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4,4'-Dichlorobenzophenone

4,4'-Dichlorobenzophenone Structure
4,4'-Dichlorobenzophenone structure
CAS No.
90-98-2
Chemical Name:
4,4'-Dichlorobenzophenone
Synonyms
4'-DBP;usafdo-4;4,4'-DBP;4,4'-DCBP;USAF do-4;AKOS 94189;4,4'-DichL;DCBP Standard;4.4'-Dichlorob;4,4'-Dichlorobenzoph
CBNumber:
CB2120403
Molecular Formula:
C13H8Cl2O
Molecular Weight:
251.11
MDL Number:
MFCD00000623
MOL File:
90-98-2.mol
MSDS File:
SDS
Last updated:2025-09-05 20:24:49
Product description Number Pack Size Price
4,4′-Dichlorobenzophenone 99% 113700 25g $50.63
4,4'-Dichlorobenzophenone >99.0%(GC) D1621 25g $47
4,4'-Dichlorobenzophenone >99.0%(GC) D1621 100g $140
4,4'-Dichlorobenzophenone >99.0%(GC) D1621 500g $561
4,4''-Dichlorobenzophenone D431980 100g $160
More product size
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4,4'-Dichlorobenzophenone Properties

Melting point 144-146 °C (lit.)
Boiling point 353 °C (lit.)
Density 1,45 g/cm3
refractive index 1.5555 (estimate)
Flash point 352-354°C
storage temp. Sealed in dry,Room Temperature
solubility Soluble in hot acetone.
form powder to crystal
color White to Light yellow
BRN 643345
Stability Stable. Incompatible with strong oxidizing agents.
InChI InChI=1S/C13H8Cl2O/c14-11-5-1-9(2-6-11)13(16)10-3-7-12(15)8-4-10/h1-8H
InChIKey OKISUZLXOYGIFP-UHFFFAOYSA-N
SMILES C(C1=CC=C(Cl)C=C1)(C1=CC=C(Cl)C=C1)=O
CAS DataBase Reference 90-98-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 3MTL0YC2Q5
NIST Chemistry Reference p-Dichlorobenzophenone(90-98-2)
EPA Substance Registry System Methanone, bis(4-chlorophenyl)- (90-98-2)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-36-26
WGK Germany  3
RTECS  DJ0525000
Hazard Note  Irritant
TSCA  Yes
HS Code  29147000
NFPA 704
1
2 0

4,4'-Dichlorobenzophenone price More Price(35)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 113700 4,4′-Dichlorobenzophenone 99% 90-98-2 25g $50.63 2025-07-31 Buy
TCI Chemical D1621 4,4'-Dichlorobenzophenone >99.0%(GC) 90-98-2 25g $47 2025-07-31 Buy
TCI Chemical D1621 4,4'-Dichlorobenzophenone >99.0%(GC) 90-98-2 100g $140 2025-07-31 Buy
TCI Chemical D1621 4,4'-Dichlorobenzophenone >99.0%(GC) 90-98-2 500g $561 2025-07-31 Buy
TRC D431980 4,4''-Dichlorobenzophenone 90-98-2 100g $160 2021-12-16 Buy
Product number Packaging Price Buy
113700 25g $50.63 Buy
D1621 25g $47 Buy
D1621 100g $140 Buy
D1621 500g $561 Buy
D431980 100g $160 Buy

4,4'-Dichlorobenzophenone Chemical Properties,Uses,Production

Chemical Properties

faintly yellow crystalline powder

Uses

4,4'-Dichlorobenzophenone is used as pharmaceutical intermediates. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and dyestuffs. Bisaminonitrile was polymerized with 4,4'-dichlorobenzophenone using NaH as base.

Application

4,4'-Dichlorobenzophenone can be used to synthesize polyether-polyketones, as well as reduce polymer costs. Furthermore, it is a metabolic product resulting from the degredation of DDT.

Preparation

4,4'-Dichlorobenzophenone is prepared by the acylation of chlorobenzene with 4-chlorobenzoyl chloride. The conversion is typically conducted in the presence of an aluminium chloride catalyst in a petroleum ether solvent.
ClC6H5C(O)Cl + C6H5Cl → (ClC6H4)2CO + HCl

Definition

ChEBI: 4-4-Dichlorobenzophenone is a member of benzophenones.

Synthesis Reference(s)

The Journal of Organic Chemistry, 54, p. 1201, 1989 DOI: 10.1021/jo00266a039
Tetrahedron Letters, 36, p. 8411, 1995 DOI: 10.1016/0040-4039(95)01802-O

General Description

4,4′-Dichlorobenzophenone (DBP) is a metabolite obtained when one strain of ectomycorrhizal fungi, Xerocomus chrysenteron, degrades 1,1,1-trichloro-2,2-bis(4-chlorophe-nyl) ethane (DDT).

