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N-Phenyl-1-naphthylamine

CAS No.
90-30-2
Chemical Name:
N-Phenyl-1-naphthylamine
Synonyms
PANA;N-phenylnaphthalen-1-amine;PHENYL ALPHA NAPHTHYLAMINE;1-Naphthalenamine, N-phenyl-;Phenylnaphthylamine;N-Phenyl-1-naphthalenamine;T351;amoco32;Nonox A;Algerite
CBNumber:
CB4322681
Molecular Formula:
C16H13N
Molecular Weight:
219.28
MDL Number:
MFCD00003878
MOL File:
90-30-2.mol
MSDS File:
SDS
Last updated:2026-05-28 04:57:10
Product description Number Pack Size Price
N-Phenyl-1-naphthylamine reagent grade, 98% 104043 500g $100
N-Phenyl-1-naphthylamine for synthesis 8.21003 250g $87.5
N-Phenyl-1-naphthylamine for synthesis. CAS 90-30-2, pH (H O) neutral., for synthesis 8.21003 8210030250 $80.4
N-Phenyl-1-naphthylamine >98.0%(GC) P0197 25g $31
N-Phenyl-1-naphthylamine >98.0%(GC) P0197 500g $131
More product size

N-Phenyl-1-naphthylamine Properties

Melting point 60-62 °C(lit.)
Boiling point 226 °C15 mm Hg(lit.)
Density 1,1 g/cm3
vapor pressure 0.504 hPa (150 °C)
refractive index 1.7020 (estimate)
Flash point >200°C
storage temp. Store below +30°C.
solubility 0.003g/l
form Crystals or Flakes
pka 0.78±0.30(Predicted)
color Pinkish to light brown
Water Solubility insoluble
λmax 252 nm
BRN 2211174
Henry's Law Constant 7.0×101 mol/(m3Pa) at 25℃, HSDB (2015)
Stability Stable. Incompatible with strong oxidizing agents, strong acids.
InChI 1S/C16H13N/c1-2-9-14(10-3-1)17-16-12-6-8-13-7-4-5-11-15(13)16/h1-12,17H
InChIKey XQVWYOYUZDUNRW-UHFFFAOYSA-N
SMILES N(c1ccccc1)c2cccc3ccccc23
CAS DataBase Reference 90-30-2(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances N-PHENYL-1-NAPHTHYLAMINE
EWG's Food Scores 1
FDA UNII 5I112077IN
NIST Chemistry Reference 1-Naphthyl phenyl amine(90-30-2)
EPA Substance Registry System N-Phenyl-1-naphthylamine (90-30-2)
UNSPSC Code 12352116
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
GHS07,GHS08,GHS09
Signal word  Warning
Hazard statements  H302-H317-H373-H410
Precautionary statements  P260-P273-P280-P301+P312-P302+P352-P314
target organs Blood
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn,N
Risk Statements  22-36/37/38-50/53-43
Safety Statements  26-36-61-37/39-29-60-36/37
RIDADR  3077
WGK Germany  2
RTECS  QM4500000
Autoignition Temperature >500 °C
TSCA  TSCA listed
HazardClass  9
PackingGroup  III
HS Code  29214980
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Skin Sens. 1B
STOT RE 2
Hazardous Substances Data 90-30-2(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: > 2000 mg/kg
REACH Registrations Active
Limited Quantities 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
0
2 0

N-Phenyl-1-naphthylamine price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 104043 N-Phenyl-1-naphthylamine reagent grade, 98% 90-30-2 500g $100 2026-04-30 Buy
Sigma-Aldrich 8.21003 N-Phenyl-1-naphthylamine for synthesis 90-30-2 250g $87.5 2022-05-15 Buy
Sigma-Aldrich 8.21003 N-Phenyl-1-naphthylamine for synthesis. CAS 90-30-2, pH (H O) neutral., for synthesis 90-30-2 8210030250 $80.4 2021-12-16 Buy
TCI Chemical P0197 N-Phenyl-1-naphthylamine >98.0%(GC) 90-30-2 25g $31 2026-04-30 Buy
TCI Chemical P0197 N-Phenyl-1-naphthylamine >98.0%(GC) 90-30-2 500g $131 2026-04-30 Buy
Product number Packaging Price Buy
104043 500g $100 Buy
8.21003 250g $87.5 Buy
8.21003 8210030250 $80.4 Buy
P0197 25g $31 Buy
P0197 500g $131 Buy

N-Phenyl-1-naphthylamine Chemical Properties,Uses,Production

Chemical Properties

brown solid

Uses

N-Phenyl-1-naphthylamine can be used as fluorescent probe for the determination of critical micelle concentration of surfactants. N-Phenyl-1-naphthylamine was used in a method for determination of the concentration of organolithium and organomagnesium reagents. N-Phenyl-1-naphthylamine was used as hydrophobic probe to study the phase transitions of membrane lipids in whole cells .

Definition

ChEBI: N-Phenyl-1-naphthylamine is a member of naphthalenes.

