2-Bromo-5-methoxyphenylboronic acid
- CAS No.
- 89694-44-0
- Chemical Name:
- 2-Bromo-5-methoxyphenylboronic acid
- Synonyms
- 2-Bromo-5-methoxyphenylboronic acid;2-bromine-5-methoxyphenylboronic acid;(2-BROMO-5-METHOXY)BENZENEBORONIC ACID;Boronic acid, B-(2-bromo-5-methoxyphenyl)-;2-Bromo-5-methoxyphenylboronic Acid (contains varying amounts of Anhydride)
- CBNumber:
- CB2468882
- Molecular Formula:
- C7H8BBrO3
- Molecular Weight:
- 230.85
- MDL Number:
- MFCD06659859
- MOL File:
- 89694-44-0.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Hazard Note | Irritant | |||||||||
| HS Code | 2931900090 | |||||||||
| NFPA 704 |
|
2-Bromo-5-methoxyphenylboronic acid price More Price(65)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | OR1188 | 2-Bromo-5-methoxybenzeneboronic acid ≥95% | 89694-44-0 | 250mg | $41 | 2026-06-04 | Buy |
| Apolloscientific | OR1188 | 2-Bromo-5-methoxybenzeneboronic acid ≥95% | 89694-44-0 | 1g | $90 | 2026-06-04 | Buy |
| AK Scientific | AMTB841 | (2-Bromo-5-methoxyphenyl)boronic acid 97% | 89694-44-0 | 250mg | $31 | 2026-06-04 | Buy |
| Activate Scientific | AS117966 | 2-Bromo-5-methoxybenzene boronic acid 97% | 89694-44-0 | 1g | $31 | 2026-06-04 | Buy |
| AK Scientific | AMTB841 | (2-Bromo-5-methoxyphenyl)boronic acid 97% | 89694-44-0 | 1g | $81 | 2026-06-04 | Buy |
2-Bromo-5-methoxyphenylboronic acid Chemical Properties, Uses, Production
Synthesis
10365-98-7
89694-44-0
Under argon protection, 3-methoxyphenylboronic acid (9.12 g, 60.0 mmol) was dissolved in dichloromethane (200 mL) with triphenylphosphine sulfide (932 mg, 6.00 mmol) in a 300 mL aubergine flask, and stirred until completely dissolved. Subsequently, N-bromosuccinimide (13.0 g, 72.0 mmol) was added to the solution and stirred continuously for 48 hours at room temperature. Upon completion of the reaction, saturated aqueous sodium thiosulfate solution was added to quench the reaction. Extraction was carried out with dichloromethane (100 mL × 3) and the organic phases were combined, washed with saturated brine and dried over anhydrous sodium sulfate. After filtration, the crude product was concentrated under reduced pressure. The target product 2-bromo-5-methoxyphenylboronic acid (8.45 g, 36.6 mmol, 61.0% yield) was purified by silica gel column chromatography (silica gel 290 g, eluent hexane/acetone = 1/1).
References
[1] Organic Letters, 2010, vol. 12, # 11, p. 2480 - 2483
[2] Patent: JP2018/30788, 2018, A. Location in patent: Paragraph 0057
[3] Organic Letters, 2015, vol. 17, # 4, p. 1042 - 1045
2-Bromo-5-methoxyphenylboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14098 | 59 |
| Bide Pharmatech Ltd. | 400-164-7117 18317119277 | product02@bidepharm.com | China | 40000 | 60 |
| Hangzhou J&H Chemical Co., Ltd. | 0571-87396432 | sales@jhechem.com | China | 14905 | 59 |
| Wuhan Chemwish Technology Co.， Ltd | 027-67849912 | sales@chemwish.com | China | 9144 | 60 |
| Henan CoreyChem Co., Ltd | 0371-86658258 | info@coreychem.com | China | 10442 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
| Nanjing Klender Bio-Technology Co., Ltd. | 025-52343882 18112933882 | sales@kldbio.com | China | 2019 | 55 |
View Latest Price from 2-Bromo-5-methoxyphenylboronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | 2-BROMO-5-METHOXYPHENYLBORONIC ACID
89694-44-0
|
$1.00 | 1KG | 98%-100% | 1 | Career Henan Chemical Co |
-
- 2-BROMO-5-METHOXYPHENYLBORONIC ACID
89694-44-0
- $1.00
- 98%-100%
- Career Henan Chemical Co
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