Methyl 1-methylpyrrole-2-carboxylate
- CAS No.
- 37619-24-2
- Chemical Name:
- Methyl 1-methylpyrrole-2-carboxylate
- Synonyms
- RARECHEM AL BF 0084;2-Methoxycarbonyl-1-methylpyrrole;Methyl 1-methylpyrrole-2-carboxylate;methyl N-methylpyrrole-2-carboxylate;Methyl-4-methylpyrrole-2-carboxylate;Methyl 1-Methyl-2-pyrrolecarboxylate;Methyl1-methylpyrrole-2-carboxylate,98%;METHYL 1-METHYL-1H-PYRROLE-2-CARBOXYLATE;1-METHYLPYRROLE-2-CARBOXYLIC ACID METHYL ESTER;1-Methyl-1H-pyrrole-2-carboxylic acid methyl ester
- CBNumber:
- CB3407697
- Molecular Formula:
- C7H9NO2
- Molecular Weight:
- 139.15
- MDL Number:
- MFCD00052747
- MOL File:
- 37619-24-2.mol
- MSDS File:
- SDS
| Melting point | 80 °C (sublm)(Press: 0.2 Torr) |
|---|---|
| Boiling point | 96-98°C 15mm |
| Density | 1.07±0.1 g/cm3(Predicted) |
| refractive index | 1.5220 |
| Flash point | 96-98°C/15mm |
| storage temp. | Sealed in dry,Room Temperature |
| pka | -7.04±0.70(Predicted) |
| Appearance | Light yellow to brown Liquid |
| Water Solubility | Slightly soluble in water. |
| BRN | 116477 |
| CAS DataBase Reference | 37619-24-2(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P305+P351+P338 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 2933998090 | |||||||||
| NFPA 704 |
|
Methyl 1-methylpyrrole-2-carboxylate price More Price(51)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| AstaTech | 64035 | METHYL 1-METHYLPYRROLE-2-CARBOXYLATE 97% | 37619-24-2 | 5G | $58 | 2026-04-30 | Buy |
| AstaTech | 64035 | METHYL 1-METHYLPYRROLE-2-CARBOXYLATE 97% | 37619-24-2 | 25G | $190 | 2026-04-30 | Buy |
| AstaTech | 64035 | METHYL 1-METHYLPYRROLE-2-CARBOXYLATE 97% | 37619-24-2 | 100G | $700 | 2026-04-30 | Buy |
| Biosynth | MBA61924 | Methyl 1-methyl-1H-pyrrole-2-carboxylate | 37619-24-2 | 25g | $1215.75 | 2026-06-04 | Buy |
| Biosynth | MBA61924 | Methyl 1-methyl-1H-pyrrole-2-carboxylate | 37619-24-2 | 50g | $1691.5 | 2026-06-04 | Buy |
Methyl 1-methylpyrrole-2-carboxylate Chemical Properties,Uses,Production
Uses
Methyl 1-methylpyrrole-2-carboxylate is used as chemical and organic Intermediates.
Synthesis
1193-62-0
74-88-4
37619-24-2
Methyl-1H-pyrrole-2-carboxylate (10 g, 79.9 mmol) was dissolved in anhydrous THF (200 mL) at 0 °C and NaH (3.52 g, 60% w/w, 87.9 mmol) was slowly added. The reaction mixture was stirred at 20 °C for 30 min before CH3I (13.62 g, 95.9 mmol) was added dropwise. The reaction was continued to be stirred at 20 °C for 17 hours. After completion of the reaction, the reaction was quenched by slowly pouring the mixture into aqueous NH4Cl (200 mL). The aqueous phase was extracted with EtOAc (200 mL x 2), the organic layers were combined and washed with brine (150 mL), dried over anhydrous Na2SO4, filtered and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: EtOAc/petroleum ether=1/20) to afford methyl 1-methyl-1H-pyrrole-2-carboxylate (9.88 g, 71 mmol, 89% yield) as a yellow oil. Mass spectrum (EI+, m/z): 140.1 [M+H]+.
References
[1] Organic Letters, 2015, vol. 17, # 11, p. 2652 - 2655
[2] Patent: WO2018/89493, 2018, A1. Location in patent: Paragraph 00214
[3] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 11, p. 3219 - 3223
Methyl 1-methylpyrrole-2-carboxylate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| PharmaBlock Sciences (Nanjing),Inc. | 025-86918202 4000255188 | sales@pharmablock.com | China | 5000 | 55 |
| ChemFuture PharmaTech (Jiangsu) Ltd | 5108538618 | suger.wang@chemfuture.com | China | 832 | 65 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11777 | 60 |
| Shangchem Co., Ltd. | +86-21-68182121 | China | 881 | 52 | |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
View Lastest Price from Methyl 1-methylpyrrole-2-carboxylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-12-26 | METHYL 1-METHYLPYRROLE-2-CARBOXYLATE
37619-24-2
|
$9.80 | 1g | ≥99% | 100kg | Career Henan Chemical Co |
-
- METHYL 1-METHYLPYRROLE-2-CARBOXYLATE
37619-24-2
- $9.80
- ≥99%
- Career Henan Chemical Co
37619-24-2(Methyl 1-methylpyrrole-2-carboxylate)Related Search:
1of4
