4-BUTOXY-3-FLUOROPHENYLBORONIC ACID
- CAS No.
- 156487-13-7
- Chemical Name:
- 4-BUTOXY-3-FLUOROPHENYLBORONIC ACID
- Synonyms
- Boronic acid, B-(4-butoxy-3-fluorophenyl)-
- CBNumber:
- CB3498525
- Molecular Formula:
- C10H14BFO3
- Molecular Weight:
- 212.03
- MDL Number:
- MFCD06411286
- MOL File:
- 156487-13-7.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 4-Butoxy-3-fluorophenylboronic acid 95% | PC412067 | 250mg | $25 |
| 4-Butoxy-3-fluorophenylboronic acid 95% | PC412067 | 1g | $30 |
| 4-Butoxy-3-fluorophenylboronic acid 95% | PC412067 | 5g | $64 |
| 4-Butoxy-3-fluorophenylboronic acid 95% | PC412067 | 250mg | $25 |
| 4-Butoxy-3-fluorophenylboronic acid 95% | PC412067 | 1g | $30 |
| Melting point | 91-96 °C(lit.) |
|---|---|
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | solid |
| Appearance | White to off-white Solid |
| InChI | 1S/C10H14BFO3/c1-2-3-6-15-10-5-4-8(11(13)14)7-9(10)12/h4-5,7,13-14H,2-3,6H2,1H3 |
| InChIKey | JVHCUZXLXOUYHX-UHFFFAOYSA-N |
| SMILES | CCCCOc1ccc(cc1F)B(O)O |
| UNSPSC Code | 12352103 |
SAFETY
Risk and Safety Statements
| PPE | Eyeshields, Gloves, type N95 (US) |
|---|---|
| WGK Germany | 3 |
| HS Code | 2931900090 |
| Storage Class | 13 - Non Combustible Solids |
4-BUTOXY-3-FLUOROPHENYLBORONIC ACID price More Price(25)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | PC412067 | 4-Butoxy-3-fluorophenylboronic acid 95% | 156487-13-7 | 250mg | $25 | 2026-06-04 | Buy |
| Apolloscientific | PC412067 | 4-Butoxy-3-fluorophenylboronic acid 95% | 156487-13-7 | 1g | $30 | 2026-06-04 | Buy |
| Apolloscientific | PC412067 | 4-Butoxy-3-fluorophenylboronic acid 95% | 156487-13-7 | 5g | $64 | 2026-06-04 | Buy |
| Apolloscientific | PC412067 | 4-Butoxy-3-fluorophenylboronic acid 95% | 156487-13-7 | 250mg | $25 | 2026-06-04 | Buy |
| Apolloscientific | PC412067 | 4-Butoxy-3-fluorophenylboronic acid 95% | 156487-13-7 | 1g | $30 | 2026-06-04 | Buy |
4-BUTOXY-3-FLUOROPHENYLBORONIC ACID Chemical Properties,Uses,Production
Synthesis
121-43-7
54509-63-6
156487-13-7
4-Butoxy-3-fluorophenylboronic acid (T-9) was synthesized as follows: 4-bromo-1-butoxy-2-fluorobenzene (T-8) (97.5 g) prepared in the previous step was dissolved in dry tetrahydrofuran (THF) (500 ml) and the solution was cooled to -70 °C. Under nitrogen protection, n-butyllithium (n-BuLi) (241 ml) was slowly added dropwise with continuous stirring for 2 h at a maintained temperature of -70°C. Subsequently, a dry THF solution of trimethyl borate (62.4 g) was slowly added dropwise to the reaction system at the same temperature. The reaction mixture was gradually warmed to room temperature and stirring was continued for 16 hours. After completion of the reaction, 2N hydrochloric acid (HCl) (200 ml) was added to the reaction mixture for acidification. The mixture was extracted with toluene and after separating the organic layer, it was washed sequentially with water and saturated saline and finally dried with anhydrous magnesium sulfate. The organic phase was concentrated under reduced pressure to give a light brown solid product. Purification by recrystallization (solvent ratio: heptane/toluene=4:1, v/v) gave the target compound 4-butoxy-3-fluorophenylboronic acid (T-9) as a colorless powder (54.8 g) in 66% yield.
References
[1] Patent: EP2399896, 2011, A1. Location in patent: Page/Page column 38
4-BUTOXY-3-FLUOROPHENYLBORONIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
4-BUTOXY-3-FLUOROPHENYLBORONIC ACID Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Alfa Chemistry | +1-5166625404; | Info@alfa-chemistry.com | United States | 20405 | 58 |
| Shanghai Scochem Technology Co., Ltd | +86-021-33758897 +86-13701882790 | sales@scochem.com | China | 1977 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| Allfluoro pharmaceutical co. ltd. | +86-400-0216110 +86-15958047586 | sales@allfluoro.com | China | 11385 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44802 | 61 |
View Lastest Price from 4-BUTOXY-3-FLUOROPHENYLBORONIC ACID manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-15 | 4-BUTOXY-3-FLUOROPHENYLBORONIC ACID
156487-13-7
|
$1.00 | 1KG | 99.0% | 100kg | Career Henan Chemical Co |
-
- 4-BUTOXY-3-FLUOROPHENYLBORONIC ACID
156487-13-7
- $1.00
- 99.0%
- Career Henan Chemical Co
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