3-BROMO-1-(TRIISOPROPYLSILYL)PYRROLE
- CAS No.
- 87630-36-2
- Chemical Name:
- 3-BROMO-1-(TRIISOPROPYLSILYL)PYRROLE
- Synonyms
- 3-BROMO-1-(TRIISOPROPYLSILYL)-1H-PYRROLE;3-bromo-1-[tris(propan-2-yl)silyl]-1H-pyrrole;DK941;3-BroMo-1-(triisopropylsi...;Bromotriisopropylsilylpyrrole;3-BROMO-1-(TRIISOPROPYLSILYL)PYRROLE;3-Bromo-N-(triisopropylsilyl)pyrrole;1-(TRIISOPROPYLSILYL)-3-BROMO-PYRROLE;3-Bromo-1(triisopropysilyl)pyrrole ;1-(Triisopropylsilyl)-3-bromo-1H-pyrrole
- CBNumber:
- CB4231491
- Molecular Formula:
- C13H24BrNSi
- Molecular Weight:
- 302.33
- MDL Number:
- MFCD01321136
- MOL File:
- 87630-36-2.mol
- MSDS File:
- SDS
| Boiling point | 100 °C(Press: 0.1 Torr) |
|---|---|
| Density | 1,16 g/cm3 |
| refractive index | n20/D1.519 |
| Flash point | >110℃ |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Oil |
| pka | -5.67±0.70(Predicted) |
| color | Black |
| InChI | InChI=1S/C13H24BrNSi/c1-10(2)16(11(3)4,12(5)6)15-8-7-13(14)9-15/h7-12H,1-6H3 |
| InChIKey | CNAUTMPRKBSDLH-UHFFFAOYSA-N |
| SMILES | N1([Si](C(C)C)(C(C)C)C(C)C)C=CC(Br)=C1 |
| CAS DataBase Reference | 87630-36-2(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280-P305+P351+P338-P264-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 36/37/38-20/21/22 | |||||||||
| Safety Statements | 26-36/37/39-36/37 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 2933.99.9701 | |||||||||
| NFPA 704 |
|
3-BROMO-1-(TRIISOPROPYLSILYL)PYRROLE price More Price(38)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | B1899 | 3-Bromo-1-(triisopropylsilyl)pyrrole >95.0%(GC) | 87630-36-2 | 1g | $66 | 2025-07-31 | Buy |
| TCI Chemical | B1899 | 3-Bromo-1-(triisopropylsilyl)pyrrole >95.0%(GC) | 87630-36-2 | 5g | $217 | 2025-07-31 | Buy |
| TCI Chemical | B1899 | 3-Bromo-1-(triisopropylsilyl)pyrrole >95.0%(GC) | 87630-36-2 | 25g | $980 | 2025-07-31 | Buy |
| TRC | B699075 | 3-Bromo-1-(triisopropylsilyl)pyrrole | 87630-36-2 | 100mg | $45 | 2021-12-16 | Buy |
| TRC | B699075 | 3-Bromo-1-(triisopropylsilyl)pyrrole | 87630-36-2 | 250mg | $50 | 2021-12-16 | Buy |
3-BROMO-1-(TRIISOPROPYLSILYL)PYRROLE Chemical Properties,Uses,Production
Uses
3-Bromo-1-(triisopropylsilyl)pyrrole is a pyrrole analogue mainly used in the field of organic synthesis. It can be used to prepare other heterocyclic compounds such as 1-(triisopropylsilyl)pyrrole and 3-Butadienyl-1-tosylpyrroles.
Synthesis
87630-35-1
87630-36-2
General procedure for the synthesis of 3-bromo-1-(triisopropylmethylsilyl)pyrrole from 1-(triisopropylmethylsilyl)pyrrole: at -78 °C, N-bromosuccinimide (NBS, 3.25 g, 18.3 mmol) was slowly added to a 1-(triisopropylmethylsilyl)pyrrole (3.72 g, 16.6 mmol) solution of tetrahydrofuran (THF, 17 mL ) solution was maintained at temperature and stirred continuously for 5 hours. Upon completion of the reaction, hexane (15 mL) and pyridine (0.5 mL) were added to the mixture and stirring was continued for 5 minutes. Subsequently, the solvent was removed by distillation under reduced pressure to give the crude product. The crude product was purified by silica gel column chromatography (eluent: n-hexane/ethyl acetate=30:1) to finally obtain 3-bromo-1-(triisopropylmethylsilyl)pyrrole (4.67 g, 93% yield) as a colorless oil.
References
[1] Chemische Berichte, 1989, vol. 122, p. 169 - 174
[2] Tetrahedron, 2011, vol. 67, # 35, p. 6673 - 6678
[3] Journal of Organic Chemistry, 1984, vol. 49, # 17, p. 3239 - 3240
[4] Tetrahedron, 2004, vol. 60, # 34, p. 7141 - 7146
[5] Organic Letters, 2014, vol. 16, # 24, p. 6334 - 6337
3-BROMO-1-(TRIISOPROPYLSILYL)PYRROLE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +8613336195806 | sales@capot.com | China | 29734 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 12938 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29800 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30229 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| Zhejiang J&C Biological Technology Co.,Limited | +1-2135480471 | sales@sarms4muscle.com | China | 10473 | 58 |
| Labnetwork lnc. | +86-27-50766799 +8618062016861 | contact@labnetwork.com | China | 19987 | 58 |
View Lastest Price from 3-BROMO-1-(TRIISOPROPYLSILYL)PYRROLE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2020-01-13 | 3-BROMO-1-(TRIISOPROPYLSILYL)PYRROLE
87630-36-2
|
US $6.68 / KG | 1KG | 97%-99% | 1kg-1000kg | Career Henan Chemical Co |
-
- 3-BROMO-1-(TRIISOPROPYLSILYL)PYRROLE
87630-36-2
- US $6.68 / KG
- 97%-99%
- Career Henan Chemical Co
