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[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

CAS No.
19978-61-1
Chemical Name:
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
Synonyms
PdCl2(dppe);DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(II);1,2-Bis;Dichloro(1;1,2-[BIS(DIPHENYLPHOSPHINO)ETHAN;2-bis(diphenylphosphino)ethane)palladium(II);Bis(diphenylphosphino)ethane]dichloropalladium;TIANFU-CHEM Bis(benzonitrile)palladium chloride-;Dichloro[1,2-bis(diphenylphosphino)ethanepalladiu;[1,2-Bis(diphenylphosphino)ethane]dichloropalladiu
CBNumber:
CB5309560
Molecular Formula:
C26H24Cl2P2Pd
Molecular Weight:
575.74
MDL Number:
MFCD00015702
MOL File:
19978-61-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-01 17:09:38
Product description Number Pack Size Price
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) 98% 345237 1g $146
[1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride >98.0%(T) B2016 1g $57
[1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride >98.0%(T) B2016 5g $169
Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98% 98% 46-0800 1g $102
Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98% 98% 46-0800 5g $350
More product size

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Properties

Melting point 360 °C
storage temp. Inert atmosphere,Room Temperature
form Powder
color off-white
Water Solubility insoluble
Sensitive Moisture sensitive
InChI InChI=1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChIKey LDJXFZUGZASGIW-UHFFFAOYSA-L
SMILES C(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Pd](Cl)Cl
CAS DataBase Reference 19978-61-1(CAS DataBase Reference)
UNSPSC Code 12161600
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
HS Code  28439000
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
0
2 1

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) price More Price(80)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 345237 [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) 98% 19978-61-1 1g $146 2026-04-30 Buy
TCI Chemical B2016 [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride >98.0%(T) 19978-61-1 1g $57 2026-04-30 Buy
TCI Chemical B2016 [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride >98.0%(T) 19978-61-1 5g $169 2026-04-30 Buy
Strem Chemicals 46-0800 Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98% 98% 19978-61-1 1g $102 2026-04-30 Buy
Strem Chemicals 46-0800 Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II), 98% 98% 19978-61-1 5g $350 2026-04-30 Buy
Product number Packaging Price Buy
345237 1g $146 Buy
B2016 1g $57 Buy
B2016 5g $169 Buy
46-0800 1g $102 Buy
46-0800 5g $350 Buy

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Chemical Properties,Uses,Production

Chemical Properties

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is off-white in color and soluble in dichloromethane. It is easily affected by water and moisture; it needs to be filled with inert gas, sealed, and stored in a dry place.

Uses

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is a precatalyst used in the production of acrylic acid sodium salt via coupling of CO2 with ethene.
suzuki reaction.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium

Synthesis

Add acetonitrile 3L in the reaction kettle, heat, add palladium chloride 177g (1.0mol) in 3 batches, add acetonitrile 2L, reflux reaction for 2~3h. When the reaction solution becomes brown-red clarified liquid, filter it while it is still hot, filter out a small amount of insoluble matter, add dppe 398g (1.0mol) in the filtrate, stir the reaction for 0.5h. Cool down to room temperature, filtrate, and wash the cake with cold tetrahydrofuran and water for 3~4 times in turn, vacuum drying for 7h to obtain 1,2-bis(diphenylphosphino)ethane palladium(II) 552g. The filter cake was washed with cold tetrahydrofuran and water for 3~4 times, and then dried under vacuum for 7h to obtain 1,2-bis(diphenylphosphino)ethane palladium(II) dichloride 552g, with 96% yield. The solvent slow evaporation method was used to cultivate single crystal, appropriate amount of solid product was dissolved in CHCl3, sealed with plastic wrap, left to stand, and naturally evaporated for 30d to obtain white flaky crystals.

Precautions

This palladium catalyst, also known as [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), presents as a very pale yellow to yellow crystalline powder. Store under inert gas, at ambient temperatures and protected from moisture. This substance is moisture sensitive. [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride is incompatible with oxidizing agents. This chemical is harmful if swallowed, in contact with skin or if inhaled. It causes skin irritation as well as serious eye irritation.

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Preparation Products And Raw materials

Global( 299)Suppliers
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ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
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View Lastest Price from [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) pictures 2026-08-20 [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
19978-61-1
$2.00-5.00 1kg 99% 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) pictures 2021-07-13 [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
19978-61-1
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) pictures 2021-07-10 [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
19978-61-1
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
Chemical Name:1,2-Bis(diphenylphosphino)ethane palladium(II) chloride,98% Dichloro(1,2-bis(diphenylphosphino)ethane)palladiuM(II),98% (DPPE)PdCl2 [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Dichloro[1,2-bis(diphenylphosphino)ethane]palladium(II) 1,2-Bis(diphenylphosphino)ethane palladium (II) dichloride, 98+% [1,2-Bis(diphenylphosphiNA)ethane]dichloropalladiuM(II) Dichloro(1,2-bis(diphenylphosphino)ethane)palladiuM(II),(DPPE)PdCl2 [1,2-Bis(diphenylphosphino)ethane]dichloropalladiuM(Ⅱ), 19% Pd, Product of UMicore Dichloro[1,2-bis(diphenylphosphino)ethane]palladiuM(II), Pd 18.5% [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(Ⅱ) 1,2-bis (diphenylphosphino) ethane dichloride palladiuM (II) PdCl2(dppe) / dichloropalladium,2-diphenylphosphanylethyl(diphenyl)phosphane dichloropalladium,2-diphenylphosphanylethyl(diphenyl)phosphane DICHLORO[BIS(1,2-DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(II) [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLOROPALLADIUM(II) 1,2-[BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(II) CHLORIDE [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(II) DICHLORIDE Dichloro[1,2-bis(diphenylphosphino)ethanepalladiu Dichloro (1,2-Bis (diphenylphosphino)ethane dichlorpalladium (II)) Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II),98% Dichloro[bis(1,2-diphenylphosphino)ethane]palladium(II), Pd 18.5% DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE PALLADIUM()] Dichloro[1,2-bis(diphenylphosphano)ethane]palladium(II) [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II),98% 2-bis(diphenylphosphino)ethane)palladium(II) Dichloro(1 [1,2-Bis(diphenylphosphino)ethane]dichloropalladiu [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), 19% Pd, Product of Umicore 1,2-[BIS(DIPHENYLPHOSPHINO)ETHAN [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride > Palladium, dichloro[1,2-ethanediylbis[diphenylphosphine-kP]]-,(SP-4-2)- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) ISO 9001:2015 REACH 1,2-bis-Diphenylphosphinoethan-palladium(II) dichloride TIANFU-CHEM Bis(benzonitrile)palladium chloride- 1,2-bis(diphenylphosphino)ethane palladium dichloride [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) PdCl2(dppe) Bis(diphenylphosphino)ethane]dichloropalladium 1,2-Bis DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(II) PdCl2(dppe) 19978-61-1 C38H34Cl2P2Pd PddppeCl2 C6H52PCH2CH2PC6H52PdCl2 C26H24Cl2P2Pd PdCl2C6H52PCH2CH2PC6H52 Catalysis and Inorganic Chemistry Homogeneous Pd Catalysts Metal Complexes Pd (Palladium) Compounds Homogeneous Catalysts Classes of Metal Compounds Transition Metal Compounds Catalysts for Organic Synthesis chemical reaction,pharm,electronic,materials metal-phosphine complexes Pd Catalysts-Ligands API intermediates