COBALTOCENE HEXAFLUOROPHOSPHATE
- CAS No.
- 12427-42-8
- Chemical Name:
- COBALTOCENE HEXAFLUOROPHOSPHATE
- Synonyms
- Bis(cyclopentadienyl)cobalt (II) hexafluorophosphate;COBALTOCENE HEXAFLUOROPHOSPHATE;BIS(CYCLOPENTADIENYL)COBALT(III);COBALTOCENIUM HEXAFLUOROPHOSPHATE;COBALTICINIUM HEXAFLUOROPHOSPHATE;Cobalticiniumhexafluorophosphate,98%;Cobaltocenium hexafluorophosphate,98%;cobaltocenium hexafluorophosphate(1-);Dicyclopentadienylcobalt hexafluorophosphate;BIS(CYCLOPENTADIENYL)COBALT HEXAFLUOROPHOSPHATE
- CBNumber:
- CB2314446
- Molecular Formula:
- C10H10CoF6P10*
- Molecular Weight:
- 334.08
- MDL Number:
- MFCD00011874
- MOL File:
- 12427-42-8.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| solubility | slightly sol. in Dimethylformamide |
|---|---|
| form | crystal |
| color | yellow |
| InChI | 1S/2C5H5.Co.F6P/c2*1-2-4-5-3-1;;1-7(2,3,4,5)6/h2*1-5H;;/q;;+1;-1 |
| InChIKey | IASMSXQWVNBFOM-UHFFFAOYSA-N |
| SMILES | [Co+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22-36/37/38 | |||||||||
| Safety Statements | 26-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 2931.90.9051 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
COBALTOCENE HEXAFLUOROPHOSPHATE price More Price(23)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 279811 | Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate 98% | 12427-42-8 | 1g | $73.9 | 2026-04-30 | Buy |
| TCI Chemical | C1589 | Bis(cyclopentadienyl)cobalt(III) Hexafluorophosphate >96.0%(T) | 12427-42-8 | 1g | $365 | 2026-04-30 | Buy |
| Strem Chemicals | 27-0410 | Cobalticinium hexafluorophosphate, 98% 98% | 12427-42-8 | 1g | $77 | 2026-04-30 | Buy |
| Strem Chemicals | 27-0410 | Cobalticinium hexafluorophosphate, 98% 98% | 12427-42-8 | 5g | $307 | 2026-04-30 | Buy |
| ChemScene | CS-0085274 | Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate ≥98% | 12427-42-8 | 250mg | $65 | 2026-06-04 | Buy |
COBALTOCENE HEXAFLUOROPHOSPHATE Chemical Properties,Uses,Production
Chemical Properties
yellow powder
Uses
Uses:
- Cocatalyst for Heck reaction of aryl iodides with alkenes using palladium as catalyst in water
- Reactant for modification of organometallic electrodes surfaces through cathodic reduction
- Reactant in synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers
Synthesis Reference(s)
[1](a) Gmelin, Handbuch der Anorganischen Chemie, 8th ed; Verlag Chemie: Weinheim, 1973; Supplement, Vol. 5, part 1. (b) Sheats, J. E. JOM Libr. 1979, 7, 461.
reaction suitability
core: cobalt
reagent type: catalyst
Synthesis
Cobaltocene hexafluorophosphate is readily synthesized from cobalt(II) salts + CpNa, followed by air + HPF6 or NH4PF6. Salts with a wide range of other counterions may be obtained similarly. The cobaltocenium ion[1] may be precipitated from aqueous solution by a variety of large anions. In addition to PF6 -, convenient counterions include Br3 - and I3 -. The simple halides are hygroscopic, but may be obtained in anhydrous form by removal of water under vacuum.
Precautions
COBALTOCENE HEXAFLUOROPHOSPHATE is very stable; irritant.
COBALTOCENE HEXAFLUOROPHOSPHATE Preparation Products And Raw materials
Raw materials
Preparation Products
COBALTOCENE HEXAFLUOROPHOSPHATE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shijizhuang Zhoukun Pharmaceutical Technology Co., LTD | 0311-83784138 18633934202 | zhoukunpharma@163.com | China | 2420 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| INTATRADE GmbH | +49 3493/605464 | sales@intatrade.de | Germany | 3563 | 66 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Maya High Purity Chemicals | +86 (573) 82222445 (0)18006601000 452520369 | sales@maya-r.com | China | 11693 | 57 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66113011 13913916777 | cfzhang@aikonchem.com | China | 19902 | 55 |
View Lastest Price from COBALTOCENE HEXAFLUOROPHOSPHATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-06-30 | COBALTOCENE HEXAFLUOROPHOSPHATE
12427-42-8
|
1kg | 99% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd |
-
- COBALTOCENE HEXAFLUOROPHOSPHATE
12427-42-8
- $0.00
- 99%
- Shaanxi Dideu New Materials Co. Ltd
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