2,6-Dichlorophenylhydrazine hydrochloride
- CAS No.
- 50709-36-9
- Chemical Name:
- 2,6-Dichlorophenylhydrazine hydrochloride
- Synonyms
- 2,6-DICHLOROPHENYLHYDRAZINE HCL;1,3-Dichloro-2-hydrazinobenzene;1-(2,6-DICHLOROPHENYL)HYDRAZINE HCL;6-Dichlorophenylhydrazine hydrochloride;2,6-Dichoropheynylhydrazine hydrochloride;2,6-DICHLOROPHENYLHYDRAZINE HYDROCHLORIDE;2,6-DichlorophenylhydrazineHydrochloride>1-(2,6-DICHLOROPHENYL)HYDRAZINE HYDROCHLORIDE;2,6-Dichlorophenylhydrazine hydrochloride 98%;2,6-Dichlorophenylhydrazine hydrochloride, 98+%
- CBNumber:
- CB3351853
- Molecular Formula:
- C6H7Cl3N2
- Molecular Weight:
- 213.49
- MDL Number:
- MFCD00012930
- MOL File:
- 50709-36-9.mol
- MSDS File:
- SDS
| Melting point | 225 °C (dec.)(lit.) |
|---|---|
| Boiling point | 346.49°C (rough estimate) |
| Density | 1.6100 (rough estimate) |
| refractive index | 1.6000 (estimate) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| form | powder to crystal |
| color | White to Light yellow to Light orange |
| BRN | 4569738 |
| InChI | 1S/C6H6Cl2N2.ClH/c7-4-2-1-3-5(8)6(4)10-9;/h1-3,10H,9H2;1H |
| InChIKey | CQNIYLLTIOPFCJ-UHFFFAOYSA-N |
| SMILES | Cl.NNc1c(Cl)cccc1Cl |
| CAS DataBase Reference | 50709-36-9(CAS DataBase Reference) |
| FDA UNII | MXU64S4WET |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H312+H332-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280-P301+P310-P302+P352+P312-P304+P340+P312-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | T,Xi,Xn | |||||||||
| Risk Statements | 20/21-25-36/37/38-20/21/22 | |||||||||
| Safety Statements | 26-36/37/39-45-22 | |||||||||
| RIDADR | UN 2811 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | Ⅲ | |||||||||
| HS Code | 29280000 | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
|||||||||
| Hazard Classifications | Acute Tox. 3 Oral Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
2,6-Dichlorophenylhydrazine hydrochloride price More Price(50)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 153419 | 2,6-Dichlorophenylhydrazine hydrochloride 98% | 50709-36-9 | 1g | $31.9 | 2023-01-07 | Buy |
| Sigma-Aldrich | 153419 | 2,6-Dichlorophenylhydrazine hydrochloride 98% | 50709-36-9 | 10g | $146 | 2023-01-07 | Buy |
| TCI Chemical | D2368 | 2,6-Dichlorophenylhydrazine Hydrochloride >98.0%(T) | 50709-36-9 | 5g | $74 | 2026-04-30 | Buy |
| Usbiological | 273470 | 2,6-Dichlorophenylhydrazine hydrochloride Asreported | 50709-36-9 | 10g | $352 | 2026-06-03 | Buy |
| Usbiological | 273470 | 2,6-Dichlorophenylhydrazine hydrochloride Asreported | 50709-36-9 | 25g | $485 | 2026-06-03 | Buy |
2,6-Dichlorophenylhydrazine hydrochloride Chemical Properties, Uses, Production
Chemical Properties
white to light yellow powder
Uses
(2,6-Dichlorophenyl)hydrazine Hydrochloride
Uses
2,6-Dichlorophenylhydrazine hydrochloride was used in the preparation of 1-(2,6-dichlorophenyl)-4-methyl-5-(4-methoxyphenyl)-1H-pyrazole-3-carboxylic acid, ethyl ester.
Synthesis
608-31-1
50709-36-9
General procedure for the synthesis of 2,6-dichlorophenylhydrazine hydrochloride from 2,6-dichloroaniline: 2,6-dichloroaniline (10.0 g, 61.72 mmol) was dissolved in an appropriate amount of solvent and cooled to -15 °C. At this temperature, aqueous sodium nitrite (5.11 g, 74.00 mmol) and hydrochloric acid were slowly added. The reaction mixture was stirred at 0-10°C for 15 minutes. The reaction mixture was filtered to remove insoluble matter and subsequently concentrated hydrochloric acid (34.7 g, 150 mmol) was added to the filtrate. The reaction system was maintained at -15 °C and stirring was continued for 30 min, after which the precipitate was collected by filtration to afford 15.00 g of the target product 2,6-dichlorophenylhydrazine hydrochloride. The product was characterized by 1H NMR (300 MHz, DMSO-d6): δ 7.18-7.28 (m, 1H), 7.39-7.52 (m, 2H), 10.30 (br s, 3H); the mass spectrum (MS) showed m/z: 176.90 (M)+.
References
[1] Patent: WO2013/186692, 2013, A1. Location in patent: Page/Page column 103; 104
2,6-Dichlorophenylhydrazine hydrochloride Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| 3B Pharmachem (Wuhan) International Co.,Ltd. | 18930552037 | 3bsc@sina.com | China | 15813 | 69 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Pure Chemistry Scientific Inc. | 001-857-928-2050 or 1-888-588-9418 | sales@chemreagents.com | United States | 10174 | 62 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Shanghai Longsheng chemical Co.,Ltd. | 58099637 13585536065 | sales@shlschem.com | China | 9880 | 59 |
View Latest Price from 2,6-Dichlorophenylhydrazine hydrochloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-03-20 | 2,6-Dichlorophenylhydrazine hydrochloride
50709-36-9
|
1KG | 99% | 20 mt | Hebei Chuanghai Biotechnology Co., Ltd | ||
![]() |
2019-07-06 | 2,6-Dichlorophenylhydrazine hydrochloride
50709-36-9
|
$1.00 | 1KG | 98% | 1kg,5kg,100kg | Career Henan Chemical Co |
-

- 2,6-Dichlorophenylhydrazine hydrochloride
50709-36-9
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-

- 2,6-Dichlorophenylhydrazine hydrochloride
50709-36-9
- $1.00
- 98%
- Career Henan Chemical Co
2,6-Dichlorophenylhydrazine hydrochloride Spectrum
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