Trimethyl(phenoxy)silane
- CAS No.
- 1529-17-5
- Chemical Name:
- Trimethyl(phenoxy)silane
- Synonyms
- PHENOXYTRIMETHYLSILANE;(Trimethylsiloxy)benzene;DK553;DKSI224;Phenol, TMS ether;Trimethylphenoxysilane;trimethylphenoxy-silan;TRIMETHYLSILYLPHENOXIDE;trimethylphenoxy-Silane;O-(Trimethylsilyl)phenol
- CBNumber:
- CB4402745
- Molecular Formula:
- C9H14OSi
- Molecular Weight:
- 166.29
- MDL Number:
- MFCD00053666
- MOL File:
- 1529-17-5.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | -55 °C |
|---|---|
| Boiling point | 81 °C23 mm Hg(lit.) |
| Density | 0.92 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 127 °F |
| storage temp. | Sealed in dry,Room Temperature |
| form | liquid |
| Specific Gravity | 0.92 |
| color | Colorless to Light orange to Yellow |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| λmax | 274nm(Heptane)(lit.) |
| BRN | 1905943 |
| InChI | InChI=1S/C9H14OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8H,1-3H3 |
| InChIKey | OJAJJFGMKAZGRZ-UHFFFAOYSA-N |
| SMILES | C1(O[Si](C)(C)C)=CC=CC=C1 |
| FDA UNII | 85E4MFC32D |
| EPA Substance Registry System | Silane, trimethylphenoxy- (1529-17-5) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226-H315-H319-H335 | |||||||||
| Precautionary statements | P210-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 10-36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| RIDADR | UN 1993 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 3.2 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29319090 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 |
|||||||||
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
Trimethyl(phenoxy)silane price More Price(13)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 380415 | Trimethyl(phenoxy)silane 97% | 1529-17-5 | 10ml | $73.5 | 2023-06-20 | Buy |
| TCI Chemical | T3222 | Trimethyl(phenoxy)silane >97.0%(GC) | 1529-17-5 | 5mL | $42 | 2026-04-30 | Buy |
| TCI Chemical | T3222 | Trimethyl(phenoxy)silane >97.0%(GC) | 1529-17-5 | 25mL | $119 | 2026-04-30 | Buy |
| aablocks | AA0035OI | Trimethyl(phenoxy)silane 97% | 1529-17-5 | 1g | $8 | 2026-05-28 | Buy |
| aablocks | AA0035OI | Trimethyl(phenoxy)silane 97% | 1529-17-5 | 5g | $24 | 2026-05-28 | Buy |
Trimethyl(phenoxy)silane Chemical Properties, Uses, Production
Chemical Properties
Clear colorless liquid
Uses
Trimethyl(phenoxy)silane can be used as a catalyst for the Friedel-Crafts reaction, which is an organic reaction that converts alkenes into alcohols or epoxides. It can also reacts with hydrochloric acid to give phenol and chloroform. Trimethyl(phenoxy)silane has been shown to have chemical properties similar to those of phenol, such as viscosity, chemical species and resonance spectroscopy properties. It can react with oxygen in the air to form peroxides, so it should be stored in a cool, dry place away from light.
General Description
Trimethyl(phenoxy)silane is a trimethylsilyl protected alcohol. Direct lateral zincation (DlZn) of trimethyl(phenoxy)silane has been reported. Dielectric studies of phenoxysilane-phenol binary systems has been reported.
Synthesis
General procedure for trimethylsilylation of alcohols with HMDS catalyzed by P2O5/Al2O3. P2O5/Al2O3 (0.1 g) was added to a stirred solution of the alcohol (10 mmol) and HMDS (7.5 mmol) and the mixture was stirred at room temperature for the time specified in Table 2. The reaction was followed by TLC (n-hexane-EtOAc, 9:1). After completion of the reaction, ethyl acetate was added to the reaction mixture and the catalyst was isolated by filtration. It was washed well with ethyl acetate (2 9 5 ml) and then dried at 100°C for 2 h before being used again. The filtered solution was evaporated and purified by passage through a short column of silica gel with n-hexane as eluent (2 x 20 ml). Evaporation of the solvent under reduced pressure gave the pure product Trimethyl(phenoxy)silane, Yield; 89%.
Trimethyl(phenoxy)silane Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| JinYan Chemicals(ShangHai) Co.,Ltd. | 13817811078 | sales@jingyan-chemical.com | China | 9963 | 60 |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| XiaoGan ShenYuan ChemPharm co,ltd | 15527621225; 15527621225 | 1791901229@qq.com | China | 6744 | 52 |
| Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11674 | 57 |
View Latest Price from Trimethyl(phenoxy)silane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2022-09-20 | Trimethylphenoxysilane
1529-17-5
|
1kg | 99% | 1000kg | henan kanbei chemical co.,ltd | ||
 |
2019-07-06 | PHENOXYTRIMETHYLSILANE
1529-17-5
|
$2.00 | 1KG | 99% | Career Henan Chemical Co |
-
- Trimethylphenoxysilane
1529-17-5
- $0.00
- 99%
- henan kanbei chemical co.,ltd
-
- PHENOXYTRIMETHYLSILANE
1529-17-5
- $2.00
- 99%
- Career Henan Chemical Co
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