Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>2-Iodoxybenzoic acid

2-Iodoxybenzoic acid

2-Iodoxybenzoic acid Structure
2-Iodoxybenzoic acid structure
CAS No.
61717-82-6
Chemical Name:
2-Iodoxybenzoic acid
Synonyms
IBX;1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;1-HYDROXY-1,2-BENZIODOXOL-3(1H)-ONE 1-OXIDE;BX;2-Iodoacylbenzoic acid;2-Iodoxybenzoic acid(IBX);1-hydroxy-1-oxo-3H-1$l^{5},2-benziodaoxol-3-one;39.0%(T);TRILON®TRILON®BX
CBNumber:
CB3194863
Molecular Formula:
C7H5IO4
Molecular Weight:
280.02
MDL Number:
MFCD02912492
MOL File:
61717-82-6.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-04 16:00:12
Request For Quotation

2-Iodoxybenzoic acid Properties

Melting point 280 °C
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
solubility DMSO (Very Slightly, Heated)
form powder to crystal
color White to Almost white
Merck 14,5048
InChI InChI=1S/C7H5IO4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H,(H,9,10)
InChIKey CQMJEZQEVXQEJB-UHFFFAOYSA-N
SMILES C1(C(=O)O)C=CC=CC=1I(=O)=O
CAS DataBase Reference 61717-82-6(CAS DataBase Reference)
FDA UNII 3K0C43POH0
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H314-H335-H372
Precautionary statements  P260-P270-P280-P303+P361+P353-P305+P351+P338-P314
target organs Lungs, Respiratory system
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C,Xi,Xn
Risk Statements  22-34-44-42/43-36/37/38-20/21/22-37-35-1
Safety Statements  26-36/37/39-45-22-35
RIDADR  UN 1759 8/PG 2
WGK Germany  3
HazardClass  8
PackingGroup  Ⅱ
HS Code  29163990
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Eye Dam. 1
Skin Corr. 1
STOT RE 1 Inhalation
STOT SE 3
Limited Quantities 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
1
2 2

2-Iodoxybenzoic acid price More Price(57)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 661384 2-Iodoxybenzoic acid contains stabilizer, 45wt. % (IBX) 61717-82-6 1g $62.5 2026-04-30 Buy
Sigma-Aldrich 661384 2-Iodoxybenzoic acid contains stabilizer, 45wt. % (IBX) 61717-82-6 10g $206 2026-04-30 Buy
TCI Chemical I0791 2-Iodoxybenzoic Acid (stabilized with Benzoic Acid + Isophthalic Acid) >39.0%(T) 61717-82-6 5g $73 2026-04-30 Buy
TCI Chemical I0791 2-Iodoxybenzoic Acid (stabilized with Benzoic Acid + Isophthalic Acid) >39.0%(T) 61717-82-6 25g $227 2026-04-30 Buy
TRC TRC-I729400-50G 2-Iodoxybenzoic Acid 61717-82-6 50g $306 2026-06-03 Buy
Product number Packaging Price Buy
661384 1g $62.5 Buy
661384 10g $206 Buy
I0791 5g $73 Buy
I0791 25g $227 Buy
TRC-I729400-50G 50g $306 Buy

2-Iodoxybenzoic acid Chemical Properties,Uses,Production

Chemical Properties

White to off-white powder, prills or agglomerates

Uses

2-Iodoxybenzoic Acid is used in the oxidation of alcohols in organic synthesis. It is also frequently used in the preparation of Dess-Martin periodinane.

Uses

Stabilized 2-Iodoxybenzoic Acid (SIBX)

Definition

ChEBI: A benziodoxole compound having hydroxy and oxo substituents at the 1-position and an oxo substituent at the 3-position.