Purification Methods

Recrystallise it from EtOH [Wagner et al. J Am Chem Soc 108 7727 1986]. The semicarbazone has m 192-193o (from H2O). [Beilstein 7 H 420, 7 I 228, 7 II 359, 7 III 2076, 7 IV 1376.]

References

[1] C. VENKATESAN. Liquid Phase Selective Benzoylation of Chlorobenzene to 4,4′-Dichlorobenzophenone over Zeolite H-Beta[J]. Catalysis Letters, 2001, 75 1-2: 119-123. DOI:10.1023/A:1016771719956.
[2] K. YONEYAMA F. M. Reductive metabolism of heptachlor, parathion, 4,4′-dichlorobenzophenone, and carbophenothion by rat liver systems[J]. Pesticide Biochemistry and Physiology, 1981, 15 3: Pages 213-221. DOI:10.1016/0048-3575(81)90003-1.
[3] YI HUANG Jie W. Degradation and mineralization of DDT by the ectomycorrhizal fungi, Xerocomus chrysenteron[J]. Chemosphere, 2013, 92 7: Pages 760-764. DOI:10.1016/j.chemosphere.2013.04.002.
[4] HONGXIN ZHOU. Synthesis and characterization of phthalazinone‐based poly(aryl ether ketone) derived from 4,4′‐dichlorobenzophenone[J]. Polymers for Advanced Technologies, 2012, 23 1: 742-747. DOI:10.1002/PAT.1950.

4,4'-Dichlorobenzophenone synthesis

90-97-1
90-98-2
Synthesis of 4,4'-Dichlorobenzophenone from 4,4'-Dichlorobenzhydrol

4,4'-Dichlorobenzophenone Preparation Products And Raw materials

Raw materials

4-Chlorobenzoyl chloride

Preparation Products

4,4'-DDMU 4,4'-DDM 4,4'-DICHLORO-ALPHA-METHYLBENZHYDROL 4,4'-Dichlorobenzhydrol Benzophenone
sodium hydrogen -2-ethoxy-5-[[4-[[4-[(4-ethoxy-3-sulphonatophenyl)amino]phenyl]-(1H-indol-3-yl-1-methyl-2-phenyl)methylene]-2,5-cyclohexadien-1-ylidene]amino]benzenesulphonate sodium hydrogen -2-hydroxy-5-[[4-[[4-[(4-hydroxy-3-sulphonatophenyl)amino]phenyl](1-methyl-2-phenyl-1H-indol-3-yl)methylene]-2,5-cyclohexadien-1-ylidene]amino]benzenesulphonate

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4,4'-Dichlorobenzophenone Suppliers

Global( 489)Suppliers
Supplier Tel Email Country ProdList Advantage
SINO HIGH(CHINA)CO.,LTD.
+86-2558392388 +86-13914336446 chang@sinohighchem.com China 34 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615350571055 Sibel@chuanghaibio.com China 8772 58
Sichuan Zhuoyu Yantang Technology Co., Ltd. 		+8613288715578 sales@sichuanzyyt.com China 12245 58
Hebei Chuanghai Biotechnology Co,.LTD 		+86-13131129325 sales1@chuanghaibio.com China 5251 58
Hebei Dangtong Import and export Co LTD 		+86-86-4001020630 +8619831957301 admin@hbdangtong.com China 998 58
airuikechemical co., ltd. 		+86-18353166132 sales02@airuikechemical.com China 983 58
Hebei Zhuanglai Chemical Trading Co Ltd 		+86-16264648883 niki@zlchemi.com China 7245 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718; +8613336195806 sales@capot.com China 29735 60
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21618 55
Shanghai Time Chemicals CO., Ltd. 		+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1803 55
Supplier Advantage
SINO HIGH(CHINA)CO.,LTD.
58
Hebei Chuanghai Biotechnology Co., Ltd 		58
Sichuan Zhuoyu Yantang Technology Co., Ltd. 		58
Hebei Chuanghai Biotechnology Co,.LTD 		58
Hebei Dangtong Import and export Co LTD 		58
airuikechemical co., ltd. 		58
Hebei Zhuanglai Chemical Trading Co Ltd 		58
Capot Chemical Co.,Ltd. 		60
Henan Tianfu Chemical Co.,Ltd. 		55
Shanghai Time Chemicals CO., Ltd. 		55