Application

N-Phenyl-1-naphthylamine is a lipophilic, crystalline solid with hydrophobic properties. It is used as an antioxidant in various lubricating oils, gear oils, and hydraulic fluids, as well as a protective agent and antioxidant for rubber and rubber blends in various products, such as tires. It can also be used as a fluorescent probe to study micelle formation and membrane lipid behavior. Studies have shown that N-Phenyl-1-naphthylamine interacts with β-lactoglobulin through hydrophobic interactions, and that β-lactoglobulin enhances the solubility and stability of N-Phenyl-1-naphthylamine.

General Description

White to slightly yellowish prisms or reddish brown crystalline powder.

Air & Water Reactions

May be sensitive to prolonged exposure to air. Insoluble in water. Napthyl amines can be slowly hydrolyzed, releasing NH3 as a byproduct [N.L. Drake, Org. React. 1, (1942), 105].

Reactivity Profile

N-Phenyl-1-naphthylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition N-Phenyl-1-naphthylamine emits toxic fumes.

Fire Hazard

Flash point data for N-Phenyl-1-naphthylamine are not available. N-Phenyl-1-naphthylamine is probably combustible.

Biochem/physiol Actions

N-Phenyl-1-naphthylamine turns fluorescent after binding to hydrophobic regions of cell membranes.

Contact allergens

Phenyl-alpha-naphthylamine is contained in some rubbers and oils as an antioxidant of the amine group. It is closely related to phenyl-beta-naphthylamine and to di-beta-naphthyl-p-phenylenediamine, but without cross-reactivity.

Purification Methods

Crystallise it from EtOH, pet ether or *C6H6/EtOH. Dry it under vacuum in an Abderhalden pistol. [Beilstein 12 H 1224.]

Toxicity evaluation

N-Phenyl-1-naphthylamine is harmful to humans and can irritate the skin, eyes, and mucous membranes. Inhalation exposure may cause bluish discoloration of the lips, nails, and skin; dizziness, headache, nausea, confusion, convulsions, and even coma. Prolonged or repeated exposure may cause damage to organs. Furthermore, it is flammable and releases irritating or toxic fumes (or gases) in the event of a fire. It has low acute oral toxicity in experimental animals and high acute toxicity in fish and daphnia, with reported minimum no-observed-effect concentrations (NOECs) of 0.11 mg/L (192 hours) and 0.02 mg/L (21 days), respectively.

134-32-7
108-90-7
90-30-2
Synthesis of N-Phenyl-1-naphthylamine from 1-Naphthylamine and Chlorobenzene
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View Lastest Price from N-Phenyl-1-naphthylamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N-Phenyl-1-naphthylamine pictures 2026-05-28 N-Phenyl-1-naphthylamine
90-30-2
$10.00-30.00 10kg 99% 100000kg Hebei Chuanghai Biotechnology Co,.LTD
N-Phenyl-1-naphthalenamine pictures 2026-04-17 N-Phenyl-1-naphthalenamine
90-30-2
$10.00-50.00 1kg 99%,Electronic grade(Single metal impurity≤ 100ppb) or pharmaceutical grade 1000kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
N-Phenyl-1-naphthylamine pictures 2026-03-20 N-Phenyl-1-naphthylamine
90-30-2
$10.00 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
  • N-Phenyl-1-naphthalenamine pictures
  • N-Phenyl-1-naphthalenamine
    90-30-2
  • $10.00-50.00
  • 99%,Electronic grade(Single metal impurity≤ 100ppb) or pharmaceutical grade
  • ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
N-Phenyl-1-naphthylaMine reagent grade, 98% Akrochem antioxidant PANA Algerite alpha-Naphthylphenylamine alpha-Phenylnaphthylamine amoco32 n-phenyl-1-naphthylamin Phenyl-1-naphthylamine Phenylnaphthylamine Vulkanox pan vulkanoxpan N-PHENYL-ALPHA NAPTHYLAMINE N-(α-Naphthyl)aniline 1-Naphthalenamine,N-phenyl- 1-Naphthylamine, N-phenyl- Aceto pan acetopan Additin 30 [1]Naphthyl-phenyl-amine 1-(N-Phenylamino)-naphthalene acetic acid 2-(1-tetrazolyl)ethyl ester N-Phenyl-1-naphthylamine in stock Factory antigenepan Antioxidant PAN AntioxidantA antioxidantpan C.I. 44050 c.i.44050 Fenyl-alpha-naftylamin Naphthyl phenyl amine Naugard PANA Neozon A Neozone A Neozone D NeozoneA N-Fenyl-1-aminonaftalen Nocrac PA Nonox A Nonox AN N-Phenyl-1-aminonaphthalene n-phenyl-1-naphthalenamin Phenyl-1-naphthylamime N-Phenyl-1-Naphthylamine~98% 1-(N-Anilino)naphthalene N-1-Naphthylanilin 1-ANILINONAPHTHALENE N-Phenyl-1-naphthyla N-Phenyl-1-naphthylaMine, 98% 25GR N-1-NAPHTHYLANILINE NAPHTHALEN-1-YL-PHENYL-AMINE PHENYL ALPHA NAPHTHYLAMINE N-PHENYL-1-NAPHTHYLAMINE N-Phenyl-α-naphthylamine N-PHENYL-ALPHA-NAPHTHYLAMINE additin30 BIS-(4,4')-N-PHENYL-1-NAPHTHYLAMINE TIMTEC-BB SBB000591 N-Phenyl-1-naphthylamine>