TETRAHYDROFURAN-2-ACETIC ACID ETHYL ESTER
- CAS No.
- 2434-02-8
- Chemical Name:
- TETRAHYDROFURAN-2-ACETIC ACID ETHYL ESTER
- Synonyms
- ethyl 2-(oxolan-2-yl)acetate;ETHYL TETRAHYDROFURAN-2-ACETATE;Tetrahydrofuranaceticacidethylester;Ethyl 2-(tetrahydrofuran-2-yl)acetate;TETRAHYDROFURAN-2-ACETIC ACID ETHYL ESTER
- CBNumber:
- CB1483073
- Molecular Formula:
- C8H14O3
- Molecular Weight:
- 158.2
- MDL Number:
- MFCD00059735
- MOL File:
- 2434-02-8.mol
| Product description | Number | Pack Size | Price |
| Ethyl Tetrahydrofuran-2-acetate >98.0%(GC) | T0957 | 5mL | $210 |
| Ethyl Tetrahydrofuran-2-acetate >98.0%(GC) | T0957 | 25mL | $736 |
| Tetrahydro-2-furanaceticAcidEthylEster | T293535 | 10g | $1320 |
| Tetrahydro-2-furanaceticAcidEthylEster | 67194 | 10g | $2200 |
| Tetrahydrofuran-2-aceticacidethylester 95% | 2H23-1-0X | 1g | $200 |
| More product size | |||
| Boiling point | 98 °C / 13mmHg |
|---|---|
| Density | 1.03 |
| refractive index | 1.4350-1.4390 |
| storage temp. | 2-8°C |
| form | clear liquid |
| color | Colorless to Almost colorless |
| CAS DataBase Reference | 2434-02-8 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H227 |
| Precautionary statements | P210-P280-P370+P378-P403+P235-P501 |
| HS Code | 2932190090 |
TETRAHYDROFURAN-2-ACETIC ACID ETHYL ESTER price More Price(17)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | T0957 | Ethyl Tetrahydrofuran-2-acetate >98.0%(GC) | 2434-02-8 | 5mL | $210 | 2025-07-31 | Buy |
| TCI Chemical | T0957 | Ethyl Tetrahydrofuran-2-acetate >98.0%(GC) | 2434-02-8 | 25mL | $736 | 2025-07-31 | Buy |
| TRC | T293535 | Tetrahydro-2-furanaceticAcidEthylEster | 2434-02-8 | 10g | $1320 | 2021-12-16 | Buy |
| Medical Isotopes, Inc. | 67194 | Tetrahydro-2-furanaceticAcidEthylEster | 2434-02-8 | 10g | $2200 | 2021-12-16 | Buy |
| SynQuest Laboratories | 2H23-1-0X | Tetrahydrofuran-2-aceticacidethylester 95% | 2434-02-8 | 1g | $200 | 2021-12-16 | Buy |
TETRAHYDROFURAN-2-ACETIC ACID ETHYL ESTER Chemical Properties,Uses,Production
Uses
Tetrahydro-2-furanacetic Acid Ethyl Ester is used in organic reactions for the opening of cyclic ethers using dimethylboron bromide.
Synthesis
109-99-9
623-73-4
2434-02-8
General procedure for the synthesis of ethyl tetrahydrofuran-2-acetate from tetrahydrofuran and ethyl diazoacetate: first, methyl phenyl diacetate was prepared by the reaction of methyl phenylacetate with p-acetamidobenzenesulfonyl azide. The dried non-homogeneous catalyst (containing 0.02 mmol Cu) was suspended in anhydrous tetrahydrofuran (10 mL containing 100 mg of n-decane as internal standard) and heated to reflux under inert atmosphere. Anhydrous tetrahydrofuran (10 mL) solution of diazo compounds (1 mmol) was slowly added over a period of 2 hours using a syringe pump. After the addition was completed, the reaction mixture was continued to be stirred under reflux conditions for 30 min. Subsequently, the catalyst was removed by filtration and washed with tetrahydrofuran (5 mL). Yield and stereoselectivity were determined by gas chromatography (GC). After addition of diazo compounds and heating at reflux for 2 h, the presence of active copper substances in solution was detected by analytical tests. After drying the catalyst under vacuum, it can be reused under the same conditions. Enantioselectivity was determined by high performance liquid chromatography (HPLC) when the reaction was carried out in the presence of chiral ligands.
References
[1] Journal of the American Chemical Society, 2002, vol. 124, # 6, p. 896 - 897
[2] Inorganic Chemistry, 2015, vol. 54, # 23, p. 11043 - 11045
[3] Dalton Transactions, 2009, # 2, p. 375 - 382
[4] Journal of Catalysis, 2011, vol. 281, # 2, p. 273 - 278
[5] Chemical Science, 2015, vol. 6, # 2, p. 1510 - 1515
TETRAHYDROFURAN-2-ACETIC ACID ETHYL ESTER Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 52923 | 58 | |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532; 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24529 | 81 |
| ShangHai DEMO Chemical Co.,Ltd | 400-021-7337 2355568890 | sales@demochem.com | China | 2572 | 57 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44801 | 61 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18207 | 66 | |
| Beijing Ouhe Technology Co., Ltd | 010-82967028 13522913783 | 2355560935@qq.com | China | 11777 | 60 |
| Shanghai Longsheng chemical Co.,Ltd. | 021-58099652-8005 13585536065 | bin.wu@shlschem.com | China | 9892 | 59 |
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