View Lastest Price from 4,4'-Dichlorobenzophenone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4,4'-Dichlorobenzophenone pictures 2025-11-01 4,4'-Dichlorobenzophenone
90-98-2
 0.99 RongNa Biotechnology Co.,Ltd
4,4'-Dichlorobenzophenone pictures 2025-10-21 4,4'-Dichlorobenzophenone
90-98-2
 US $0.00-0.00 / KG 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
4,4'-Dichlorobenzophenone pictures 2025-09-26 4,4'-Dichlorobenzophenone
90-98-2
 US $5.00-1.00 / kg 1kg 99% 300tons Hebei Dangtong Import and export Co LTD

4,4'-Dichlorobenzophenone Spectrum

4,4'-Dichlorobenzophenone(90-98-2)MS4,4'-Dichlorobenzophenone(90-98-2)1HNMR4,4'-Dichlorobenzophenone(90-98-2)13CNMR4,4'-Dichlorobenzophenone(90-98-2)IR14,4'-Dichlorobenzophenone(90-98-2)IR24,4'-Dichlorobenzophenone(90-98-2)Raman

90-98-2(4,4'-Dichlorobenzophenone)Related Search:

Benzophenone imine 4-Chlorobenzophenone 3,4-Dihydroxybenzophenone 4,4'-Dihydroxybenzophenone 2,4-Dihydroxybenzophenone
2,4-Difluorobenzophenone Bis(4-fluorophenyl)-methanone Benzophenone oxime Benzophenone (3,4-Diaminophenyl)phenylmethanone
2,2',4,4'-Tetrahydroxybenzophenone 4,4'-Dimethylbenzophenone 4'-Methylacetophenone 4'-Chloropropiophenone 4,4'-DICHLORO-3,3'-DINITROBENZOPHENONE
2-Amino-2',5-dichlorobenzophenone 2-Chloro-N-[4-chloro-2-(2-chlorobenzoyl)phenyl]acetamide 2,5-Dichlorobenzophenone

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Benzophenone, 4,4'-dichloro- benzophenone,4,4’-dichloro- p-p#-Dichlorbenzophenon USAF do-4 usafdo-4 BIS(4-CHLOROPHENYL) KETONE BIS-(4-CHLORO-PHENYL)-METHANONE 4,4'-DBP 4,4'-DCBP p-dichlorobenzophenone 4,4’-bis(p-Chlorophenyl)ketone 4,4’-dichloro-benzophenon 4,4’-dichlorodiphenylketone 4,4'-DICHLOROBENZOPHENONE, 100MG, NEAT 4,4'-DBP, PESTANAL (4,4'-DICHLORO- BENZO 4,4-Dichlorobenzophenone99% AKOS 94189 4,4μ-DBP, 4,4μ-Dichlorobenzophenone (4,4-dichloro-1-cyclohexa-1,5-dienyl)-phenylmethanone 4,4'-Dichlorobenzophenone 4.4'-Dichlorob 4.4'-Dichlorobenzophenone 100mg [90-98-2] 4,4′-Dichlorobenzophenone,4,4′-DBP 4,4'-Dichlorobenzoph 4'-DBP 4,4'-Dichlorobenzophenone 10 μg/mL in Cyclohexane bis(4-chlorophenyl)-methanon bis(p-chlorophenyl)ketone dbp(degradationproduct) di(4-chlorophenyl)ketone Di(p-Chlorophenyl)ketone Methanone, bis(4-chlorophenyl)- methanone,bis(4-chlorophenyl)- p,p’-dichlorobenzophenone p,p'-Dichlorobenzophenone p,p-Dichlorobenzophenone 4,4'-Dichlorbenzophenon DCBP Standard 4,4'-Dichlorobenzophenone @100 μg/mL in MeOH 4,4'-Dichlorobenzophenone @1000 μg/mL in MeOH 4,4'-Dichlorobenzophenone > 4,4'-DichL 4,4’-Dichlorobenzophenone Solution in Methanol, 100μg/mL 4,4'-Dicholorobenzophenone 2,6-Dichloro-8-fluoropyridin 4,4'-Dichlorobenzophenone in methanol 4,4'-Dichlorobenzophenone 100 μg/ml Acetone 4,4'-Dichlorobenzophenone 100 μg/ml Acetonitrile 4,4'-Dichlorobenzophenone 100 μg/ml Ethyl acetate C12410000 4,4`-Dichlorobenzophenone L12410000CY 4,4`-DichlorobenzophenonE10μg/mL Cetirizine Impurity 89 4,4'-Dichlorobenzophenone, 98% 4,4′-DBP, CAS 90-98-2 4,4`-dichlorobenzophenone, 99%min 90-98-2 C13Cl2H8O1 C19H15AlCl2O