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Ammonium sulfamate

CAS No.
7773-06-0
Chemical Name:
Ammonium sulfamate
Synonyms
AMS;AMMONIUM AMIDOSULFATE;Sulfamate;SULFAMIC ACID AMMONIUM SALT;Ammat;Amcide;Ammate;Ikurin;famate;Amicide
CBNumber:
CB4344641
Molecular Formula:
H6N2O3S
Molecular Weight:
114.12
MDL Number:
MFCD00011429
MOL File:
7773-06-0.mol
MSDS File:
SDS
Last updated:2026-01-22 09:27:45
Product description Number Pack Size Price
Ammonium sulfamate ACS reagent, ≥98.0% 228745 100g $45.4
Ammonium sulfamate ACS reagent, ≥98.0% 228745 500g $108.8
Ammonium amidosulfonate for analysis (for detection of sulfonamide in blood) EMSURE? ACS,Reag. Ph Eur 1.01220 100g $69
Ammonium Amidosulfate >98.5%(T) S0117 25g $27
Ammonium Amidosulfate >98.5%(T) S0117 500g $76
More product size

Ammonium sulfamate Properties

Melting point 131-135 °C (lit.)
Boiling point 160°C
bulk density 680kg/m3
Density 1.769
vapor pressure 0Pa at 20℃
Flash point 160°C
storage temp. no restrictions.
solubility H2O: 1 M at 20 °C, clear, colorless
form Crystalline Powder
color White
Odor Slight amine odor
PH 5.0-6.0 (50g/l, H2O, 20℃)
PH Range 4.5 - 6.0
Water Solubility 1950 g/L (20 ºC)
Sensitive Air & Moisture Sensitive
Merck 14,554
Exposure limits ACGIH: TWA 10 mg/m3
OSHA: TWA 15 mg/m3; TWA 5 mg/m3
NIOSH: IDLH 1500 mg/m3; TWA 10 mg/m3; TWA 5 mg/m3
Stability Stable. Incompatible with strong acids, strong oxidizing agents.
InChI 1S/H3NO3S.H3N/c1-5(2,3)4;/h(H3,1,2,3,4);1H3
InChIKey GEHMBYLTCISYNY-UHFFFAOYSA-N
SMILES N.NS(O)(=O)=O
LogP -4.34 at 20℃
Indirect Additives used in Food Contact Substances AMMONIUM SULFAMATE
FDA 21 CFR 175.105
CAS DataBase Reference 7773-06-0(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 945C6IU09L
NIST Chemistry Reference Ammonium sulfamate(7773-06-0)
Pesticides Freedom of Information Act (FOIA) Ammonium sulfamate
EPA Substance Registry System Ammonium sulfamate (7773-06-0)
UNSPSC Code 12352301
NACRES NB.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS09,GHS07
Signal word  Warning
Hazard statements  H319-H335-H336-H302-H400
Precautionary statements  P301+P312a-P330-P501a-P273-P261-P264-P270-P271-P280-P301+P312+P330-P304+P340+P312-P305+P351+P338+P337+P313-P403+P233-P405-P501
Hazard Codes  Xn,N
Risk Statements  22-50
Safety Statements  24/25-22-61
RIDADR  UN3077
OEB B
OEL TWA: 10 mg/m3 (total)
WGK Germany  1
RTECS  WO6125000
3-10
TSCA  TSCA listed
HazardClass  9
HS Code  29222100
Storage Class 13 - Non Combustible Solids
Hazardous Substances Data 7773-06-0(Hazardous Substances Data)
Toxicity LD50 orally in rats: 3.0 g/kg (Ambrose)
IDLA 1,500 mg/m3
Limited Quantities 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
1
1 0
OX

Ammonium sulfamate price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 228745 Ammonium sulfamate ACS reagent, ≥98.0% 7773-06-0 100g $45.4 2025-07-31 Buy
Sigma-Aldrich 228745 Ammonium sulfamate ACS reagent, ≥98.0% 7773-06-0 500g $108.8 2025-07-31 Buy
Sigma-Aldrich 1.01220 Ammonium amidosulfonate for analysis (for detection of sulfonamide in blood) EMSURE? ACS,Reag. Ph Eur 7773-06-0 100g $69 2025-07-31 Buy
TCI Chemical S0117 Ammonium Amidosulfate >98.5%(T) 7773-06-0 25g $27 2025-07-31 Buy
TCI Chemical S0117 Ammonium Amidosulfate >98.5%(T) 7773-06-0 500g $76 2025-07-31 Buy
Product number Packaging Price Buy
228745 100g $45.4 Buy
228745 500g $108.8 Buy
1.01220 100g $69 Buy
S0117 25g $27 Buy
S0117 500g $76 Buy

