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(4-BROMO-3-METHYLPHENYL)METHANOL

(4-BROMO-3-METHYLPHENYL)METHANOL structure

CAS No.: 149104-89-2

Chemical Name:: (4-BROMO-3-METHYLPHENYL)METHANOL

Synonyms: 4-bromo-3-methylbenzyl alcoho;4-Bromo-3-methylbenzyl alcohol;(4-BROMO-3-METHYLPHENYL)METHANOL;4-Bromo-3-methylbenzylalcohol,tech;Benzenemethanol, 4-bromo-3-methyl-;4-Bromo-3-methylbenzyl alcohol≥ 97% (GC)

CBNumber:: CB32449446

Molecular Formula:: C8H9BrO

Molecular Weight:: 201.06

MDL Number:: MFCD09264005

MOL File:: 149104-89-2.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 01:04:03

Product description	Number	Pack Size	Price
4-Bromo-3-methylbenzyl Alcohol >98.0%(GC)	B5285	1g	$123
4-Bromo-3-methylbenzyl Alcohol >98.0%(GC)	B5285	5g	$400
4-Bromo-3-methylbenzyl Alcohol 97%	AS27473	1g	$40
4-Bromo-3-methylbenzyl Alcohol 97%	AS27473	5g	$152
4-Bromo-3-methylbenzyl alcohol 98%	OR400665	5g	$128
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(4-BROMO-3-METHYLPHENYL)METHANOL Properties

Melting point	31-32℃
Boiling point	283℃
Density	1.481
Flash point	125℃
storage temp.	2-8°C
form	fused solid
pka	14.16±0.10(Predicted)
color	Orange/tan, waxy

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P271-P261-P280

Hazard Codes

Risk Statements

HS Code

2906290090

NFPA 704

	1
0		0

(4-BROMO-3-METHYLPHENYL)METHANOL price More Price(64)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	B5285	4-Bromo-3-methylbenzyl Alcohol >98.0%(GC)	149104-89-2	1g	$123	2026-04-30	Buy
TCI Chemical	B5285	4-Bromo-3-methylbenzyl Alcohol >98.0%(GC)	149104-89-2	5g	$400	2026-04-30	Buy
Activate Scientific	AS27473	4-Bromo-3-methylbenzyl Alcohol 97%	149104-89-2	1g	$40	2026-06-04	Buy
Activate Scientific	AS27473	4-Bromo-3-methylbenzyl Alcohol 97%	149104-89-2	5g	$152	2026-06-04	Buy
Apolloscientific	OR400665	4-Bromo-3-methylbenzyl alcohol 98%	149104-89-2	5g	$128	2026-06-04	Buy

Product number	Packaging	Price	Buy
B5285	1g	$123	Buy
B5285	5g	$400	Buy
AS27473	1g	$40	Buy
AS27473	5g	$152	Buy
OR400665	5g	$128	Buy

(4-BROMO-3-METHYLPHENYL)METHANOL Chemical Properties,Uses,Production

Chemical Properties

White low melting crystalline solid

Synthesis

148547-19-7

149104-89-2

Procedure for the synthesis of 4-bromo-3-methylbenzyl alcohol: Methyl 4-bromo-3-methylbenzoate (2.0 g, 8.7 mmol) was dissolved in anhydrous THF (10 mL) and slowly added to a pre-cooled suspension of lithium aluminum hydride (400 mg, 10.4 mmol) in anhydrous THF (30 mL). After addition, the reaction mixture was allowed to gradually warm up to room temperature with continuous stirring for 3 hours. Upon completion of the reaction, water (0.4 mL), 15% NaOH aqueous solution (0.4 mL), and water (1.2 mL) were added sequentially to quench the excess lithium aluminum hydride under the cooling of an ice bath. Insoluble material was removed by diatomaceous earth filtration and the solid residue was washed with ethyl acetate (20 mL x 5). The filtrates were combined and washed with saturated saline (50 mL) and subsequently dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure to afford the crude product 4-bromo-3-methylbenzyl alcohol (1.6 g, 100% yield), which could be used in the subsequent reaction without further purification.1H-NMR (CDCl3, 400 MHz) data were as follows: δ 7.53 (1H, d, J = 8.1 Hz), 7.26 (1H, d, J = 1.5 Hz), 6.40 (1H, dd, J = 8.1, 1.5 Hz). = 8.1, 1.5 Hz), 4.68 (2H, s), 2.44 (3H, s).

References

[1] Patent: US2014/51863, 2014, A1. Location in patent: Paragraph 0205; 0256-0257
[2] Patent: WO2011/143426, 2011, A1. Location in patent: Page/Page column 51
[3] Patent: US2013/131016, 2013, A1. Location in patent: Paragraph 0190
[4] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 1, p. 66 - 71
[5] Journal of Medicinal Chemistry, 2006, vol. 49, # 13, p. 3774 - 3789

(4-BROMO-3-METHYLPHENYL)METHANOL Preparation Products And Raw materials

Raw materials

4-Bromo-3-methylbenzoic acid Ethyl 4-Bromo-3-methylbenzoate Methyl 4-bromo-3-methylbenzoate 4-BROMO-3-METHYL-BENZALDEHYDE Tetrahydrofuran

Lithium Aluminum Hydride

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Preparation Products

(4-BROMO-3-METHYLPHENYL)METHANOL Suppliers

Global( 110)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
CONIER CHEM AND PHARMA LIMITED		sales@conier.com	China	49906	58
career henan chemical co	+86-0371-86658258	factory@coreychem.com	China	29780	58
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14301	58
AFINE CHEMICALS LIMITED	+86-571-85134551 +86-18958018566	info@afinechem.com	China	15058	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 17705817739	info@dycnchem.com	China	52693	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418684 +86-18949823763	sales@tnjchem.com	China	25333	58
Aromsyn Co., Ltd.	+86-0571-85585865 +86-13336024896	CB@aromsyn.com	China	19176	58
PT CHEM GROUP LIMITED	+86-85511178; +86-85511178	peter68@ptchemgroup.com	China	35405	58
GIHI CHEMICALS CO.,LIMITED	+86-571-86217390; +8618058761490	info@gihichemicals.com	China	49859	58
Tianjin Xinghan Biotechnology Co., Ltd	+86-18698089028	1725517238@qq.com	China	2479	58

Supplier	Advantage
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Win-Win chemical CO., Limited	58
AFINE CHEMICALS LIMITED	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Aromsyn Co., Ltd.	58
PT CHEM GROUP LIMITED	58
GIHI CHEMICALS CO.,LIMITED	58
Tianjin Xinghan Biotechnology Co., Ltd	58

View Lastest Price from (4-BROMO-3-METHYLPHENYL)METHANOL manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-01-10	4-BROMO-3-METHYLPHENYL)METHANOL 149104-89-2	$1.00	1g	99%	10000KGS	Career Henan Chemical Co

4-BROMO-3-METHYLPHENYL)METHANOL
149104-89-2
$1.00
99%
Career Henan Chemical Co

(4-BROMO-3-METHYLPHENYL)METHANOL Spectrum

(4-BROMO-3-METHYLPHENYL)METHANOL(149104-89-2)¹HNMR

149104-89-2((4-BROMO-3-METHYLPHENYL)METHANOL)Related Search:

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(4-BROMO-3-METHYLPHENYL)METHANOL Benzenemethanol, 4-bromo-3-methyl- 4-Bromo-3-methylbenzyl alcohol 4-Bromo-3-methylbenzylalcohol,tech 4-Bromo-3-methylbenzyl alcohol≥ 97% (GC) 4-bromo-3-methylbenzyl alcoho 149104-89-2