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2-(TRIBUTYLSTANNYL)THIAZOLE

2-(TRIBUTYLSTANNYL)THIAZOLE Structure
2-(TRIBUTYLSTANNYL)THIAZOLE structure
CAS No.
121359-48-6
Chemical Name:
2-(TRIBUTYLSTANNYL)THIAZOLE
Synonyms
2-(Tributylstannyl)-1,3-thiazole;TZ-Sn;SKL010;SKL978;2-(Tributyltin)thiazole;2-Tributylstaylthiazole;Clomethiazolum Impurity 13;2-(TRIBUTYLSTANNYL)THIAZOLE;Tributyl-2-thiazolylstannane;2-Tributylstannanyl-thiazole
CBNumber:
CB3238857
Molecular Formula:
C15H29NSSn
Molecular Weight:
374.17
MDL Number:
MFCD01319057
MOL File:
121359-48-6.mol
MSDS File:
SDS
Last updated:2026-05-28 01:03:43
Product description Number Pack Size Price
2-Tributylstannylthiazole 97% 642541 1g $169
2-Tributylstannylthiazole 97% 642541 5g $587
2-(Tributylstannyl)-1,3-thiazole Asreported 291022 1g $453
2-(Tributylstannyl)-1,3-thiazole Asreported 291022 2g $731
2-(Tributylstannyl)-1,3-thiazole Asreported 291022 5g $1118
More product size
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2-(TRIBUTYLSTANNYL)THIAZOLE Properties

Melting point 224-225℃
Boiling point 307-309 °C(lit.)
Density 1.1900 g/mL at 25 °C(lit.)
refractive index n20/D 1.5200(lit.)
Flash point >230 °F
storage temp. Sealed in dry,2-8°C
solubility Not miscible or difficult to mix.
pka 2.73±0.10(Predicted)
form liquid
color Clear, almost colourless
InChI InChI=1S/3C4H9.C3H2NS.Sn/c3*1-3-4-2;1-2-5-3-4-1;/h3*1,3-4H2,2H3;1-2H;
InChIKey WUOFQGMXQCSPPV-UHFFFAOYSA-N
SMILES S1C=CN=C1[Sn](CCCC)(CCCC)CCCC
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Skull and Crossbones (GHS06)Health Hazard (GHS08)Environment (GHS09)
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H312-H315-H319-H360FD-H372-H410
Precautionary statements  P202-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  T,N,Xi
Risk Statements  21-25-36/38-48/23/25-50/53
Safety Statements  35-36/37/39-45-60-61
RIDADR  UN 2788 6.1/PG 2
WGK Germany  3
HazardClass  IRRITANT, KEEP COLD, TOXIC
HazardClass  6.1
HS Code  2934100090
Storage Class 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard Classifications Acute Tox. 3 Oral
Acute Tox. 4 Dermal
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Repr. 1B
Skin Irrit. 2
STOT RE 1
NFPA 704
1
3 0

2-(TRIBUTYLSTANNYL)THIAZOLE price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 642541 2-Tributylstannylthiazole 97% 121359-48-6 1g $169 2026-04-30 Buy
Sigma-Aldrich 642541 2-Tributylstannylthiazole 97% 121359-48-6 5g $587 2026-04-30 Buy
Usbiological 291022 2-(Tributylstannyl)-1,3-thiazole Asreported 121359-48-6 1g $453 2026-06-03 Buy
Usbiological 291022 2-(Tributylstannyl)-1,3-thiazole Asreported 121359-48-6 2g $731 2026-06-03 Buy
Usbiological 291022 2-(Tributylstannyl)-1,3-thiazole Asreported 121359-48-6 5g $1118 2026-06-03 Buy
Product number Packaging Price Buy
642541 1g $169 Buy
642541 5g $587 Buy
291022 1g $453 Buy
291022 2g $731 Buy
291022 5g $1118 Buy

2-(TRIBUTYLSTANNYL)THIAZOLE Chemical Properties,Uses,Production

Uses

Reagent for arylation of thiazole by Stille cross-coupling.1

Uses

Used as reagent for arylation of thiazole by Stille cross-coupling.

Synthesis

2-Bromothiazole

3034-53-5

Tributyltin chloride

1461-22-9

2-(TRIBUTYLSTANNYL)THIAZOLE

121359-48-6

A hexane solution of n-butyllithium (6.14 mmol, 2.5 M) was slowly added dropwise to a stirred anhydrous ethyl ether solution of 2-bromothiazole (3.07 mmol) at 0 °C under argon protection. After 1 hour of reaction, the mixture was cooled to -78 °C, followed by the slow addition of anhydrous ether solution of tributyltin chloride (3.07 mmol). The mixture was stirred at -78°C overnight. After completion of the reaction, the mixture was poured into water (50 mL) and the aqueous layer was extracted with ether (3 x 30 mL). The organic layers were combined, dried with anhydrous magnesium sulfate, and concentrated under reduced pressure to remove the solvent to give 2-(tri-n-butylmethylstannyl)thiazole (L-01b) as a light brown oil in quantitative yield. The product was used directly for the synthesis of the subsequent compound L-01a without further purification.

