(4-BROMO-2-THIENYL)METHANOL
- CAS No.
- 79757-77-0
- Chemical Name:
- (4-BROMO-2-THIENYL)METHANOL
- Synonyms
- RARECHEM AL BD 0179;(4-BroMothien-2-yl)Methanol;(4-BROMO-2-THIENYL)METHANOL;4-Bromo-2-thiophenemethanol;4-Bromothiophene-2-methanol;2-Thiophenemethanol, 4-bromo-;4-BROMO-2-(HYDROXYMETHYL)THIOPHENE
- CBNumber:
- CB3493030
- Molecular Formula:
- C5H5BrOS
- Molecular Weight:
- 193.06
- MDL Number:
- MFCD04115392
- MOL File:
- 79757-77-0.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 4-Bromo-2-thiophenemethanol >98.0%(GC) | B5060 | 1g | $37 |
| 4-Bromo-2-thiophenemethanol >98.0%(GC) | B5060 | 5g | $66 |
| (4-Bromo-2-thienyl)methanol 98% | OR900842 | 5g | $21 |
| (4-Bromo-2-thienyl)methanol 98% | OR900842 | 25g | $59 |
| (4-Bromo-2-thienyl)methanol 98% | OR900842 | 100g | $226 |
| More product size | |||
| Melting point | 30 °C |
|---|---|
| Boiling point | 271.5±25.0 °C(Predicted) |
| Density | 1.772±0.06 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
| solubility | soluble in Methanol |
| pka | 13.50±0.10(Predicted) |
| form | powder to lump |
| color | White to Orange to Green |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319-H332-H335 | |||||||||
| Precautionary statements | P280-P305+P351+P338-P310 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22-36/37/38-41-22 | |||||||||
| Safety Statements | 26-36/37/39-39 | |||||||||
| HS Code | 2934999090 | |||||||||
| NFPA 704 |
|
(4-BROMO-2-THIENYL)METHANOL price More Price(75)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | B5060 | 4-Bromo-2-thiophenemethanol >98.0%(GC) | 79757-77-0 | 1g | $37 | 2026-04-30 | Buy |
| TCI Chemical | B5060 | 4-Bromo-2-thiophenemethanol >98.0%(GC) | 79757-77-0 | 5g | $66 | 2026-04-30 | Buy |
| Apolloscientific | OR900842 | (4-Bromo-2-thienyl)methanol 98% | 79757-77-0 | 5g | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR900842 | (4-Bromo-2-thienyl)methanol 98% | 79757-77-0 | 25g | $59 | 2026-06-04 | Buy |
| Apolloscientific | OR900842 | (4-Bromo-2-thienyl)methanol 98% | 79757-77-0 | 100g | $226 | 2026-06-04 | Buy |
(4-BROMO-2-THIENYL)METHANOL Chemical Properties,Uses,Production
Synthesis
18791-75-8
79757-77-0
Step I: Sodium borohydride (5.20 g, 0.137 mol) was added batchwise to a solution of 4-bromo-2-thiophenecarboxaldehyde (25.0 g, 0.131 mol) in anhydrous tetrahydrofuran (400 mL). The reaction mixture was stirred at room temperature for 1.5 hours. Upon completion of the reaction, saturated ammonium chloride solution (100 mL) was slowly added to quench the reaction. Subsequently, the reaction mixture was extracted with ethyl acetate and the organic phases were combined and washed with saturated brine. The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to afford (4-bromo-2-thienyl)methanol (25.02 g, 99% yield), and the product could be used for subsequent reactions without further purification. NMR hydrogen spectrum (400 MHz, CDCl3): δ = 1.93 (broad single peak, 1H), 4.79 (single peak, 2H), 6.93 (single peak, 1H), 7.18 (double peak, J = 1.5 Hz, 1H).
References
[1] Journal of the American Chemical Society, 2007, vol. 129, # 24, p. 7523 - 7530
[2] Bioorganic and Medicinal Chemistry Letters, 2012, vol. 22, # 4, p. 1788 - 1792
[3] Synthesis, 1983, # 1, p. 73 - 75
[4] Patent: WO2013/110643, 2013, A1. Location in patent: Paragraph 00212; 00213
[5] Bioorganic and Medicinal Chemistry, 2008, vol. 16, # 4, p. 1992 - 2010
(4-BROMO-2-THIENYL)METHANOL Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52704 | 58 |
| Zhejiang J&C Biological Technology Co.,Limited | +1-2135480471 +1-2135480471; | sales@sarms4muscle.com | China | 10457 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 24597 | 58 |
| Shanghai Scochem Technology Co., Ltd | +86-021-33758897 +86-13701882790 | sales@scochem.com | China | 1977 | 58 |
View Lastest Price from (4-BROMO-2-THIENYL)METHANOL manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-12-27 | (4-BROMO-2-THIENYL)METHANOL
79757-77-0
|
$1.00 | 1KG | 99% | 200kg | Career Henan Chemical Co |
-
- (4-BROMO-2-THIENYL)METHANOL
79757-77-0
- $1.00
- 99%
- Career Henan Chemical Co
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