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Bis(benzonitrile)palladium chloride

Bis(benzonitrile)palladium chloride Structure
Bis(benzonitrile)palladium chloride structure
CAS No.
14220-64-5
Chemical Name:
Bis(benzonitrile)palladium chloride
Synonyms
Pd(PhCN)2Cl2;BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE;Bis(benzonitrile)palladium dichloride;BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE;Dichlorobis(benzonitrile)palladium;DICHLOROBIS(BENZONITRILE)PALLADIUM(II);TRANS-BIS(BENZONITRILE)DICHLOROPALLADIUM(II);Bis(benzonitrile)palladiuM(II);BIS(BENZONITRILE)DICHLOROPALLADIUM(II);Bis(benzonitriL
CBNumber:
CB4339461
Molecular Formula:
C14H10Cl2N2Pd
Molecular Weight:
383.57
MDL Number:
MFCD00013123
MOL File:
14220-64-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-04 16:00:12
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Bis(benzonitrile)palladium chloride Properties

Melting point 131 °C(lit.)
storage temp. Inert atmosphere,2-8°C
solubility Soluble in acetone, chloroform
form Crystalline Powder
color Orange to brown
Water Solubility insoluble
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN 3981730
Exposure limits NIOSH: IDLH 25 mg/m3
InChI InChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChIKey WXNOJTUTEXAZLD-UHFFFAOYSA-L
SMILES C1(C#N)=CC=CC=C1.C1(C#N)=CC=CC=C1.[Pd](Cl)Cl
CAS DataBase Reference 14220-64-5(CAS DataBase Reference)
UNSPSC Code 12161600
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Skull and Crossbones (GHS06)Exclamation Mark (GHS07)
GHS06,GHS07
Signal word  Danger
Hazard statements  H301+H311+H331-H315-H319-H302-H312-H332
Precautionary statements  P280h-P301+P312a-P304+P340-P321-P501a-P261-P264-P270-P271-P280-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P305+P351+P338+P337+P313-P403+P233-P405-P501
PPE Eyeshields, Gloves, type N95 (US)
Hazard Codes  Xn
Risk Statements  20/21-23/24/25
Safety Statements  22-24/25-23-45-36/37-27-20-9-4
RIDADR  UN3439
WGK Germany  3
F  9
TSCA  No
HazardClass  6.1
PackingGroup  III
HS Code  28439090
Storage Class 11 - Combustible Solids
Limited Quantities 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
0
1 0

Bis(benzonitrile)palladium chloride price More Price(74)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 223689 Bis(benzonitrile)palladium(II) chloride 95% 14220-64-5 1g $96.2 2026-04-30 Buy
Sigma-Aldrich 223689 Bis(benzonitrile)palladium(II) chloride 95% 14220-64-5 10g $885 2026-04-30 Buy
TCI Chemical B1668 Bis(benzonitrile)palladium(II) Dichloride >98.0%(T) 14220-64-5 1g $179 2026-04-30 Buy
TCI Chemical B1668 Bis(benzonitrile)palladium(II) Dichloride >98.0%(T) 14220-64-5 5g $672 2026-04-30 Buy
Strem Chemicals 46-0400 Dichlorobis(benzonitrile)palladium(II), 99% 99% 14220-64-5 1g $94 2026-04-30 Buy
Product number Packaging Price Buy
223689 1g $96.2 Buy
223689 10g $885 Buy
B1668 1g $179 Buy
B1668 5g $672 Buy
46-0400 1g $94 Buy

Bis(benzonitrile)palladium chloride Chemical Properties, Uses, Production

Reaction

  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.
Reactions of 14220-64-5_1
Reactions of 14220-64-5_2

Chemical Properties

yellow powder

Uses

suzuki reaction

Uses

Catalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.

Uses

Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:

  • For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
  • In cross-coupling reactions and α-O-glycosidation.

Formal anti-Markovnikov hydroamination of terminal olefins

General Description

This product has been enhanced for catalytic efficiency.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Synthesis

Bis(cyanophenyl)dichloropalladium can be prepared by reacting palladium acetate or palladium chloride with benzonitrile.
A mixture of palladium(II) acetate (502 mg, 2.2 mmol), HCl (37% aqueous solution, 0.7 mL, 8.5 mmol), and benzonitrile (15 mL) was stirred for 30 minutes at 90C in a 50 mL flask. The mixture was allowed to cool at 20C and then hexane (8 mL) was added. The mixture was filtered through diatomaceous earth and washed with hexane. The filtrate was cooled to 4C to obtain crystals. Filter the crystals. Wash with hexane and dry under high vacuum.

