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Palladium (I) tri-tert-butylphosphine bromide

CAS No.
185812-86-6
Chemical Name:
Palladium (I) tri-tert-butylphosphine bromide
Synonyms
Pd-113;broMopalladiuM;[Pd(μ-Br)t-Bu3P]2;bromopalladium tritert-butylphosphane;Palladium (I) tri-tert-butylphosphine bromide;Dibromobis(tri-tert-butylphosphine)dipalladium;Bromo(tri-tert-butylphosphine)palladium(I)dimer;DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I);Dibromobis(tri-tert-butylphosphine)dipalladium(I);Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium
CBNumber:
CB3279937
Molecular Formula:
C24H56Br2P2Pd2
Molecular Weight:
779.31
MDL Number:
MFCD04114019
MOL File:
185812-86-6.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:51:58

Palladium (I) tri-tert-butylphosphine bromide Properties

storage temp. Inert atmosphere,Store in freezer, under -20°C
form crystal
color dark-green
Water Solubility Soluble in benzene and tolueneSoluble in tetrahydrofuran, toluene, dichloromethane and chloroform. Insoluble in alcohols and water.
Sensitive Air Sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Danger
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  F,C
Risk Statements  36/37/38-34-17-14
Safety Statements  26-36/37/39-45
RIDADR  UN 3393 4.2/PG 1
NFPA 704
1
2 0

Palladium (I) tri-tert-butylphosphine bromide price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 46-0355 Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I) 185812-86-6 100mg $65 2026-04-30 Buy
Strem Chemicals 46-0355 Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I) 185812-86-6 500mg $257 2026-04-30 Buy
Strem Chemicals 46-0355 Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I) 185812-86-6 2g $769 2026-04-30 Buy
aablocks AA00360U Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium 98% 185812-86-6 100mg $17 2026-05-28 Buy
aablocks AA00360U Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium 98% 185812-86-6 250mg $31 2026-05-28 Buy
Product number Packaging Price Buy
46-0355 100mg $65 Buy
46-0355 500mg $257 Buy
46-0355 2g $769 Buy
AA00360U 100mg $17 Buy
AA00360U 250mg $31 Buy

Palladium (I) tri-tert-butylphosphine bromide Chemical Properties, Uses, Production

Reactions

  • Palladium catalyst for rapid room temperature alkylation of unactivated hindered aryl bromides with arylboronic acids.
  • Aryl bromide - silyl ketene acetal coupling.
  • Catalyst for intermolecular α-arylation of zinc amide enolates.
  • Catalyst for α-vinylation of carbonyl compounds.
  • Catalyst for thiol coupling of heteroaromatic aryl bromides.
Reactions of 185812-86-6

Chemical Properties

Greenish blue

Uses

Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.

Palladium (I) tri-tert-butylphosphine bromide Preparation Products And Raw materials

Raw materials

Preparation Products

Global Suppliers ( 123)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shandong Xiya Chemical Co., Ltd 13355009207 13355009207 3007715519@qq.com China 18722 57
Chengdu Ai Keda Chemical Technology Co., Ltd. 4008-755-333 18080918076 800078821@qq.com China 9706 55
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. 025-66113011 13913916777 cfzhang@aikonchem.com China 19902 55
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Beijing Guofang Dingsheng Technology Co., Ltd. 18610472091 gfdskj@163.com China 496 58

View Latest Price from Palladium (I) tri-tert-butylphosphine bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bromo(tri-tert-butylphosphine)palladium(I) dimer pictures 2026-08-25 Bromo(tri-tert-butylphosphine)palladium(I) dimer
185812-86-6
$2.00-5.00 1kg 99% 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE pictures 2019-07-06 PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
185812-86-6
$1.00 1kg 95%-99% 100kg Career Henan Chemical Co

Palladium (I) tri-tert-butylphosphine bromide Spectrum

DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I) Dibromobis(tri-tert-butylphosphine)dipalladium Dibromobis(tri-tert-butylphosphine)dipalladium(I) -bromobis(tri-tert-butylphosphine)dipalladium/ Pd (I) dimer Reasonably stable for packaging and transfer. PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE, DIMER Bromo(tri-tert-butylphosphine)palladium(I)dimer DI--BROMOBIS(TRI-TERT-BUTYLPHOSPHINO)DIPALLADIUM(I) Di-mu-bromobis(tri-t-butylphosphino)dipalladium(I) Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium Palladium, di-μ-bromobis[tris(1,1-dimethylethyl)phosphine]di-, (Pd-Pd) Dibromobis(tri-tert-butylphosphino)dipalladium(I), Palladium(I) tri-tert-butylphosphine bromide, dimer PalladiuM, di-M-broMobis[tris(1,1-diMethylethyl)phosphine]di-,(Pd-Pd) Di-^M-broMobis(tri-tert-butylphosphine)dipalladiuM(I) broMopalladiuM [Pd(μ-Br)t-Bu3P]2 Pd-113 PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE ISO 9001:2015 REACH Bis (tri-t-butylphosphine) palladium bromide (I), dimer bromopalladium tritert-butylphosphane Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I),96% Palladium (I) tri-tert-butylphosphine bromide 185812-86-6 PdC4H93PBr2 C24H54Br2P2Pd2 C12H27BrPPd Pd metal phosphine complex