References

[1] Patent: US8575355, 2013, B2. Location in patent: Paragraph 0032
[2] Patent: JP2016/56276, 2016, A. Location in patent: Paragraph 0129; 0130
[3] Patent: KR2017/26286, 2017, A. Location in patent: Paragraph 0112-0115
[4] Patent: EP1982982, 2008, A1. Location in patent: Page/Page column 76
[5] Patent: KR101511396, 2015, B1. Location in patent: Paragraph 1061-1064

2-(TRIBUTYLSTANNYL)THIAZOLE Preparation Products And Raw materials

Raw materials

2-Bromothiazole Tributyltin chloride 2-(Trimethylsilyl)thiazole Hexane n-Butyllithium

Preparation Products

3-(Thiazol-2-yl)aniline

2-(TRIBUTYLSTANNYL)THIAZOLE Suppliers

Global( 122)Suppliers
Supplier Tel Email Country ProdList Advantage
Sach biotech Co.,Ltd 		+86-15888865902; +8615888865902 sales@hzsqchem.com China 66 58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD 		+86-15225627621 +86-13213167925 jiuyitime@fdachem.com China 16512 58
Shanghai Arbor Chemical Co., Ltd. 		021-60451682 act@arborchemical.com CHINA 904 58
Accela ChemBio Inc. 		+1-858-6993322 info@accelachem.com United States 21193 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49979 58
career henan chemical co 		+86-0371-86658258 +8613203830695 factory@coreychem.com China 29792 58
Alfa Chemistry 		+1-5166625404; Info@alfa-chemistry.com United States 20405 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418684 +8618949823763 sales@tnjchem.com China 25356 58
Suzhou Victorypharm Co.,Ltd. 		+86-13916956214 sales@victory-pharm.com China 1299 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615531151365 mina@chuanghaibio.com China 18126 58
Supplier Advantage
Sach biotech Co.,Ltd 		58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD 		58
Shanghai Arbor Chemical Co., Ltd. 		58
Accela ChemBio Inc. 		58
CONIER CHEM AND PHARMA LIMITED 		58
career henan chemical co 		58
Alfa Chemistry 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Suzhou Victorypharm Co.,Ltd. 		58
Hebei Chuanghai Biotechnology Co., Ltd 		58

View Lastest Price from 2-(TRIBUTYLSTANNYL)THIAZOLE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-(Tributylstannyl)-1,3-thiazole pictures 2026-04-17 2-(Tributylstannyl)-1,3-thiazole
121359-48-6
 $1.10-9.90 1kg 99%min 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
2-(TRIBUTYLSTANNYL)THIAZOLE pictures 2025-06-14 2-(TRIBUTYLSTANNYL)THIAZOLE
121359-48-6
 $6900.00-7142.00 1kg 99% 5mt Sach biotech Co.,Ltd
2-(TRIBUTYLSTANNYL)THIAZOLE pictures 2020-01-09 2-(TRIBUTYLSTANNYL)THIAZOLE
121359-48-6
 $2.00 1g 98%min Career Henan Chemical Co

2-(TRIBUTYLSTANNYL)THIAZOLE Spectrum

2-(TRIBUTYLSTANNYL)THIAZOLE(121359-48-6)1HNMR

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2-(Tri-n-butylstannyl)thiazole, 96% 2-(TRIBUTYLSTANNYL)THIAZOLE 2-(Tributylstannyl)-1,3-thiazole 95+% 2-Tributylstaylthiazole (1,3-Thiazol-2-yl)tributylstannane Thiazole,2-(tributylstannyl)- 2-(Tributyltin)thiazole Tributyl-2-thiazolylstannane 2-Tributylstannylthiazole 97% TZ-Sn 2-(tributylstannanyl)-1,3-thiazole 2-Tributylstannanyl-thiazole tributyl(thiazol-2-yl)stannane Tributyl(1,3-thiazol-2-yl)stannane SKL010 SKL978 2-(Tributylstannyl)thiazole - [T2252] Clomethiazolum Impurity 13 2-(Tributylstannyl)-1,3-thiazole 121359-48-6 C15H29NSSn Organometallic Reagents Organotins Organotin Organometallic Reagents Organostannes Thiazole Tributylstanny Organometallic Reagents Organotin Organotins Chemical Synthesis