4 g, 37.6 mmol, 55.5% yield) as a yellow oil.

References

[1] Patent: US6025390, 2000, A
[2] Gazzetta Chimica Italiana, 1955, vol. 85, p. 381,388
[3] Patent: US4332952, 1982, A
[4] Patent: US4342771, 1982, A

5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID Preparation Products And Raw materials

Global( 129)Suppliers
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View Lastest Price from 5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID pictures 2021-08-12 5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID
10242-10-1
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID pictures 2019-07-06 5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID
10242-10-1
$1.00 1kg 98% 200KG Career Henan Chemical Co

5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID Spectrum

ASISCHEM D19360 ASINEX-REAG BAS 12719327 BUTTPARK 40\07-65 5-CHLOROBENZOFURAN-2-CARBOXYLIC ACID 5-Chlorobenzo[b]furan-2-carboxylic acid 5-Chlorobenzofuran-2-carboxylic acid ,97% 5-Chloro-2-benzofurancarboxylic acid 5-Chlorocoumarilic acid RT 63 5-Chloro-1-benzofuran-2-carboxylic acid, 2-Carboxy-5-chlorobenzo[b]furan 5-Chlorobenzofuran-2-carboxylic Acid > 2-Benzofurancarboxylic acid, 5-chloro- 5-Chlorobenzofuran-2-Carboxylic Acid Hydrochloride 10242-10-1