ChemicalBook >> CAS DataBase List >>Methyl tetrahydropyran-4-carboxylate
Methyl tetrahydropyran-4-carboxylate
- CAS No.
- 110238-91-0
- Chemical Name:
- Methyl tetrahydropyran-4-carboxylate
- Synonyms
- THPE;METHYL TETRAHYDRO-2H-PYRAN-4-CARBOXYLATE;Methyl oxane-4-carboxylate;CAS:110238-91-0;2H-Pyran-4-carboxylic aci;Methyl tetrahydropyran-4-...;4-(Methoxycarbonyl)tetrahydropyran;METHYL TETRAHYDROPYRAN-4-CARBOXYLATE;Methyl tetrahydro-2H-pyran-4- carboxyl;Methyltetrahydro-2H-pyran-4-carboxylat
- CBNumber:
- CB2217413
- Molecular Formula:
- C7H12O3
- Molecular Weight:
- 144.17
- MDL Number:
- MFCD01075170
- MOL File:
- 110238-91-0.mol
- MSDS File:
- SDS
Last updated:2025-08-28 17:34:51
| Product description | Number | Pack Size | Price |
| Methyl tetrahydro-2H-pyran-4-carboxylate produced by BASF, ≥98.0% (GC) | 40199 | 50ml | $82.5 |
| Methyl tetrahydro-2H-pyran-4-carboxylate produced by BASF, ≥98.0% (GC) | 40199 | 250ml | $547 |
| Methyl tetrahydro-2H-pyran-4-carboxylate | M331503 | 50mg | $45 |
| Methyl tetrahydro-2H-pyran-4-carboxylate | OR10552 | 25g | $53 |
| Methyl tetrahydro-2H-pyran-4-carboxylate | 2H23-1-X3 | 25g | $58 |
| More product size | |||
| Melting point | -33°C |
|---|---|
| Boiling point | 197°C |
| Density | 1.080 g/mL at 20 °C(lit.) |
| Flash point | 86°C |
| storage temp. | Sealed in dry,Room Temperature |
| form | liquid |
| color | Clear |
| BRN | 114974 |
| InChIKey | CNCMVGXVKBJYNU-UHFFFAOYSA-N |
| CAS DataBase Reference | 110238-91-0(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H319 |
| Precautionary statements | P305+P351+P338 |
| Hazard Codes | Xi |
| Risk Statements | 36-36/37/38 |
| Safety Statements | 26-37/39 |
| RIDADR | 1993 |
| WGK Germany | 2 |
| Hazard Note | Harmful |
| HS Code | 29329990 |
Methyl tetrahydropyran-4-carboxylate price More Price(25)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 40199 | Methyl tetrahydro-2H-pyran-4-carboxylate produced by BASF, ≥98.0% (GC) | 110238-91-0 | 50ml | $82.5 | 2025-07-31 | Buy |
| Sigma-Aldrich | 40199 | Methyl tetrahydro-2H-pyran-4-carboxylate produced by BASF, ≥98.0% (GC) | 110238-91-0 | 250ml | $547 | 2023-06-20 | Buy |
| TRC | M331503 | Methyl tetrahydro-2H-pyran-4-carboxylate | 110238-91-0 | 50mg | $45 | 2021-12-16 | Buy |
| Apolloscientific | OR10552 | Methyl tetrahydro-2H-pyran-4-carboxylate | 110238-91-0 | 25g | $53 | 2021-12-16 | Buy |
| SynQuest Laboratories | 2H23-1-X3 | Methyl tetrahydro-2H-pyran-4-carboxylate | 110238-91-0 | 25g | $58 | 2021-12-16 | Buy |
Methyl tetrahydropyran-4-carboxylate Chemical Properties,Uses,Production
Chemical Properties
colorless liquid
Uses
Methyl tetrahydro-2H-pyran-4-carboxylate may be used in the following syntheses:
- cycloalkylamide derivatives
- tetrahydro-2-furoic chloride
- tetrahydro-2H-pyran-4-carboxylic chloride
Synthesis
5337-03-1
77-78-1
110238-91-0
Tetrahydropyran-4-carboxylic acid (1.00 g, 7.68 mmol) was slowly added to a stirred suspension of anhydrous potassium carbonate (1.17 g, 8.45 mmol) in acetone (40 mL), followed by the dropwise addition of dimethyl sulfate (0.8 mL, 8.45 mmol). The reaction mixture was stirred under heating conditions for 3 hours. After completion of the reaction, the inorganic salts were removed by filtration and the filter cake was washed with acetone. The filtrates were combined, dried and concentrated to afford methyl tetrahydropyran-4-carboxylate (1.1 g, 99% yield), which was used in the subsequent reaction without further purification. The product was analyzed by GC-MS showing m/z 145 (MH+); 1H NMR (300 MHz, CDCl3) δ 1.70-1.80 (m, 4H), 2.47-2.52 (m, 1H), 3.34-3.43 (m, 2H), 3.65 (s, 3H), 3.88-3.95 (m, 2H).
References
[1] Patent: US2004/224997, 2004, A1. Location in patent: Page 18
[2] Journal of the American Chemical Society, 1993, vol. 115, # 18, p. 8401 - 8408
Synthesis of Methyl tetrahydropyran-4-carboxylate from Tetrahydro-2H-pyran-4-carboxylic acid and Dimethyl sulfate
Methyl tetrahydropyran-4-carboxylate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
Global( 222)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Chuanghai Biotechnology Co., Ltd | +8615350571055 | Sibel@chuanghaibio.com | China | 8767 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29843 | 58 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 8497 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Changzhou Ditong Chemical Co.,Ltd | +86-0519-88299272 | info@edengenechem.com | China | 2176 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
View Lastest Price from Methyl tetrahydropyran-4-carboxylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-12-17 | Methyl tetrahydropyran-4-carboxylate
110238-91-0
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
 |
2025-12-11 | Methyl tetrahydropyran-4-carboxylate
110238-91-0
|
US $0.00 / KG | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-11-18 | Methyl tetrahydropyran-4-carboxylate
110238-91-0
|
US $1.10 / g | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited |
-
- Methyl tetrahydropyran-4-carboxylate
110238-91-0
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- Methyl tetrahydropyran-4-carboxylate
110238-91-0
- US $0.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- Methyl tetrahydropyran-4-carboxylate
110238-91-0
- US $1.10 / g
- 99.00%
- Dideu Industries Group Limited
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CAS:110238-91-0
Methyl tetrahydro-2H-pyran-4-carboxylate
110238-91-0
10238-91-0
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