METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE
- CAS No.
- 668262-52-0
- Chemical Name:
- METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE
- Synonyms
- -5-chlorobenzoate;2-(bromethyl)-5-chloromethyl benzoate;METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE;2-BROMOMETHYL-5-CHLORO-BENZOIC ACID METHYL ESTER;2-carboxy-4-chloro-broMoMethylbenzene Methyl ester;Benzoic acid, 2-(bromomethyl)-5-chloro-, methyl ester
- CBNumber:
- CB3762945
- Molecular Formula:
- C9H8BrClO2
- Molecular Weight:
- 263.52
- MDL Number:
- MFCD06804577
- MOL File:
- 668262-52-0.mol
| Product description | Number | Pack Size | Price |
| Methyl2-(bromomethyl)-5-chlorobenzoate | OR400300 | 250mg | $58 |
| Methyl 2-(bromomethyl)-5-chlorobenzoate | 2723-D-00 | 250mg | $64 |
| Methyl2-(bromomethyl)-5-chlorobenzoate | OR400300 | 1g | $145 |
| Methyl 2-(bromomethyl)-5-chlorobenzoate | 2723-D-00 | 1g | $160 |
| Methyl 2-(bromomethyl)-5-chlorobenzoate 95+% | 119369 | 250mg | $231 |
| More product size | |||
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302+H332-H315-H319-H335 |
| Precautionary statements | P260-P280-P312 |
| HS Code | 2916310090 |
METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE price More Price(21)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | OR400300 | Methyl2-(bromomethyl)-5-chlorobenzoate | 668262-52-0 | 250mg | $58 | 2021-12-16 | Buy |
| SynQuest Laboratories | 2723-D-00 | Methyl 2-(bromomethyl)-5-chlorobenzoate | 668262-52-0 | 250mg | $64 | 2021-12-16 | Buy |
| Apolloscientific | OR400300 | Methyl2-(bromomethyl)-5-chlorobenzoate | 668262-52-0 | 1g | $145 | 2021-12-16 | Buy |
| SynQuest Laboratories | 2723-D-00 | Methyl 2-(bromomethyl)-5-chlorobenzoate | 668262-52-0 | 1g | $160 | 2021-12-16 | Buy |
| Matrix Scientific | 119369 | Methyl 2-(bromomethyl)-5-chlorobenzoate 95+% | 668262-52-0 | 250mg | $231 | 2021-12-16 | Buy |
METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE Chemical Properties,Uses,Production
Synthesis
99585-13-4
668262-52-0
General procedure for the synthesis of methyl 2-(bromomethyl)-5-chlorobenzoate from methyl 2-methyl-5-chlorobenzoate: methyl 5-chloro-2-methylbenzoate (10.0 g, 54 mmol), N-bromosuccinimide (NBS, 10.6 g, 59.5 mmol), and azobisisobutyronitrile (AIBN, 200 mg) were dissolved in 1,2-dichloroethane ( 300 mL). The reaction mixture was irradiated and stirred for 2 h under photocatalytic conditions using [PHOTOLAMP]. Upon completion of the reaction, the mixture was cooled to room temperature and concentrated under reduced pressure. The residue was purified by silica gel column chromatography with heptane/dichloromethane as eluent (gradient elution: 9:1, 4:1, 1:1) to afford 11.8 g of methyl 2-(bromomethyl)-5-chlorobenzoate (83% yield). The product was characterized by 1H NMR (300 MHz, CDCl3): δ 7.98 (d, J = 2.1 Hz, 1H), 7.49 (dd, J = 2.2, 8.2 Hz, 1H), 7.43 (d, J = 8.2 Hz, 1H), 4.93 (s, 2H), 3.97 (s, 3H).
References
[1] Patent: WO2004/18414, 2004, A2. Location in patent: Page 112
[2] Patent: WO2005/21508, 2005, A1. Location in patent: Page/Page column 148
[3] Israel Journal of Chemistry, 1971, vol. 9, p. 111 - 118
[4] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 5, p. 1628 - 1631
[5] Bioorganic and Medicinal Chemistry Letters, 2013, vol. 23, # 1, p. 360 - 365
METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29640 | 60 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29794 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14307 | 58 |
| Zhejiang J&C Biological Technology Co.,Limited | +1-2135480471 +1-2135480471; | sales@sarms4muscle.com | China | 10473 | 58 |
| Changzhou Anxuan Chemical Co., Ltd | +86-0519-89882563 +86-18961279162 | andy@anxuanchem.com | China | 4327 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
| Aromsyn Co., Ltd. | +86-0571-85585865 +8613336024896 | CB@aromsyn.com | China | 19183 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 52923 | 58 |
View Lastest Price from METHYL 2-BROMOMETHYL-5-CHLORO-BENZOATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-10 | Methyl 2-(bromomethyl)-5-chlorobenzoate
668262-52-0
|
US $1.00 / KG | 1KG | ≥98% | 20 tons | Career Henan Chemical Co |
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- Methyl 2-(bromomethyl)-5-chlorobenzoate
668262-52-0
- US $1.00 / KG
- ≥98%
- Career Henan Chemical Co
