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(R)-DIFLUORPHOS(TM)

(R)-DIFLUORPHOS(TM) structure

CAS No.: 503538-70-3

Chemical Name:: (R)-DIFLUORPHOS(TM)

Synonyms: (S)-DIFLUORPHOS;(S)-DIFLUORPHOS(TM);(S)-(2,2,2',2'-tetrafluoro-[4,4'-bibenzo[d][1,3]dioxole]-5,5'-diyl)bis(diphenylphosphane);(R)-DIFLUORPHOS(TM);(S)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole;S-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE;R-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE;S-(+)-5,5''-Bis(diphenylphosphino)-2,2,2'',2''-tetrafluoro-4,4''-bi-1,3-benzodioxole;(S)-(2,2,2’,2’-Tetrafluoro-[4,4’-bibenzo[d][1,3]dioxole]-5,5’-diyl)bis(diphenylphosphine);Phosphine,[(4S)-2,2,2'',2''-tetrafluoro[4,4''-bi-1,3-benzodioxole]-5,5''-diyl]bis[diphenyl-

CBNumber:: CB1355145

Molecular Formula:: C38H24F4O4P2

Molecular Weight:: 682.54

MDL Number:: MFCD05861607

MOL File:: 503538-70-3.mol

MSDS File:: SDS

Last updated:2025-07-29 21:08:05

Product description	Number	Pack Size	Price
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, min. 98%, (99% ee), (S)-DIFLUORPHOS min.98%(99%ee)	15-0487	100mg	$146
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, min. 98%, (99% ee), (S)-DIFLUORPHOS min.98%(99%ee)	15-0487	500mg	$579
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97% (S)-DIFLUORPHOS(TM)	15-0487	100mg	$121
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97% (S)-DIFLUORPHOS(TM)	15-0487	500mg	$482
(S)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole 97%	AA00DD3K	50mg	$51

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(R)-DIFLUORPHOS(TM) Properties

Boiling point	670.9±55.0 °C(Predicted)
storage temp.	2-8°C, protect from light, stored under nitrogen
form	Powder
color	white
Sensitive	air sensitive
InChIKey	HGMLTMOEYCQDDR-UHFFFAOYSA-N
SMILES	O1C2=CC=C(P(C3=CC=CC=C3)C3=CC=CC=C3)C(C3=C4C(=CC=C3P(C3=CC=CC=C3)C3=CC=CC=C3)OC(F)(F)O4)=C2OC1(F)F
CAS DataBase Reference	503538-70-3

SAFETY

Risk and Safety Statements

Risk Statements	36/37/38
Safety Statements	26-36/37/39

(R)-DIFLUORPHOS(TM) price More Price(16)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Strem Chemicals	15-0487	S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, min. 98%, (99% ee), (S)-DIFLUORPHOS min.98%(99%ee)	503538-70-3	100mg	$146	2026-04-30	Buy
Strem Chemicals	15-0487	S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, min. 98%, (99% ee), (S)-DIFLUORPHOS min.98%(99%ee)	503538-70-3	500mg	$579	2026-04-30	Buy
Strem Chemicals	15-0487	S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97% (S)-DIFLUORPHOS(TM)	503538-70-3	100mg	$121	2024-03-01	Buy
Strem Chemicals	15-0487	S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97% (S)-DIFLUORPHOS(TM)	503538-70-3	500mg	$482	2024-03-01	Buy
aablocks	AA00DD3K	(S)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole 97%	503538-70-3	50mg	$51	2026-05-28	Buy

Product number	Packaging	Price	Buy
15-0487	100mg	$146	Buy
15-0487	500mg	$579	Buy
15-0487	100mg	$121	Buy
15-0487	500mg	$482	Buy
AA00DD3K	50mg	$51	Buy

(R)-DIFLUORPHOS(TM) Chemical Properties,Uses,Production

Reaction

Ligand used for the enantioselective hydrogenation of olefins, and especially electron-poor ketones.
Ligand used for the enantioselective α-arylation of ketones.
Ligand used for enantioselective alkylative aldol reactions.
Nickel-catalyzed asymmetric α-heteroarylation of ketones with chloroarenes.
Palladium-catalyzed asymmetric intramolecular arylation of α-keto amides.

Uses

(S)-DIFLUORPHOS is an electron-poor diphosphane, and can also be used as a chiral supporting ligand.Also, used in preparation of chiral Amino Acid Esters and deuterated Amino Acid Esters.

