ChemicalBook >> CAS DataBase List >>DIBUTYLBORON TRIFLUOROMETHANESULFONATE
DIBUTYLBORON TRIFLUOROMETHANESULFONATE
- CAS No.
- 60669-69-4
- Chemical Name:
- DIBUTYLBORON TRIFLUOROMETHANESULFONATE
- Synonyms
- DIBUTYLBORON TRIFLATE;DIBUTYLBORYL TRIFLUOROMETHANESULFONATE;dibutyl(((trifluoroMethyl)sulfonyl)oxy)borane;dibutylboryl triflate;Dibutylboryl trifluoromethanesulfonate solution;dibutylboron triflate solution;DIBUTYLBORON TRIFLUOROMETHANESULFONATE;dibutylboranyl trifluoromethanesulfonate;Di-Butyl Boron Triflate (1.0M in Toluene);Dibutylboron trifluoromethanesulfonate,98%
- CBNumber:
- CB3402304
- Molecular Formula:
- C9H18BF3O3S
- Molecular Weight:
- 274.11
- MDL Number:
- MFCD00009669
- MOL File:
- 60669-69-4.mol
- MSDS File:
- SDS
Last updated:2026-05-28 06:25:54
| Product description | Number | Pack Size | Price |
| Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution | FD75244 | 10ml | $263.2 |
| Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution | FD75244 | 25ml | $570.25 |
| Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution | FD75244 | 50ml | $965 |
| Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution | FD75244 | 100ml | $1579 |
| Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution | FD75244 | 200ml | $2808 |
| More product size | |||
| Boiling point | 37℃ (0.12 Torr) |
|---|---|
| Density | 1.271 g/mL at 25 °C |
| Flash point | 80 °F |
| storage temp. | 2-8°C |
| form | Solution |
| color | Clear light yellow to orange |
| BRN | 1968660 |
| InChI | InChI=1S/C9H18BF3O3S/c1-3-5-7-10(8-6-4-2)16-17(14,15)9(11,12)13/h3-8H2,1-2H3 |
| InChIKey | FAVAVMFXAKZTMV-UHFFFAOYSA-N |
| SMILES | B(CCCC)(CCCC)OS(=O)(=O)C(F)(F)F |
| UNSPSC Code | 12352106 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS05,GHS07,GHS08 |
|---|---|
| Signal word | Danger |
| Hazard statements | H226-H314-H335-H336-H351-H373 |
| Precautionary statements | P261-P280-P305+P351+P338-P310 |
| target organs | Central nervous system |
| PPE | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
| Hazard Codes | C,F+,F |
| Risk Statements | 12-22-34-66-67-40-10-37-65-48/20-11-63-19 |
| Safety Statements | 9-16-26-33-36/37/39-45-62 |
| RIDADR | UN 2924 3/PG 1 |
| WGK Germany | 3 |
| F | 1-10 |
| HazardClass | 3.2 |
| PackingGroup | III |
| HS Code | 29310099 |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Carc. 2 Eye Dam. 1 Flam. Liq. 3 Skin Corr. 1B STOT SE 3 |
DIBUTYLBORON TRIFLUOROMETHANESULFONATE price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | FD75244 | Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution | 60669-69-4 | 10ml | $263.2 | 2026-06-04 | Buy |
| Biosynth | FD75244 | Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution | 60669-69-4 | 25ml | $570.25 | 2026-06-04 | Buy |
| Biosynth | FD75244 | Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution | 60669-69-4 | 50ml | $965 | 2026-06-04 | Buy |
| Biosynth | FD75244 | Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution | 60669-69-4 | 100ml | $1579 | 2026-06-04 | Buy |
| Biosynth | FD75244 | Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution | 60669-69-4 | 200ml | $2808 | 2026-06-04 | Buy |
DIBUTYLBORON TRIFLUOROMETHANESULFONATE Chemical Properties,Uses,Production
Chemical Properties
clear light yellow to orange solution
Uses
Dibutylboryl trifluoromethanesulfonate may be used in the following studies:
- Stereo- and regio-selective synthesis of erythro aldols.
- As a promoter for the solution and polymer-supported trichloroacetimidate-based glycosylations.
- Synthesis of β-alkoxy carbonyl compounds via one-step Mukaiyama aldol-type reaction.
- Aldol-type cyclization for the stereoselective synthesis of cyclic ethers.
- As a reagent for the formation of boron enolates.
- As a complexation aid for the isolation of 1-acyldipyrromethanes.
