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ChemicalBook >> CAS DataBase List >>(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Structure
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny structure
CAS No.
352655-61-9
Chemical Name:
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
Synonyms
(R)-3,5-t-Bu-4-MeO-MeOBIPHEP;SL-A109-1;-diyl)bis[bis(3，5-di-tert-butyl-4-methoxyphenyl)phosphine;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine;(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine];(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine];(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(R)-2,2'-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl) phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CBNumber:
CB6972437
Molecular Formula:
C74H104O6P2
Molecular Weight:
1151.56
MDL Number:
MFCD09265029
MOL File:
352655-61-9.mol
MSDS File:
SDS
Last updated:2026-05-28 02:06:38
Product description Number Pack Size Price
(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 15-0042 100mg $74
(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 15-0042 500mg $278
(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% AA003C3P 50mg $53
(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% AA003C3P 100mg $98
(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% AA003C3P 250mg $215
Request For Quotation

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Properties

Boiling point 951.5±65.0 °C(Predicted)
storage temp. 2-8°C, protect from light, stored under nitrogen
form crystal
color white
optical activity -6.6287°(C=0.8946g/100ml CHCL3)
InChIKey JSSIQFXOSWLAGA-UHFFFAOYSA-N
UNSPSC Code 12352112
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
PPE Eyeshields, Gloves, type N95 (US)
WGK Germany  3
HS Code  29319090
Storage Class 13 - Non Combustible Solids

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-0042 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 352655-61-9 100mg $74 2021-12-16 Buy
Strem Chemicals 15-0042 (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% 352655-61-9 500mg $278 2021-12-16 Buy
aablocks AA003C3P (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 352655-61-9 50mg $53 2026-05-28 Buy
aablocks AA003C3P (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 352655-61-9 100mg $98 2026-05-28 Buy
aablocks AA003C3P (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98% 352655-61-9 250mg $215 2026-05-28 Buy
Product number Packaging Price Buy
15-0042 100mg $74 Buy
15-0042 500mg $278 Buy
AA003C3P 50mg $53 Buy
AA003C3P 100mg $98 Buy
AA003C3P 250mg $215 Buy

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Chemical Properties,Uses,Production

Reaction

  1. Rh-catalyzed reductive coupling of acetylene to aldehydes and ketones.
  2. Pt-catalyzed intramolecular hydroarylation of unactivated alkenes with indoles.
  3. Enantioselective C-C bond activation of allenyl cyclobutanes.
  4. Enantioselective ring-opening of rac-ethynyl epoxides.
  5. Enantioselective Au-catalyzed allylic alkylation of indoles with alcohols.
  6. Enantioselective Rh-catalyzed conjugate alkynylation with TMS-acetylene.
  7. Enantioselective Rh-catalyzed [3+2] annulation of aromatic ketimines.
  8. Asymmetric Rh-catalyzed Pausan-Khand reaction. 
Reactions of 352655-61-9_1
Reactions of 352655-61-9_2
Reactions of 352655-61-9_3

Chemical Properties

Off-white powder

Uses

Atropisomeric MeOBIPHEP ligands

  • Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes
  • Intramolecular ketone hydroacylation
  • Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
  • Hydroamination of bicyclic alkenes and dienes with anilines
  • 1,4-addition/asymmetric protonation of amino acrylates

General Description

sold in collaboration with Solvias AG

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Suppliers

Global( 36)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 14026 58
Aladdin Scientific 		tp@aladdinsci.com United States 57505 58
Soochow Chirally Material Science and Technology Co.,Ltd 		+86-51266834346 +86-17751128648 sales@krl-tech.com China 1050 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44878 61
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51395 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18737115891;18625597674 info@kingorgchem.com;sales@kingorgchem.com China 812 55
Shanghai YuanYe Biotechnology Co., Ltd. 13636370518 shyysw007@163.com China 89686 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2280 58
Aikon International Limited 025-58859352 15955137747 sales01@aikonchem.com China 16027 58
Supplier Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		58
Aladdin Scientific 		58
Soochow Chirally Material Science and Technology Co.,Ltd 		58
J & K SCIENTIFIC LTD. 76
Energy Chemical 61
Sigma-Aldrich 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
Shanghai YuanYe Biotechnology Co., Ltd. 60
LaaJoo 58
Aikon International Limited 58

352655-61-9((R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny)Related Search:

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(R)-(+)-TolBINAP R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-SEGPHOS
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1of4

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% (R)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97% (S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine] (S)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-2, (S)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine} (R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine] (R)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-1, (R)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine} (R)-(-)-2,2'-Bis[di-(3,5-di-tert-butyl-4-methoxy-phenyl)phosphino]-(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl (R)-3,5-t-Bu-4-MeO-MeOBIPHEP SL-A109-1 (R)-(-)-2,2'-Bis[di-(3,5-di-t-butyl-4-methoxy- phenyl)phosphino]-(diphenylphosphino)-6,6'- dimethoxy-1,1'-biphenyl (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl (R)-(6,6'-DiMethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-Methoxyphenyl)phosphine] >=97%, optical purity ee: >=99% Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]- (R)-2,2'-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl) phosphino]-6,6'-dimethoxy-1,1'-biphenyl -diyl)bis[bis(3，5-di-tert-butyl-4-methoxyphenyl)phosphine (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine (R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine] (R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine], CAS 352655-61-9 352655-61-9 C74H104O6P2 Chiral Phosphine MeOBIPHEP Series