- N-Phenyl-1-naphthalenamine
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- $50.00 / 1000kg
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2025-10-13
- CAS:90-30-2
- Min. Order: 1kg
- Purity: 99%，Electronic grade(Single metal impurity≤ 100ppb) or pharmaceutical grade
- Supply Ability: 1000kg
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| | N-Phenyl-1-naphthylamine Basic information |
| | N-Phenyl-1-naphthylamine Chemical Properties |
| Melting point | 60-62 °C(lit.) | | Boiling point | 226 °C15 mm Hg(lit.) | | density | 1,1 g/cm3 | | vapor pressure | 0.504 hPa (150 °C) | | refractive index | 1.7020 (estimate) | | Fp | >200°C | | storage temp. | Store below +30°C. | | solubility | 0.003g/l | | form | Crystals or Flakes | | pka | 0.78±0.30(Predicted) | | color | Pinkish to light brown | | Water Solubility | insoluble | | λmax | 252 nm | | BRN | 2211174 | | Henry's Law Constant | 7.0×101 mol/(m3Pa) at 25℃, HSDB (2015) | | Stability: | Stable. Incompatible with strong oxidizing agents, strong acids. | | InChI | 1S/C16H13N/c1-2-9-14(10-3-1)17-16-12-6-8-13-7-4-5-11-15(13)16/h1-12,17H | | InChIKey | XQVWYOYUZDUNRW-UHFFFAOYSA-N | | SMILES | N(c1ccccc1)c2cccc3ccccc23 | | CAS DataBase Reference | 90-30-2(CAS DataBase Reference) | | NIST Chemistry Reference | 1-Naphthyl phenyl amine(90-30-2) | | EPA Substance Registry System | N-Phenyl-1-naphthylamine (90-30-2) |
| Hazard Codes | Xn,N | | Risk Statements | 22-36/37/38-50/53-43 | | Safety Statements | 26-36-61-37/39-29-60-36/37 | | RIDADR | 3077 | | WGK Germany | 2 | | RTECS | QM4500000 | | Autoignition Temperature | >500 °C | | TSCA | TSCA listed | | HazardClass | 9 | | PackingGroup | III | | HS Code | 29214980 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Skin Sens. 1B
STOT RE 2 | | Hazardous Substances Data | 90-30-2(Hazardous Substances Data) | | Toxicity | LD50 orally in Rabbit: > 2000 mg/kg |
| | N-Phenyl-1-naphthylamine Usage And Synthesis |
| Chemical Properties | brown solid | | Uses | N-Phenyl-1-naphthylamine can be used as fluorescent probe for the determination of critical micelle concentration of surfactants. N-Phenyl-1-naphthylamine was used in a method for determination of the concentration of organolithium and organomagnesium reagents. N-Phenyl-1-naphthylamine was used as hydrophobic probe to study the phase transitions of membrane lipids in whole cells . | | Definition | ChEBI: N-Phenyl-1-naphthylamine is a member of naphthalenes. | | Application | N-Phenyl-1-naphthylamine is a lipophilic, crystalline solid with hydrophobic properties. It is used as an antioxidant in various lubricating oils, gear oils, and hydraulic fluids, as well as a protective agent and antioxidant for rubber and rubber blends in various products, such as tires. It can also be used as a fluorescent probe to study micelle formation and membrane lipid behavior. Studies have shown that N-Phenyl-1-naphthylamine interacts with β-lactoglobulin through hydrophobic interactions, and that β-lactoglobulin enhances the solubility and stability of N-Phenyl-1-naphthylamine.
| | General Description | White to slightly yellowish prisms or reddish brown crystalline powder. | | Air & Water Reactions | May be sensitive to prolonged exposure to air. Insoluble in water. Napthyl amines can be slowly hydrolyzed, releasing NH3 as a byproduct [N.L. Drake, Org. React. 1, (1942), 105]. | | Reactivity Profile | N-Phenyl-1-naphthylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. | | Health Hazard | ACUTE/CHRONIC HAZARDS: When heated to decomposition N-Phenyl-1-naphthylamine emits toxic fumes. | | Fire Hazard | Flash point data for N-Phenyl-1-naphthylamine are not available. N-Phenyl-1-naphthylamine is probably combustible. | | Biochem/physiol Actions | N-Phenyl-1-naphthylamine turns fluorescent after binding to hydrophobic regions of cell membranes. | | Contact allergens | Phenyl-alpha-naphthylamine is contained in some rubbers
and oils as an antioxidant of the amine group. It is
closely related to phenyl-beta-naphthylamine and to
di-beta-naphthyl-p-phenylenediamine, but without
cross-reactivity. | | Purification Methods | Crystallise it from EtOH, pet ether or *C6H6/EtOH. Dry it under vacuum in an Abderhalden pistol. [Beilstein 12 H 1224.] | | Toxicity evaluation | N-Phenyl-1-naphthylamine is harmful to humans and can irritate the skin, eyes, and mucous membranes. Inhalation exposure may cause bluish discoloration of the lips, nails, and skin; dizziness, headache, nausea, confusion, convulsions, and even coma. Prolonged or repeated exposure may cause damage to organs. Furthermore, it is flammable and releases irritating or toxic fumes (or gases) in the event of a fire. It has low acute oral toxicity in experimental animals and high acute toxicity in fish and daphnia, with reported minimum no-observed-effect concentrations (NOECs) of 0.11 mg/L (192 hours) and 0.02 mg/L (21 days), respectively. |
| | N-Phenyl-1-naphthylamine Preparation Products And Raw materials |
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