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Tributylborane

CAS No.
122-56-5
Chemical Name:
Tributylborane
Synonyms
Tributylboron;Boronbutoxide;Tributylborine;tributyl-boran;Tributylborane;Borane,tributyl-;TRI-N-BUTYLBORON;Tri-n-butylborane;Borane, tributyl-;tri-n-butylborane,
CBNumber:
CB1725849
Molecular Formula:
C12H27B
Molecular Weight:
182.15
MDL Number:
MFCD00009423
MOL File:
122-56-5.mol
MSDS File:
SDS
Last updated:2026-09-12 18:50:04

Tributylborane Properties

Melting point -34 °C
Boiling point 109 °C20 mm Hg(lit.)
Density 0.834 g/mL at 25 °C
refractive index 1.4285
Flash point 1 °F
storage temp. Flammables area
solubility Benzene, Tetrahydrofuran
form Solution
color Clear colorless to light yellow
Water Solubility Not miscible or difficult to mix with water.
Sensitive Air Sensitive
InChI 1S/C12H27B/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
InChIKey CMHHITPYCHHOGT-UHFFFAOYSA-N
SMILES CCCCB(CCCC)CCCC
CAS DataBase Reference 122-56-5
EWG's Food Scores 1
EPA Substance Registry System Borane, tributyl- (122-56-5)
UNSPSC Code 12352001
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
Signal word  Danger
Hazard statements  H250-H314-H318
Precautionary statements  P210-P222-P231+P232-P233-P280-P260-P264-P302+P334-P370+P378-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P305+P351+P338-P405-P501
PPE Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)
Hazard Codes  F,Xn,C
Risk Statements  17-34-40-36/37/38-20/21/22-11-22-19-37
Safety Statements  7-23-26-36/37/39-43-45-16
RIDADR  UN 2845 4.2/PG 1
WGK Germany  1
RTECS  ED1850000
TSCA  TSCA listed
HazardClass  4.2
PackingGroup  I
HS Code  29310099
Storage Class 4.2 - Pyrophoric and self-heating hazardous materials
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Pyr. Liq. 1
Skin Corr. 1B
NFPA 704
4
3 1

Tributylborane price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 297976 Tributylborane solution 1.0M in diethyl ether 122-56-5 100ml $229 2023-01-07 Buy
Sigma-Aldrich 179906 Tributylborane solution 1.0 M in THF 122-56-5 100ml $154 2022-05-15 Buy
AHH MT-60032 Tri-n-butylboron 97% 100g $280 2026-05-26 Buy
Sigma-Aldrich 298425 Tributylborane 122-56-5 50g $329 2023-06-20 Buy
TRC T773385 Tributylborane(1.0 MinTHF) 122-56-5 1g $45 2021-12-16 Buy
Product number Packaging Price Buy
297976 100ml $229 Buy
179906 100ml $154 Buy
MT-60032 100g $280 Buy
298425 50g $329 Buy
T773385 1g $45 Buy

Tributylborane Chemical Properties,Uses,Production

Chemical Properties

Colorless pyrophoric fluid. Insoluble in water; soluble in most organic solvents.

Uses

Petrochemical industry, organic reactions, catalyst.

Uses

Tributylborane is a reducing agent used in the controlled radical polymerization of alkyl acrylates.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 427, 1986 DOI: 10.1021/jo00354a002
Tetrahedron Letters, 26, p. 4311, 1985 DOI: 10.1016/S0040-4039(00)98721-5

Hazard

Flammable, dangerous fire risk, store and use in inert atmosphere, ignites spontaneously in air.

reaction suitability

reagent type: reductant

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. A very dangerous fire hazard when exposed to heat or flame; can ignite spontaneously. When heated to decomposition it emits acrid smoke and irritating fumes. See also BORANES.

Tributylborane Preparation Products And Raw materials

Tributylborane Suppliers

Global( 70)Suppliers
Supplier Tel Email Country ProdList Advantage
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Syntechem Co.,Ltd info@syntechem.com China 12973 57
Thermo Fisher Scientific 800-810-5118 cnchemical@thermofisher.com China 17752 75
TIANJIN SPRING PHARMA SCIENCE CO., LTD. 0086-22-60330256 China 83 58
Wuxi Zhongkun Biochemical Technology Co., Ltd. 0510-85629785 18013409632; sales@reading-chemicals.com China 15165 58
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Xishi Chemical (Shanghai) Co., Ltd. 021-60499358 13661956116 info@cs-pharm.com China 227 58

View Lastest Price from Tributylborane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TRIBUTYLBORANE pictures 2020-03-06 TRIBUTYLBORANE
122-56-5
$1.00 1KG 99% 200kgs Career Henan Chemical Co
Tributylboron TRI-N-BUTYLBORON Borane, tributyl- Tributylborane, 1.0 M solution in THF, SpcSeal Tributylborane solution 1.0 M in THF Tributylborane, 1M Solution in Tetrahydrofuran Borane,tributyl- tributyl-boran Tributylborine Tri-n-butylborane tri-n-butylborane, tri-n-butylborane,tnbb Boronbutoxide Tributylborane solution TRIBUTYLBORANE, 1.0M SOLUTION IN DIETHYL ETHER TRIBUTYLBORANE, 1.0M SOLUTION IN TETRAHY DROFURAN 1.0Msolutionintetrahydrofuran Tributylborane, 1M solution in THF Tributylborane1M solution in THFAcroSeal§3 Tributylborane,98% Tributylborane, 1M solution in THF, AcroSeal Tri-n-butylborane, 1M soln. in THF Tributylborane (1.0M in THF) TIANFU CHEM-- TRIBUTYLBORANE Tributylborane 122-56-5 C12H27B CH3CH233B Boranes Synthetic Reagents Reduction Boranes Reduction Synthetic Reagents