- As a promoter in [1,2]-Wittig reaction between aldehydes and O-benzyl or O-allyl glycolate esters, creating two contiguous stereocenters (1,2-diol) in good yield without the need for strong base.
General Description
Dibutylboryl trifluoromethanesulfonate (Dibutylboron triflate, Bu2BOTf) is an organometallic reagent. It efficiently promotes the1,4-addition of benzylic and allylic organocopper reagents.
Purification Methods
Distil it in a vacuum under argon and store it under argon. It should be used within 2 weeks of purchase or after redistillation. Use a short path distillation system. It has IR bands in CCl4 at max 1405, 1380, 1320, 1200 and 1550cm1 , and 1 3C NMR (CDCl3) with at 118.1, 25.1, 21.5 and 13.6ppm. [Gage & Evans Org Synth 68 83 1990, Evans et al. J Am Chem Soc 103, 3099 1981.] TOXIC
Synthesis of DIBUTYLBORON TRIFLUOROMETHANESULFONATE from TRIBUTYLBORANE and Trifluoromethanesulfonic acid
DIBUTYLBORON TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Global( 85)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32998 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29766 | 58 |
| CONIER CHEM AND PHARMA LIMITED | sales@conier.com | China | 49906 | 58 | |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +86-189 4982 3763 | sales@tnjchem.com | China | 34526 | 58 |
| Wuxi Rejoys chemical Technology Co., Ltd. | 0510-86103381 | sales@rejoyschem.com | CHINA | 976 | 58 |
| GLR Innovations | -- | info@glrgroup.in | India | 4525 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 +8619957148339 | market18@leapchem.com | China | 24569 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57473 | 58 | |
| Shanghai Likang New Materials Co., Limited | +86-16631818819 +86-17736933208 | 3684455296@qq.com | China | 9287 | 58 |
| DAYANG CHEM (HANGZHOU) CO.,LTD | +86-88938639 +86-17705817739 | info@dycnchem.com | China | 53799 | 58 |
View Lastest Price from DIBUTYLBORON TRIFLUOROMETHANESULFONATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-09-03 | DIBUTYLBORON TRIFLUOROMETHANESULFONATE
60669-69-4
|
$1.80-3.60 | 1KG | 99% | 88kg | Career Henan Chemical Co |
-
- DIBUTYLBORON TRIFLUOROMETHANESULFONATE
60669-69-4
- $1.80-3.60
- 99%
- Career Henan Chemical Co
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Dibutylboron trifluoromethanesulfonate, 1M solution in diethylether
dibutylboron triflate solution
TRIFLUOROMETHANESULFONIC ACID ANHYDRIDE WITH DIBUTYLBORINIC ACID)
Dibutylboryl trifluoromethanesulfonate - 1M dichloromethane solution
dibutylboryl triflate
Dibutylboron trifluoromethanesulfonate,98%
Dibutylboryl trifluoromethanesulfonate solution,Dibutylboron triflate solution
Dibutylboron trifluoroMethanesulfonate, 1M solution in diethyl ether, AcroSeal
Dibutylboryl trifluoroMethanesulfonate solution 1.0 M in Methylene chloride
dibutylboranyl trifluoromethanesulfonate
DIBUTYLBORON TRIFLUOROMETHANESULFONATE
dibutylboryl trifluoromethanesulfonate sol.,~1 M in diet.E.
DIBUTYLBORON TRIFLATE, 1.0M SOLUTION IN DIETHYL ETHER
DIBUTYLBORON TRIFLATE, 1.0M SOLUTION IN DICHLOROMETHANE
DIBUTYLBORYL TRIFLUOROMETHANESULF. SOL., ~1M IN DICHLOROMET.
Dibutylboron trifluoromethanesulfonate, 1M sol. in dichloromethane
Methanesulfonic acid, 1,1,1-trifluoro-, anhydride with B,B-dibutylborinic acid
Borane,dibutyl[[(trifluoromethyl)sulfonyl]oxy]-
Dibutylboryl trifluoromethanesulphonate solution, 1.0 M in methylene chloride
Di-Butyl Boron Triflate (1.0M in Toluene)
Dibutylboryl trifluoromethanesulfonate 1.0M in M.D.C
dibutyl(((trifluoroMethyl)sulfonyl)oxy)borane
DIBUTYLBORON TRIFLATE
DIBUTYLBORYL TRIFLUOROMETHANESULFONATE
Dibutylboryl trifluoromethanesulfonate solution
60669-69-4
C9H18BF3O3S
CF3SO3BCH23CH32
C-C Bond Formation
Boronic Acids and Derivatives
Synthetic Reagents
Others
Organometallic Reagents
