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2,6-Dichlorophenylhydrazine hydrochloride

CAS No.
50709-36-9
Chemical Name:
2,6-Dichlorophenylhydrazine hydrochloride
Synonyms
2,6-DICHLOROPHENYLHYDRAZINE HCL;1,3-Dichloro-2-hydrazinobenzene;1-(2,6-DICHLOROPHENYL)HYDRAZINE HCL;6-Dichlorophenylhydrazine hydrochloride;2,6-Dichoropheynylhydrazine hydrochloride;2,6-DICHLOROPHENYLHYDRAZINE HYDROCHLORIDE;2,6-DichlorophenylhydrazineHydrochloride>1-(2,6-DICHLOROPHENYL)HYDRAZINE HYDROCHLORIDE;2,6-Dichlorophenylhydrazine hydrochloride 98%;2,6-Dichlorophenylhydrazine hydrochloride, 98+%
CBNumber:
CB3351853
Molecular Formula:
C6H7Cl3N2
Molecular Weight:
213.49
MDL Number:
MFCD00012930
MOL File:
50709-36-9.mol
MSDS File:
SDS
Last updated:2026-05-28 05:18:23

2,6-Dichlorophenylhydrazine hydrochloride Properties

Melting point 225 °C (dec.)(lit.)
Boiling point 346.49°C (rough estimate)
Density 1.6100 (rough estimate)
refractive index 1.6000 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form powder to crystal
color White to Light yellow to Light orange
BRN 4569738
InChI 1S/C6H6Cl2N2.ClH/c7-4-2-1-3-5(8)6(4)10-9;/h1-3,10H,9H2;1H
InChIKey CQNIYLLTIOPFCJ-UHFFFAOYSA-N
SMILES Cl.NNc1c(Cl)cccc1Cl
CAS DataBase Reference 50709-36-9(CAS DataBase Reference)
FDA UNII MXU64S4WET
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Skull and Crossbones (GHS06)
GHS06
Signal word  Danger
Hazard statements  H301-H312+H332-H315-H319-H335
Precautionary statements  P261-P280-P301+P310-P302+P352+P312-P304+P340+P312-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes  T,Xi,Xn
Risk Statements  20/21-25-36/37/38-20/21/22
Safety Statements  26-36/37/39-45-22
RIDADR  UN 2811 6.1/PG 3
WGK Germany  3
Hazard Note  Irritant
HazardClass  6.1
PackingGroup 
HS Code  29280000
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Oral
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
1
2 0

2,6-Dichlorophenylhydrazine hydrochloride price More Price(50)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 153419 2,6-Dichlorophenylhydrazine hydrochloride 98% 50709-36-9 1g $31.9 2023-01-07 Buy
Sigma-Aldrich 153419 2,6-Dichlorophenylhydrazine hydrochloride 98% 50709-36-9 10g $146 2023-01-07 Buy
TCI Chemical D2368 2,6-Dichlorophenylhydrazine Hydrochloride >98.0%(T) 50709-36-9 5g $74 2026-04-30 Buy
Usbiological 273470 2,6-Dichlorophenylhydrazine hydrochloride Asreported 50709-36-9 10g $352 2026-06-03 Buy
Usbiological 273470 2,6-Dichlorophenylhydrazine hydrochloride Asreported 50709-36-9 25g $485 2026-06-03 Buy
Product number Packaging Price Buy
153419 1g $31.9 Buy
153419 10g $146 Buy
D2368 5g $74 Buy
273470 10g $352 Buy
273470 25g $485 Buy

2,6-Dichlorophenylhydrazine hydrochloride Chemical Properties, Uses, Production

Chemical Properties

white to light yellow powder

Uses

(2,6-Dichlorophenyl)hydrazine Hydrochloride

Uses

2,6-Dichlorophenylhydrazine hydrochloride was used in the preparation of 1-(2,6-dichlorophenyl)-4-methyl-5-(4-methoxyphenyl)-1H-pyrazole-3-carboxylic acid, ethyl ester.

Synthesis

2,6-Dichloroaniline

608-31-1

2,6-Dichlorophenylhydrazine hydrochloride

50709-36-9

General procedure for the synthesis of 2,6-dichlorophenylhydrazine hydrochloride from 2,6-dichloroaniline: 2,6-dichloroaniline (10.0 g, 61.72 mmol) was dissolved in an appropriate amount of solvent and cooled to -15 °C. At this temperature, aqueous sodium nitrite (5.11 g, 74.00 mmol) and hydrochloric acid were slowly added. The reaction mixture was stirred at 0-10°C for 15 minutes. The reaction mixture was filtered to remove insoluble matter and subsequently concentrated hydrochloric acid (34.7 g, 150 mmol) was added to the filtrate. The reaction system was maintained at -15 °C and stirring was continued for 30 min, after which the precipitate was collected by filtration to afford 15.00 g of the target product 2,6-dichlorophenylhydrazine hydrochloride. The product was characterized by 1H NMR (300 MHz, DMSO-d6): δ 7.18-7.28 (m, 1H), 7.39-7.52 (m, 2H), 10.30 (br s, 3H); the mass spectrum (MS) showed m/z: 176.90 (M)+.

References

[1] Patent: WO2013/186692, 2013, A1. Location in patent: Page/Page column 103; 104

2,6-Dichlorophenylhydrazine hydrochloride Preparation Products And Raw materials

Global Suppliers ( 164)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
3B Pharmachem (Wuhan) International Co.,Ltd. 18930552037 3bsc@sina.com China 15813 69
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9389 66
Pure Chemistry Scientific Inc. 001-857-928-2050 or 1-888-588-9418 sales@chemreagents.com United States 10174 62
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 marketing@accelachem.com China 10972 64
Shanghai Longsheng chemical Co.,Ltd. 58099637 13585536065 sales@shlschem.com China 9880 59

View Latest Price from 2,6-Dichlorophenylhydrazine hydrochloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,6-Dichlorophenylhydrazine hydrochloride pictures 2026-03-20 2,6-Dichlorophenylhydrazine hydrochloride
50709-36-9
1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
2,6-Dichlorophenylhydrazine hydrochloride pictures 2019-07-06 2,6-Dichlorophenylhydrazine hydrochloride
50709-36-9
$1.00 1KG 98% 1kg,5kg,100kg Career Henan Chemical Co
2,6-Dichoropheynylhydrazine hydrochloride Hydrazine, (2,6-dichlorophenyl)-, monohydrochloride 6-Dichlorophenylhydrazine hydrochloride (2,6-dichlorophenyl)hydrazine monohydrochloride 2,6-Dichlorophenylhydrazine hydrochloride, 98+% 2,6-DICHLOROPHENYLHYDRAZINE HCL 2,6-DICHLOROPHENYLHYDRAZINE HYDROCHLORIDE 1,3-Dichloro-2-hydrazinobenzene 2,6-Dichlorophenylhydrazine hydrochloride 98% 1-(2,6-DICHLOROPHENYL)HYDRAZINE HYDROCHLORIDE 1-(2,6-DICHLOROPHENYL)HYDRAZINE HCL 2,6-DichlorophenylhydrazineHydrochloride> 2,6-Dichlorophenylhydrazine hydrochloride ISO 9001:2015 REACH 50709-36-9 Building Blocks Organic Building Blocks Hydrazines Nitrogen Compounds Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks Hydrazines Nitrogen Compounds Organic Building Blocks Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes API intermediates