[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
- CAS No.
- 19978-61-1
- Chemical Name:
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
- Synonyms
- PdCl2(dppe);DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(II);1,2-Bis;Dichloro(1;1,2-[BIS(DIPHENYLPHOSPHINO)ETHAN;2-bis(diphenylphosphino)ethane)palladium(II);Bis(diphenylphosphino)ethane]dichloropalladium;TIANFU-CHEM Bis(benzonitrile)palladium chloride-;Dichloro[1,2-bis(diphenylphosphino)ethanepalladiu;[1,2-Bis(diphenylphosphino)ethane]dichloropalladiu
- CBNumber:
- CB5309560
- Molecular Formula:
- C26H24Cl2P2Pd
- Molecular Weight:
- 575.74
- MDL Number:
- MFCD00015702
- MOL File:
- 19978-61-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) 98% | 345237 | 1g | $146 |
| [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride >98.0%(T) | B2016 | 1g | $57 |
| [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride >98.0%(T) | B2016 | 5g | $169 |
| Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98% 98% | 46-0800 | 1g | $102 |
| Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98% 98% | 46-0800 | 5g | $350 |
| More product size | |||
| Melting point | 360 °C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| form | Powder |
| color | off-white |
| Water Solubility | insoluble |
| Sensitive | Moisture sensitive |
| InChI | InChI=1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2 |
| InChIKey | LDJXFZUGZASGIW-UHFFFAOYSA-L |
| SMILES | C(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Pd](Cl)Cl |
| CAS DataBase Reference | 19978-61-1(CAS DataBase Reference) |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 28439000 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) price More Price(80)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 345237 | [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) 98% | 19978-61-1 | 1g | $146 | 2026-04-30 | Buy |
| TCI Chemical | B2016 | [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride >98.0%(T) | 19978-61-1 | 1g | $57 | 2026-04-30 | Buy |
| TCI Chemical | B2016 | [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride >98.0%(T) | 19978-61-1 | 5g | $169 | 2026-04-30 | Buy |
| Strem Chemicals | 46-0800 | Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98% 98% | 19978-61-1 | 1g | $102 | 2026-04-30 | Buy |
| Strem Chemicals | 46-0800 | Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98% 98% | 19978-61-1 | 5g | $350 | 2026-04-30 | Buy |
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Chemical Properties,Uses,Production
Chemical Properties
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is off-white in color and soluble in dichloromethane. It is easily affected by water and moisture; it needs to be filled with inert gas, sealed, and stored in a dry place.
Uses
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is a precatalyst used in the production of acrylic acid sodium salt via coupling of CO2 with ethene.
suzuki reaction.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
Synthesis
Add acetonitrile 3L in the reaction kettle, heat, add palladium chloride 177g (1.0mol) in 3 batches, add acetonitrile 2L, reflux reaction for 2~3h. When the reaction solution becomes brown-red clarified liquid, filter it while it is still hot, filter out a small amount of insoluble matter, add dppe 398g (1.0mol) in the filtrate, stir the reaction for 0.5h. Cool down to room temperature, filtrate, and wash the cake with cold tetrahydrofuran and water for 3~4 times in turn, vacuum drying for 7h to obtain 1,2-bis(diphenylphosphino)ethane palladium(II) 552g. The filter cake was washed with cold tetrahydrofuran and water for 3~4 times, and then dried under vacuum for 7h to obtain 1,2-bis(diphenylphosphino)ethane palladium(II) dichloride 552g, with 96% yield. The solvent slow evaporation method was used to cultivate single crystal, appropriate amount of solid product was dissolved in CHCl3, sealed with plastic wrap, left to stand, and naturally evaporated for 30d to obtain white flaky crystals.
Precautions
This palladium catalyst, also known as [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), presents as a very pale yellow to yellow crystalline powder. Store under inert gas, at ambient temperatures and protected from moisture. This substance is moisture sensitive. [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride is incompatible with oxidizing agents. This chemical is harmful if swallowed, in contact with skin or if inhaled. It causes skin irritation as well as serious eye irritation.
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-15225627621 +86-13213167925 | jiuyitime@fdachem.com | China | 16505 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14036 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21533 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29766 | 58 |
| CONIER CHEM AND PHARMA LIMITED | sales@conier.com | China | 49906 | 58 | |
| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 | contact@trustwe.com | China | 5742 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 | marketing1@neostarunited.com | China | 8827 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17339 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +86-189 4982 3763 | sales@tnjchem.com | China | 34526 | 58 |
| Shanghai UCHEM Inc. | +86-18930848214 +86-021-56762820 | sales@myuchem.com | China | 8898 | 58 |
View Lastest Price from [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-08-20 | [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
19978-61-1
|
$2.00-5.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
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2021-07-13 | [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
19978-61-1
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
![]() |
2021-07-10 | [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
19978-61-1
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-
![[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) pictures](/ProductImageEN1/2025-06/Small/ebd3182c-5722-4978-8074-509be20a6981.png)
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
19978-61-1
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
![[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) pictures](/ProductImageEN/2021-07/Small/010e74b9-c22c-49cc-a302-8c1c2252dc75.jpg)
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
19978-61-1
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
![[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) pictures](/ProductImageEN/2021-07/Small/24c9a1d3-d0da-40de-b51d-153a9e5f4ab3.jpg)
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
19978-61-1
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
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