Synthesis Reference(s)

The Journal of Organic Chemistry, 48, p. 4155, 1983 DOI: 10.1021/jo00170a070

reaction suitability

reagent type: oxidant

Synthesis

2-Iodobenzoic acid

88-67-5

2-Iodoxybenzoic acid

61717-82-6

General procedure for the synthesis of 2-iodobenzoic acid from 2-iodobenzoic acid: note: IBX may explode when subjected to shock or heated to over 200 °C. IBX was prepared with reference to the method described by Sputore and coworkers.In a 500 mL round bottom flask equipped with a mechanical stirrer, 2-iodobenzoic acid (12.5 g, 50.4 mmol) was added to a solution of Oxone (40.281 g, 65.5 mmol) in deionized water (163 mL). The reaction mixture was heated to 73 °C and stirred vigorously at this temperature for 3 hours. Subsequently, the reaction mixture was cooled to 0 °C and continued to stir slowly for 1.5 hours. The mixture was filtered through a porous glass funnel and the resulting white solid was washed sequentially with deionized water (730 mL) and acetone (235 mL). Finally, the product was dried under high vacuum for 2 days to afford 2-iodoylbenzoic acid as a white solid in 84% yield (11.848 g, 42.3 mmol).

References

[1] European Journal of Organic Chemistry, 2012, # 7, p. 1439 - 1447
[2] Journal of Organic Chemistry, 1983, vol. 48, # 22, p. 4155 - 4156
[3] Journal of the American Chemical Society, 1991, vol. 113, # 19, p. 7277 - 7287
[4] Journal of Organic Chemistry, 2005, vol. 70, # 17, p. 6991 - 6994
[5] Tetrahedron, 2002, vol. 58, # 23, p. 4573 - 4587

2-Iodoxybenzoic acid Preparation Products And Raw materials

Raw materials

2-Iodobenzoic acid Isophthalic acid Potassium bromate Benzoic acid Sulfuric acid
o-Iodobenzoic acid sodium salt 1-Hydroxy-2-oxa-1-ioda(III)indan-3-one 2-Iodosobenzoic acid Potassium peroxymonosulfate

1of2

Preparation Products

Dess-Martin periodinane (5-Bromothiophen-3-yl)methanesulfonyl chloride 2,4-Dimethyl-3-pentanol Pinacol 2-Methyl-2-butanol

2-Iodoxybenzoic acid Suppliers

Global( 319)Suppliers
Supplier Tel Email Country ProdList Advantage
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11777 60
Shanghai Yanze Chemical Co., Ltd. 15345144255 19975051755 260924549@qq.com China 2979 58
Nanjing ChuGuang Chemical Industry Co., Ltd. 025-83697070 15001062168 wen-jun.zheng@chemlin.com.cn China 23 58
Shanghai Boyle Chemical Co., Ltd. 021-50182298 021-50180596 sales@boylechem.com China 2202 55
Nanbu County Chengxin Technology Co., Ltd. 0838-5675166 15883665058 nbcxkj@126.com China 956 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Supplier Advantage
Beijing Ouhe Technology Co., Ltd 60
Shanghai Yanze Chemical Co., Ltd. 58
Nanjing ChuGuang Chemical Industry Co., Ltd. 58
Shanghai Boyle Chemical Co., Ltd. 55
Nanbu County Chengxin Technology Co., Ltd. 55
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
INTATRADE GmbH 66
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61

Related articles

View Lastest Price from 2-Iodoxybenzoic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Iodoxybenzoic acid pictures 2026-07-22 2-Iodoxybenzoic acid
61717-82-6
 1kg 98% 20MT Watson Biotechnology Co.,Ltd
2-Iodoxybenzoic acid pictures 2024-04-12 2-Iodoxybenzoic acid
61717-82-6
 1kg 99% 2000ton Shaanxi Haibo Biotechnology Co., Ltd
2-Iodoxybenzoic Acid pictures 2021-07-13 2-Iodoxybenzoic Acid
61717-82-6
 $10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd

2-Iodoxybenzoic acid Spectrum

2-Iodoxybenzoic acid(61717-82-6)FT-IR

61717-82-6(2-Iodoxybenzoic acid)Related Search:

