Palladium (I) tri-tert-butylphosphine bromide
- CAS No.
- 185812-86-6
- Chemical Name:
- Palladium (I) tri-tert-butylphosphine bromide
- Synonyms
- Pd-113;broMopalladiuM;[Pd(μ-Br)t-Bu3P]2;bromopalladium tritert-butylphosphane;Palladium (I) tri-tert-butylphosphine bromide;Dibromobis(tri-tert-butylphosphine)dipalladium;Bromo(tri-tert-butylphosphine)palladium(I)dimer;DI-BROMOBIS(TRI-T-BUTYLPHOSPHINO)DIPALLADIUM (I);Dibromobis(tri-tert-butylphosphine)dipalladium(I);Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium
- CBNumber:
- CB3279937
- Molecular Formula:
- C24H56Br2P2Pd2
- Molecular Weight:
- 779.31
- MDL Number:
- MFCD04114019
- MOL File:
- 185812-86-6.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
|---|---|
| form | crystal |
| color | dark-green |
| Water Solubility | Soluble in benzene and tolueneSoluble in tetrahydrofuran, toluene, dichloromethane and chloroform. Insoluble in alcohols and water. |
| Sensitive | Air Sensitive |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | F,C | |||||||||
| Risk Statements | 36/37/38-34-17-14 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3393 4.2/PG 1 | |||||||||
| NFPA 704 |
|
Palladium (I) tri-tert-butylphosphine bromide price More Price(40)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Strem Chemicals | 46-0355 | Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I) | 185812-86-6 | 100mg | $65 | 2026-04-30 | Buy |
| Strem Chemicals | 46-0355 | Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I) | 185812-86-6 | 500mg | $257 | 2026-04-30 | Buy |
| Strem Chemicals | 46-0355 | Di-μ-bromobis(tri-t-butylphosphino)dipalladium(I) | 185812-86-6 | 2g | $769 | 2026-04-30 | Buy |
| aablocks | AA00360U | Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium 98% | 185812-86-6 | 100mg | $17 | 2026-05-28 | Buy |
| aablocks | AA00360U | Di-mu-Bromobis(tri-tert-butylphosphine)dipalladium 98% | 185812-86-6 | 250mg | $31 | 2026-05-28 | Buy |
Palladium (I) tri-tert-butylphosphine bromide Chemical Properties, Uses, Production
Reactions
- Palladium catalyst for rapid room temperature alkylation of unactivated hindered aryl bromides with arylboronic acids.
- Aryl bromide - silyl ketene acetal coupling.
- Catalyst for intermolecular α-arylation of zinc amide enolates.
- Catalyst for α-vinylation of carbonyl compounds.
- Catalyst for thiol coupling of heteroaromatic aryl bromides.
Chemical Properties
Greenish blue
Uses
Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.
Palladium (I) tri-tert-butylphosphine bromide Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Chengdu Ai Keda Chemical Technology Co., Ltd. | 4008-755-333 18080918076 | 800078821@qq.com | China | 9706 | 55 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66113011 13913916777 | cfzhang@aikonchem.com | China | 19902 | 55 |
| Bide Pharmatech Ltd. | 400-164-7117 18317119277 | product02@bidepharm.com | China | 40000 | 60 |
| Beijing Guofang Dingsheng Technology Co., Ltd. | 18610472091 | gfdskj@163.com | China | 496 | 58 |
View Latest Price from Palladium (I) tri-tert-butylphosphine bromide manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-08-25 | Bromo(tri-tert-butylphosphine)palladium(I) dimer
185812-86-6
|
$2.00-5.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
![]() |
2019-07-06 | PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
185812-86-6
|
$1.00 | 1kg | 95%-99% | 100kg | Career Henan Chemical Co |
-

- Bromo(tri-tert-butylphosphine)palladium(I) dimer
185812-86-6
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-

- PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
185812-86-6
- $1.00
- 95%-99%
- Career Henan Chemical Co





