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rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride

CAS No.
100163-29-9
Chemical Name:
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
Synonyms
Rac-EthyL;enebis(tetrahydroindenyL;(ethylene bis-tetrahydroindenyl)zirconium dichloride;Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride;RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM;rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichl...;Rac-[ethylenebis(4,5,6,7-tetrahydroindenyl)]zirconium dichloride;(S)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;(R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE;RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE
CBNumber:
CB4202015
Molecular Formula:
C20H24Cl2Zr
Molecular Weight:
426.53
MDL Number:
MFCD00672123
MOL File:
100163-29-9.mol
MSDS File:
SDS
Last updated:2026-05-28 02:11:55

rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Properties

Melting point 267-271 °C(lit.)
form Powder
color white to pale yellow
Sensitive moisture sensitive
InChI InChI=1S/C20H24.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12H,1-8,13-14H2;2*1H;/q;;;+2/p-2
InChIKey AKXWJOYQORUUHS-UHFFFAOYSA-L
SMILES [C]12[C]([CH][CH][C]1CCCC2)CC[C]1[CH][CH][C]2CCCC[C]12.[Zr](Cl)Cl |^1:0,1,2,3,4,11,12,13,14,19|
UNSPSC Code 12161600
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  C,Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39-45-36
RIDADR  UN 3261 8/PG 2
WGK Germany  3
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 532126 Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV) 97% 100163-29-9 500mg $450 2026-04-30 Buy
Strem Chemicals 40-1400 rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride 100163-29-9 100mg $140 2026-04-30 Buy
Strem Chemicals 40-1400 rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride 100163-29-9 500mg $445 2026-04-30 Buy
TRC E923668 Rac-Ethylenebis(tetrahydroindenyl)zirconiumDichloride 100163-29-9 10mg $55 2021-12-16 Buy
TRC E923668 Rac-Ethylenebis(tetrahydroindenyl)zirconiumDichloride 100163-29-9 50mg $195 2021-12-16 Buy
Product number Packaging Price Buy
532126 500mg $450 Buy
40-1400 100mg $140 Buy
40-1400 500mg $445 Buy
E923668 10mg $55 Buy
E923668 50mg $195 Buy

rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Chemical Properties, Uses, Production

Stability

Stable under normal temperature and pressure, avoid contact with water and oxidants.

Storage

sealed storage, stored in a cool, dry warehouse. Keep away from oxidants, water sources.

Chemical Properties

White to pale yellow powder,it can carry out catalytic reaction.

Uses

Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride is a catalyst for enantioselective methylalumination of monosubstituted alkenes.The Kaminsky catalyst with co-catalyst methylaluminoxane (MAO) is a type of Ziegler-Natta catalyst, showing extremely high activity for polymerization of olefins such as ethylene, propylene, and styrene.

Uses

Catalyst for:
Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines

reaction suitability

core: zirconium
reagent type: catalyst

rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride Preparation Products And Raw materials

Raw materials

Preparation Products

Global Suppliers ( 63)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340;13818007232 307593986@qq.com China 475 58
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Sinocompound Catalysts Co., Ltd. 0512-67216630 67216634 sales@sinocompound.com China 252 64
WUXI HONORSHINE CHEMICAL CO.,LTD. 0510-83593312 13665125081 sales@honorshinechem.com China 54 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9170 60

View Latest Price from rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl))zirconium dichloride pictures 2026-09-14 rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl))zirconium dichloride
100163-29-9
$10.00 1ASSAYS 99% 1 ton RongNa Biotechnology Co.,Ltd
Ethylenebis (tetrahydroindenyl) zirconium dichloride  pictures 2026-09-14 Ethylenebis (tetrahydroindenyl) zirconium dichloride
100163-29-9
100g/Bag 98% 2tons WUXI HONOR SHINE CHEMICAL CO.,LTD
rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride pictures 2026-06-30 rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium dichloride
100163-29-9
1kg 99% 10000KGS Shaanxi Dideu New Materials Co. Ltd
RAC-DICHLOROETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV) RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM(IV) DICHLORIDE RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM (R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE (S)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)ZIRCONIUM DICHLORIDE DICHLORO[RAC-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)]ZIRCONIUM(IV) DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV) DICHLORO-(R,R)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-ZIRCONIUM(IV) Rac-Ethylenebis(tetrahydroindenyl)zirconium Dichloride (R)-ethylene-1,2-bis(η5-4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride (ethylene bis-tetrahydroindenyl)zirconium dichloride Rac-Ethylenebis(4,5,7-tetrahydro-1-indenyl)zirconium(Ⅳ)Dichloride Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium Rac-[ethylenebis(4,5,6,7-tetrahydroindenyl)]zirconium dichloride enebis(tetrahydroindenyL Rac-EthyL rac-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)zirconium dichl... Dichloro[rel-(7aR,7'aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV) 60. Chinese name: rac-ethylene bis(4,5,6,7-tetrahydro-1-indenyl)diChlorozirconium 100163-29-9 C2H4C9H102ZrCl2 C20H26Cl2Zr C20H24Cl2Zr Chiral Catalysts, Ligands, and Reagents Other Chiral Catalysts Zirconium Asymmetric Synthesis Catalysis and Inorganic Chemistry metallocene Zr Catalysis and Inorganic Chemistry Chemical Synthesis Zirconium