Citric acid 2-Iodobenzoic acid Ethyl 2-(Chlorosulfonyl)acetate Sodium lauroylglutamate Sodium N-lauroylsarcosinate
Folic acid Ascoric Acid 2-Iodosobenzoic acid 2-Iodobenzyl alcohol 2-Iodobenzaldehyde
2-Iodylbenzoic acid 2-Iodotoluene Iodosobenzene Iodoxybenzene 1-HYDROXY-1,3-DIOXO-1,3-DIHYDRO-1L5-BENZO[D][1,2]IODOXOLE-4-CARBOXYLIC ACID
2-Iodoxybenzoic acid Stabilized 2-iodoxybenzoic acid (sibix) mixture 2-IODOXYBENZOIC ACID STABILIZED MIXTURE (DESS MART

1of4

1-hydroxy-1-oxo-3H-1$l^{5},2-benziodaoxol-3-one 2-Iodoxybenzoic Acid Stabilized (SIBX) 2-Iodoxybenzoic Acid (stabilized with Benzoic Acid + Isophthalic Acid) 1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide 97%, 45 wt. % IBX SIBX, 1,3-Dihydro-1,3-dioxo-1-hydroxy-1,2-benziodoxole stabilised Iodoxybenzoic aci 2-Iodoxybenzoic acid contains stabilizer, 45 wt. % (IBX) TRILON® TRILON®BX 2-IODOXYBENZOIC ACID (IBX) 1M SOLUTION IN DMSO 1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide (mixture of isomers) 1,2-BENZIODOXOL-3(1H)-ONE, 1-HYDROXY, 1-OXIDE 1-HYDROXY-1,2-BENZIODOXOL-3(H)-ONE 1-OXIDE 2-IODOXYBENZOIC ACID, STABILIZED (45 WT& IbxO-IodoxybenzoicAcid 2-Iodoxybenzoic acid, stabilized 2-Iodoxybenzoic acid IBX(1-HYDROXY-1,2-BENZIODOXOL-3(1H)-ONE-1-OXIDE) SIBX, Stabilized IBX 2-Iodoxybenzoic acid ,39-50% [Stabilizer：Benzoic acid 23%，Isophtalic acid 30%] 1-Hydroxy-1,3-dioxo-3H-benz[d][1,2]iodoxol 1-Hydroxy-3H-benz[d][1,2]iodoxol-1,3-dione 2-Iodoxybenzoic acidDess Martin analogueSIBX 1-Hydroxy-1,2-benziodoxy-3-(1h)-one-1-xoide 2-Iodoxybenzoic Acid Stabilized (SIBX), 46 wt% IBX 1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide 97% IBX, 1,3-Dihydro-1,3-dioxo-1-hydroxy-1,2-benziodoxole 1-hydroxy-1,3-dioxobenziodoxole 1-hydroxy-1-oxo-1$l^{5},2-benziodoxol-3-one 2-Iodoxybenzoic acid (mixture of isomers) 2-Iodoxybenzoic acid, stabilized (45 wt.% IBX) 2-IodoxybenzoicAcid(stabilizedwithBenzoicAcid+IsophthalicAcid)> 39.0%(T) 2-Iodoxybenzoic Acid,>95% 2-Iodoxybenzoic acid (Stabilised) 2-IodoxybenzoicAci 2-Iodoxybenzoic acid, contains stabilizer, 0.45wt (IBX) 2-Iodoxybenzoic acid contains stabilizer 1-hydroxy-1-oxo-3H-1λ?,2-benziodaoxol-3-one Stabilised IBX [Stabilised iodoxy benzoic acid} 1-hydroxy-1-oxo-3H-1lambda5,2-benziodaoxol-3-one IBX,contains stabilizer, 45-47wt% 1-Hydroxy-1,2-benziodoxol-3(1H)-one 1-oxide, 45 wt. % IBX 1-HYDROXY-1,2-BENZIODOXOL-3(H)-ONE 1-OXIDE (45% W/W WITH STABLIZER) 1-HYDROXY-1,2-BENZIODOXOL-3(1H)-ONE 1-OXIDE 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione 2-Iodoxybenzoic acid(IBX) 2-Iodoacylbenzoic acid BX IBX 61717-82-6 1717-82-6 C7H5IO4 Hypervalent Iodine Oxidation Synthetic Reagents Fused Ring Systems pharmacetical