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2-Chloro-6-formylbenzonitrile

2-Chloro-6-formylbenzonitrile Structure
2-Chloro-6-formylbenzonitrile structure
CAS No.
77532-86-6
Chemical Name:
2-Chloro-6-formylbenzonitrile
Synonyms
3-Chloro-2-cyanobenzaldehyde;2-Chloro-6-formylbenzonitrile;Benzonitrile, 2-chloro-6-formyl-
CBNumber:
CB42454946
Molecular Formula:
C8H4ClNO
Molecular Weight:
165.58
MDL Number:
MFCD10699534
MOL File:
77532-86-6.mol
Last updated:2026-09-12 18:52:40
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2-Chloro-6-formylbenzonitrile Properties

Melting point 137-138 °C
Boiling point 323.5±27.0 °C(Predicted)
Density 1.32±0.1 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
Appearance White to yellow Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
HazardClass  IRRITANT

2-Chloro-6-formylbenzonitrile price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Activate Scientific AS45690 2-Chloro-6-formylbenzonitrile 98% 77532-86-6 1g $81 2026-06-04 Buy
Matrix Scientific 307004 2-Chloro-6-formylbenzonitrile 77532-86-6 250.00mg $34 2026-05-19 Buy
Matrix Scientific 307004 2-Chloro-6-formylbenzonitrile 77532-86-6 1.00g $73 2026-05-19 Buy
Matrix Scientific 307004 2-Chloro-6-formylbenzonitrile 77532-86-6 5.00g $315 2026-05-19 Buy
Matrix Scientific 057632 2-Chloro-6-formylbenzonitrile 77532-86-6 250.00mg $31 2026-05-18 Buy
Product number Packaging Price Buy
AS45690 1g $81 Buy
307004 250.00mg $34 Buy
307004 1.00g $73 Buy
307004 5.00g $315 Buy
057632 250.00mg $31 Buy

2-Chloro-6-formylbenzonitrile Chemical Properties, Uses, Production

Synthesis

Benzonitrile, 2-chloro-6-(dibromomethyl)-

77532-80-0

2-CHLORO-6-FORMYLBENZONITRILE

77532-86-6

General procedure for the synthesis of 2-chloro-6-formylbenzonitrile (III-B) from the compound (CAS: 77532-80-0): to a solution of IV-B (18.0 g, 58.2 mmol) in acetonitrile (60 mL) was added an aqueous solution of silver nitrate (AgNO3, 39.5 g, 23.3 mmol) (32 mL). The resulting yellow suspension was refluxed for 20 min. The solids were removed by filtration and washed with dichloromethane (150 mL). The combined filtrates were washed with water (25 mL), dried over sodium sulfate (Na2SO4) and subsequently concentrated under vacuum. The crude product was purified by rapid chromatography on silica gel (eluent: hexane/ethyl acetate, 2/1) to afford pure III-B, 8.67 g (90% yield).1H-NMR (300 MHz, CDCl3): δ 7.72 (t, J = 7.9 Hz, 1H), 7.79 (dd, J = 1.2, 7.9 Hz, 1H), 7.94 (dd, J = 1.2, 7.9 Hz, 1H), 10.31 (s, 1H) ppm. 13C-NMR (75.4 MHz, CDCl3): δ 112.9 (C), 114.4 (C), 127.5 (CH), 133.8 (CH), 134.9 (CH), 138.5 (C), 139.0 (C), 187.6 (CH) ppm. IR (HATR): 3069, 2865, 2221, 1697, 1584, 1566, 1443, 1395, 1291, 1224, 1195, 1182, 1155, 922, 798, 781, 726, 675 cm-1. EI-MS m/z (% relative intensity): 167 (5); 165 (15), 139 (33), 137 (100), 110 (24), 101 (44), 84 (13), 75 (79), 61 (23), 50 (45). Melting point: 140°C.

References

[1] Tetrahedron Asymmetry, 2009, vol. 20, # 17, p. 1962 - 1968
[2] Patent: US2012/77989, 2012, A1. Location in patent: Page/Page column 7-8
[3] Journal of Organic Chemistry, 2008, vol. 73, # 18, p. 7361 - 7364
[4] Patent: US4244966, 1981, A

2-Chloro-6-formylbenzonitrile Preparation Products And Raw materials

Raw materials

Benzonitrile, 2-chloro-6-(dibromomethyl)- Acetonitrile Silver nitrate

Preparation Products

2-Chloro-6-formylbenzonitrile Suppliers

Global Suppliers ( 53)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
ChemFuture PharmaTech (Jiangsu) Ltd 5108538618 suger.wang@chemfuture.com China 832 65
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Shanghai Harvest Chemical Industrial Co., Ltd. 15721252604 17321035817 sales@harvest-chem.com China 2829 64
Wuhan Arike Technology Co., Ltd. 027- 51832457 94518350 China 746 62
Nanjing Norris-Pharm Technology Co., Ltd 13901585132 sales@norris-pharm.com China 8869 55
Shanghai Balmxy Pharmaceutical Co., Ltd 021-24206007 13764915196 sales@balmxy.com China 6959 55
Shanghai YuLue Chemical Co., Ltd. 021-60345187 13671753212 lzz841106@aliyun.com China 10244 55
3A SpeedChemical Inc 21-65679720 service@speedchemical.com China 604 55
Supplier Advantage
J & K SCIENTIFIC LTD. 76
ChemFuture PharmaTech (Jiangsu) Ltd 65
ShangHai DEMO Chemical Co.,Ltd 57
Capot Chemical Co., Ltd 66
Shanghai Harvest Chemical Industrial Co., Ltd. 64
Wuhan Arike Technology Co., Ltd. 62
Nanjing Norris-Pharm Technology Co., Ltd 55
Shanghai Balmxy Pharmaceutical Co., Ltd 55
Shanghai YuLue Chemical Co., Ltd. 55
3A SpeedChemical Inc 55

View Latest Price from 2-Chloro-6-formylbenzonitrile manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-CHLORO-6-FORMYLBENZONITRILE pictures 2019-07-06 2-CHLORO-6-FORMYLBENZONITRILE
77532-86-6
 $1.00 1kg 98% 200kg Career Henan Chemical Co

2-Chloro-6-formylbenzonitrile Spectrum

2-CHLORO-6-FORMYLBENZONITRILE(77532-86-6)1HNMR

77532-86-6 (2-Chloro-6-formylbenzonitrile) Related Search:

2-Chloro-6-formylbenzonitrile 2-Chloro-6-methylbenzonitrile 3,4,5,6-Tetrachloro-2-cyanobenzoic acid ammonium salt
3-Chloro-2-cyanobenzaldehyde Benzonitrile, 2-chloro-6-formyl- 2-Chloro-6-formylbenzonitrile 77532-86-6