Bis(benzonitrile)palladium chloride Preparation Products And Raw materials

Raw materials

Toluene Palladium chloride Benzonitrile

Preparation Products

Chlorodimethylphenylsilane 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Bis(tricyclohexylphosphine)palladium(II) Dichloride

Bis(benzonitrile)palladium chloride Suppliers

Global Suppliers ( 385)
Supplier Tel Email Country ProdList Advantage
Shaanxi Rock New Materials Co., Ltd. 0917-8888777 18691786767 liuwei@bjrock.com China 309 62
Nanjing Pharmaluxury Co., Ltd. 025-83726959 15851816062 goodsalejs@163.com China 128 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11777 60
Supplier Advantage
Shaanxi Rock New Materials Co., Ltd. 62
Nanjing Pharmaluxury Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
ShangHai DEMO Chemical Co.,Ltd 57
Beijing HwrkChemical Technology Co., Ltd 55
Energy Chemical 61
Beijing Ouhe Technology Co., Ltd 60

View Latest Price from Bis(benzonitrile)palladium chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(benzonitrile)palladium(II)chloride pictures 2026-08-18 Bis(benzonitrile)palladium(II)chloride
14220-64-5
 1KG 98.00% 100KG /month Shanghai Daken Advanced Materials Co.,Ltd
Bis(benzonitrile)palladium chloride pictures 2022-09-24 Bis(benzonitrile)palladium chloride
14220-64-5
 1kg 99% 1000kg henan kanbei chemical co.,ltd
Bis(benzonitrile)palladium chloride pictures 2021-07-13 Bis(benzonitrile)palladium chloride
14220-64-5
 $10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd

Bis(benzonitrile)palladium chloride Spectrum

Bis(benzonitrile)palladium chloride(14220-64-5)1HNMRBis(benzonitrile)palladium chloride(14220-64-5)IR1Bis(benzonitrile)palladium chloride(14220-64-5)IR2Bis(benzonitrile)palladium chloride(14220-64-5)Raman

14220-64-5 (Bis(benzonitrile)palladium chloride) Related Search:

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TRANS-BIS-(BENZONITRILE)PALLADIUM(II) CHLORIDE Dichlorobis(benzonitrile)palladiuM(II),98% (C6H5CN)2PdCl2 trans-Bis(benzonitrile)palladiuM chloride Dichlorobis(benzonitrile)palladium(Ⅱ) Benzonitrile, palladium complex Bis(phenylnitrile)dichloropalladium Dibenzonitrilepalladium dichloride Dichlorobis(benzonitrile)palladium Dichlorobis(phenyl cyanide)palladium Palladium dichloride bis(benzonitrile) Bis(benzonitrile)palladiuM(II)chloridel Bis(benzonitrile)palladiuM(II) chloride 95% Bis (benzonitrile) palladiuM bis(benzonitrile)dichloro-Palladium Bis(benzonitrile)-palladium(II) chloride (27.7% Pd) for synthesis PALLADIUM(II) CHLORIDE BIS(BENZONITRILE) COMPLEX Dichlorodiamminepalladium(II) PdCl2(C6H5CN)2 is(benzonitrile)palladium chloride Bis(benzonitrile)palladium(II) chloride 95+% TRANS-DICHLOROBIS-(BENZONITRILO)-PALLADIUM TRANS-BIS(BENZONITRILE)DICHLOROPALLADATE (II) Bis(benzonitrile)palladium chloride Dichlorobis(benzonitrile)palladium(II) ,(C6H5CN)2PdCl2 Benzonitrile - dichloropalladium (2:1) Bis(benzonitrile)palladium(II) chloride, 99+% trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.7% Trans-Bis(benzonitrile)dichloropalladium(II) Can be used to form catalysts in situ by separate addition of ligand Dichlorobis(benzonitrile)palladium(II),99% Palladium, bis(benzonitrile)dichloro- Palladium(II)chloro-bis(benzonitrile) trans-Bis(benzonitrile)dichloropalladium(II), Pd Dichlorobis(benzonitrile)palladium (II) ,98% Bis(benzonitrile)palladiuM(II) trans-Bis(benzonitrile)dichloropalladiuM(II), Pd 27.1% Bis(benzonitrile)palladiuM(II) chloride, 99+% 1GR Bis(benzonitrile)palladium(II) Dichloride > Bis(benzonitrile)dichloropalladium(Ⅱ) Bis(benzonitriL Bis(benzonitrile)palladium chloride ISO 9001：2015 REACH Bis(benzonitrile)palladium(II)chloride 14220-64-5 Bis(benzonitrile)palladium(II) Dichloride extrapure, 27.4% Pd BIS (BENZONITRILE) DICHLORO PALLADIUM (II) For synthesis Bis(benzonitrile Palladium(II)bis(benzonitrile)chloride Bis(benzonitrile)palladium(II) chloride 99% pd:27.7 Bis(benzonitrile)palladium(II) chlo benzonitrile,palladium(2+),dichloride BIS(BENZONITRILE)DICHLOROPALLADIUM(II) BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE Bis(benzonitrile)palladium dichloride DICHLOROBIS(BENZONITRILE)PALLADIUM(II) Pd(PhCN)2Cl2 TRANS-BIS(BENZONITRILE)DICHLOROPALLADIUM(II) 14220-64-5 PdCl2C6H5CN2 C6H5CN2PdCl2 C14H10N2PdCl2