(R)-DIFLUORPHOS(TM) Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-DIFLUORPHOS(TM) Suppliers

Global( 62)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	462	58
Shenzhen Nexcon Pharmatechs Ltd.	+86-0755-89396905 +86-18025329037	admin@nexconn.com	China	5615	58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	+86-15225627621 +86-13213167925	jiuyitime@fdachem.com	China	16512	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569266 +86-17392581500	1015@dideu.com	China	3861	58
Jinan Honest Pharm Co., Ltd	+8615318812076	zpy8217@163.com	China	286	58
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	laboratory@coreychem.com	China	30224	58
Henan Research New Materials Co., Ltd.	+86-18903931628 +86-18903931531	sales036@researchvip.com	China	302	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49734	58
Protheragen-ING	+16313385890	info@protheragen-ing.com	United States	3868	58
Shanghai Acmec Biochemical Technology Co., Ltd.	+86-18621343501; +undefined18621343501	product@acmec-e.com	China	33324	58

Supplier	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	58
Shenzhen Nexcon Pharmatechs Ltd.	58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	58
Shaanxi Dideu Medichem Co. Ltd	58
Jinan Honest Pharm Co., Ltd	58
Career Henan Chemica Co	58
Henan Research New Materials Co., Ltd.	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	58
Protheragen-ING	58
Shanghai Acmec Biochemical Technology Co., Ltd.	58

Unveiling (R)-DIFLUORPHOS(TM): A Catalyst for Change in Organophosphorus Chemistry
(R)-DIFLUORPHOS(TM) This specialized ligand is gaining traction in academic and industrial settings due to its unique properti....
May 6，2024

(R)-DIFLUORPHOS(TM): Chemical synthesis and application
The (R)-DIFLUORPHOS(TM) is a kind of phosphorus ligand, and is often used as a catalyst for asymmetric catalytic hydrogenation....
Mar 29，2023

View Lastest Price from (R)-DIFLUORPHOS(TM) manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-07-09	(R)-DIFLUORPHOS(TM) 503538-70-3		1KG	99%	2000	Shenzhen Nexcon Pharmatechs Ltd.
2026-07-02	(R)-DIFLUORPHOS(TM) 503538-70-3	$2.00-5.00		99%		ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
2025-12-23	(S)-DIFLUORPHOS(TM) 503538-70-3		1KG	0.98	500kg	XINXIANG RUNYU MATERIAL CO., LTD.

(R)-DIFLUORPHOS(TM)
503538-70-3
99%
Shenzhen Nexcon Pharmatechs Ltd.

(R)-DIFLUORPHOS(TM)
503538-70-3
$2.00-5.00
99%
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

(S)-DIFLUORPHOS(TM)
503538-70-3
0.98
XINXIANG RUNYU MATERIAL CO., LTD.

(R)-DIFLUORPHOS(TM) Spectrum

(R)-DIFLUORPHOS(TM)(503538-70-3)¹HNMR

503538-70-3((R)-DIFLUORPHOS(TM))Related Search:

(R)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole (R)-DTBM-SEGPHOS (S)-H8-BINAP (R)-DM-BINAP (S)-SunPhos

(S)-(+)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(+)-TolBINAP (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-SEGPHOS (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS (R)-H8-BINAP

(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Dichloromethane

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S-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE (R)-DIFLUORPHOS(TM) R-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE Phosphine,[(4S)-2,2,2'',2''-tetrafluoro[4,4''-bi-1,3-benzodioxole]-5,5''-diyl]bis[diphenyl- S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole,dichloromethaneadduct,min.97%(S)-DIFLUORPHOS S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloroMethane adduct (S)-DIFLUORPHOS S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97% (S)-DIFLUORPHOS(TM) S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97% 1,1'-[(4S)-2,2,2',2'-Tetrafluoro[4,4'-bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-diphenylphosphine] S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, min. 98%, (99% ee), (S)-DIFLUORPHOS Phosphine, 1,1'-[(4S)-2,2,2',2'-tetrafluoro[4,4'-bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-diphenyl- (+)-[4-(5-diphenylphosphanyl-2,2-difluoro-1,3-benzodioxol-4-yl)-2,2-difluoro-1,3-benzodioxol-5-yl]-diphenyl-phosphane (S)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole[(S)-DIFLUORPHOS] (S)-[4-(5-diphenylphosphanyl-2,2-difluoro-1,3-benzodioxol-4-yl)-2,2-difluoro-1,3-benzodioxol-5-yl]-diphenyl-phosphane S-(+)-5,5''-Bis(diphenylphosphino)-2,2,2'',2''-tetrafluoro-4,4''-bi-1,3-benzodioxole (S)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole (S)-(2,2,2’,2’-Tetrafluoro-[4,4’-bibenzo[d][1,3]dioxole]-5,5’-diyl)bis(diphenylphosphine) S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole [(S)-Difluorphos 1,1'-[(4S)-2,2,2',2'-Tetrafluoro[4,4'-bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-diphenylphosphine (S)-(2,2,2',2'-tetrafluoro-[4,4'-bibenzo[d][1,3]dioxole]-5,5'-diyl)bis(diphenylphosphane) (S)-DIFLUORPHOS(TM) (S)-DIFLUORPHOS 503538-70-3 C38H24F4O4P2稾CH2Cl2