Ammonium sulfamate Chemical Properties,Uses,Production

Description

Ammonium sulfamate (or ammonium sulphamate) is a white crystalline solid, readily soluble in water. It is a salt formed from ammonia and sulfamic acid. Based on its good performance, it is widely used in industrial production and scientific research. Ammonium sulfamate is used as a herbicide, a composting accelerator in horticultural settings, a flame retardant, and so on.

Chemical Properties

Ammonium sulfamate is a white to yellow crystalline solid.

Application

Ammonium sulfamate could be widely used in pesticides, printing and dyeing, tobacco, building materials, textiles, and other industries. It could used as an analytical reagent. It could also used in the manufacture of fire-retardant compositions, for flameproofing textiles and paper products, and in the manufacture of weed-killing compositions. It is also used in electroplating solutions and could used for the generation of nitrous oxide gas.

Uses

Ammonium sulfamate (AMS) is an inorganic herbicide used for control of woody plants and herbaceous perennials.

Definition

ChEBI: Ammonium sulfamate is an organic molecular entity.

Preparation

Ammonium sulfamate is prepared continuously, starting from ammonia and sulfur trioxide, in which liquid sulfur trioxide and liquid ammonia are introduced in a molar ratio NH3 /SO3 greater than 2.0:1 into a pressure reactor containing the reaction product in the molten state, excess ammonia being removed continuously from the reactor and the liquid sulfur trioxide being introduced into the melt.

General Description

Ammonium sulfamate is a white crystalline solid. Ammonium sulfamate is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Ammonium sulfamate is used to flameproof fabrics and papers, in weed or brush killing products, and for other uses.

Air & Water Reactions

Water soluble. Hot water [Note: Elevated temperatures cause a highly exothermic reaction with water (in the presence of acid)] .

Reactivity Profile

Ammonium sulfamate is incompatible with the following: Acids, hot water [Note: Elevated temperatures cause a highly exothermic reaction with water (in the presence of acid).] .

Hazard

Hot acid solutions when enclosed may explode.

Health Hazard

Inhalation causes irritation of nose and throat. Ingestion causes gastrointestinal disturbances. Dust irritates eyes.

Fire Hazard

Special Hazards of Combustion Products: Toxic oxides of nitrogen may form in fires.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. Somewhat explosive when heated or by spontaneous chemical reaction in a hot acid solution. A powerful oxidizer. When heated to decomposition it emits very toxic fumes of NH3, NOx, and SOx. See also SULFONATES and SULFAMIC ACID.

Potential Exposure

Ammonium sulfamate is used as a herbicide and in compositions for retarding flame in textiles and paper products; a softener for paper, cotton textiles.

Carcinogenicity

The oral LD50 values were 3900 mg/kg for rats and 5760 mg/kg for mice.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Purification Methods

Crystallise it from water at room temperature (1mL/g) by adding EtOH and cooling. [Sisler & Audrieth Inorg Synth II 180 1946.]

Incompatibilities

Strong oxidizers, potassium, potassium chlorate, sodium nitrite, metal chlorates, and hot acid solutions. Elevated temperatures cause a highly exothermic reaction with water.

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Dilute with water, make neutral with acid or base and flush into sewer with more water.

Global( 504)Suppliers
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View Lastest Price from Ammonium sulfamate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ammonium sulfamate pictures 2026-01-30 Ammonium sulfamate
7773-06-0
US $10.00 / KG 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
Ammonium sulfamate pictures 2025-09-25 Ammonium sulfamate
7773-06-0
US $5.00-0.50 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Ammonium sulfamate pictures 2025-06-20 Ammonium sulfamate
7773-06-0
US $30.00-1.00 / kg 1kg 99 20tons Hebei Yanxi Chemical Co., Ltd.
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