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(3-acrylamidophenyl)boronic acid

CAS No.
99349-68-5
Chemical Name:
(3-acrylamidophenyl)boronic acid
Synonyms
(m-AcryL;amidophenyL;3-(Propenamido);Boronic acid acrylamide;Phenylboronate acrylamide;(3-Acrylamidophenyl)boronicaci;3-Acrylamidobenzeneboronic Acid;(M-ACRYLAMIDOPHENYL)BORONIC ACID;3-(Propenamido)phenylboronic acid;3-(AcrylaMido)phenylboronic acid 98%
CBNumber:
CB3837283
Molecular Formula:
C9H10BNO3
Molecular Weight:
190.99
MDL Number:
MFCD09025755
MOL File:
99349-68-5.mol
MSDS File:
SDS
Last updated:2025-07-29 17:05:30
Product description Number Pack Size Price
3-(Acrylamido)phenylboronic acid 98% 771465 1g $151
3-Acrylamidophenylboronic Acid (contains varying amounts of Anhydride) A3199 1g $128
3-Acrylamidophenylboronic Acid (contains varying amounts of Anhydride) A3199 5g $379
3-(Acrylamido)phenylboronic acid A191315 500mg $100
3-(Acrylamido)phenylboronic acid A191315 2.5g $330
More product size

(3-acrylamidophenyl)boronic acid Properties

Melting point 129-146°C
Density 1.22±0.1 g/cm3(Predicted)
storage temp. 2-8°C
form powder to crystal
pka 8.05±0.10(Predicted)
color White to Amber
UNSPSC Code 12162002
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332
Precautionary statements  P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
Hazard Codes  Xn
Risk Statements  22
WGK Germany  3
HS Code  2931900090
NFPA 704
0
2 0

(3-acrylamidophenyl)boronic acid price More Price(36)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 771465 3-(Acrylamido)phenylboronic acid 98% 99349-68-5 1g $151 2025-07-31 Buy
TCI Chemical A3199 3-Acrylamidophenylboronic Acid (contains varying amounts of Anhydride) 99349-68-5 1g $128 2025-07-31 Buy
TCI Chemical A3199 3-Acrylamidophenylboronic Acid (contains varying amounts of Anhydride) 99349-68-5 5g $379 2025-07-31 Buy
TRC A191315 3-(Acrylamido)phenylboronic acid 99349-68-5 500mg $100 2021-12-16 Buy
TRC A191315 3-(Acrylamido)phenylboronic acid 99349-68-5 2.5g $330 2021-12-16 Buy
Product number Packaging Price Buy
771465 1g $151 Buy
A3199 1g $128 Buy
A3199 5g $379 Buy
A191315 500mg $100 Buy
A191315 2.5g $330 Buy

(3-acrylamidophenyl)boronic acid Chemical Properties,Uses,Production

Uses

suzuki reaction

Uses

This acrylamide monomer contains a glucose sensitive boronic acid commonly used for intelligent polymers solutions and gels;for drug delivery systems;sensors;actuator systems;and bioreactors.

Synthesis

3-Aminobenzeneboronic acid

30418-59-8

Acryloyl chloride

814-68-6

(M-ACRYLAMIDOPHENYL)BORONIC ACID

99349-68-5

General procedure for the synthesis of 3-acrylamidophenylboronic acid from 3-aminophenylboronic acid and acryloyl chloride: 3-aminophenylboronic acid (0.566 g, 3.65 mmol) and Na2CO3 (0.67 g, 80.3 mmol) were added to 20 mL of a 1:1 (v/v) solvent mixture of tetrahydrofuran and water and the mixture was cooled to 0 °C. Acryloyl chloride (960 mg, 8.06 mmol) was slowly added dropwise under stirring conditions. After the dropwise addition, the mixture was allowed to warm up naturally to room temperature and stirring was continued for 2 hours. Upon completion of the reaction, 10 mL of water was added to terminate the reaction, followed by extraction of the reaction mixture with ethyl acetate (20 mL x 3). The organic phases were combined, washed with saturated NaCl solution (10 mL) and finally the organic layer was dried with anhydrous Na2SO4. After concentrating the organic layer, it was purified by column chromatography to give the light yellow solid product 3-acrylamidophenylboronic acid (0.32 g, 40.1% yield).

References

[1] Journal of Medicinal Chemistry, 2017, vol. 60, # 11, p. 4636 - 4656
[2] Soft Matter, 2014, vol. 10, # 6, p. 911 - 920
[3] Journal of the American Chemical Society, 2011, vol. 133, # 49, p. 19832 - 19838
[4] Patent: CN104945411, 2018, B. Location in patent: Paragraph 0077; 0078; 0079
[5] New Journal of Chemistry, 2012, vol. 36, # 2, p. 438 - 451

(3-acrylamidophenyl)boronic acid Preparation Products And Raw materials

Global( 162)Suppliers
Supplier Tel Email Country ProdList Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
+86-13017695106 +86-13676922317 jiuyitime@fdachem.com China 16516 58
Capot Chemical Co.,Ltd.
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Shanghai Daken Advanced Materials Co.,Ltd
+86-2158073036 info@dakenam.com China 13445 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 33024 60
career henan chemical co
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Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
Wuhan Chemwish Technology Co., Ltd
027-67849912 sales@chemwish.com CHINA 10821 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9636 58

View Lastest Price from (3-acrylamidophenyl)boronic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(3-acrylamidophenyl)boronic acid pictures 2025-10-29 (3-acrylamidophenyl)boronic acid
99349-68-5
US $0.00 / kg 20kg 99% 20 tons Qingdao RENAS Polymer Material Co., Ltd.
3-Acrylamidophenylboronic acid pictures 2025-10-13 3-Acrylamidophenylboronic acid
99349-68-5
US $2.00-6.00 / kg 1kg 99% 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
(M-ACRYLAMIDOPHENYL)BORONIC ACID pictures 2025-07-25 (M-ACRYLAMIDOPHENYL)BORONIC ACID
99349-68-5
US $0.00 / kg 1kg 99% 10000KGS Shaanxi Dideu New Materials Co. Ltd

(3-acrylamidophenyl)boronic acid Spectrum

(M-ACRYLAMIDOPHENYL)BORONIC ACID 3-(Acrylamido)phenylboronic acid, 3-[(Prop-2-enoyl)amino]benzeneboronic acid 3-(Acryloylamino)benzeneboronic acid 3-(AcrylaMido)phenylboronic acid 98% 3-(Propenamido)phenylboronic acid Boronic acid acrylamide N-Acryloyl-3-aminophenylboronic acid Phenylboronate acrylamide Boronic acid, B-[3-[(1-oxo-2-propen-1-yl)amino]phenyl]- N-Acryloyl-m-aminophenylboronic acid 3-Acrylamidophenylboronic Acid (contains varying amounts of Anhydride) 3-(Propenamido) (m-AcryL amidophenyL 3-Acrylamidobenzeneboronic Acid (3-Acrylamidophenyl)boronicaci 99349-68-5 9934-68-5 C9H10BNO3 Aryl Organoborons