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4-(Methoxymethyl)aniline

4-(Methoxymethyl)aniline Structure
4-(Methoxymethyl)aniline structure
CAS No.
80936-82-9
Chemical Name:
4-(Methoxymethyl)aniline
Synonyms
AKOS MSC-0184;4-(Methoxymethyl);4-(Methoxymethyl)aniline;4-(Methoxymethyl)benzenamine;Benzenamine,4-(methoxymethyl)-
CBNumber:
CB5168871
Molecular Formula:
C8H11NO
Molecular Weight:
137.18
MDL Number:
MFCD06804487
MOL File:
80936-82-9.mol
MSDS File:
SDS
Last updated:2026-09-12 18:53:14
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4-(Methoxymethyl)aniline Properties

storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
Appearance Light brown to brown Solid
InChI InChI=1S/C8H11NO/c1-10-6-7-2-4-8(9)5-3-7/h2-5H,6,9H2,1H3
InChIKey URSADVDNUKPSIK-UHFFFAOYSA-N
SMILES C1(N)=CC=C(COC)C=C1

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H412
Precautionary statements  P264-P270-P301+P312-P330-P501-P273-P501
Hazard Codes  Xn
Risk Statements  22
HS Code  2922190090

4-(Methoxymethyl)aniline price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR952839 4-(Methoxymethyl)aniline 98% 80936-82-9 250mg $21 2026-06-04 Buy
Apolloscientific OR952839 4-(Methoxymethyl)aniline 98% 80936-82-9 1g $24 2026-06-04 Buy
Apolloscientific OR952839 4-(Methoxymethyl)aniline 98% 80936-82-9 5g $85 2026-06-04 Buy
Apolloscientific OR952839 4-(Methoxymethyl)aniline 98% 80936-82-9 25g $305 2026-06-04 Buy
Apolloscientific OR952839 4-(Methoxymethyl)aniline 98% 80936-82-9 100g $1189 2026-06-04 Buy
Product number Packaging Price Buy
OR952839 250mg $21 Buy
OR952839 1g $24 Buy
OR952839 5g $85 Buy
OR952839 25g $305 Buy
OR952839 100g $1189 Buy

4-(Methoxymethyl)aniline Chemical Properties, Uses, Production

Synthesis

Benzene,1-(methoxymethyl)-4-nitro-

1515-83-9

4-(METHOXYMETHYL)ANILINE

80936-82-9

General procedure for the synthesis of 4-methoxymethylaniline from 1-(methoxymethyl)-4-nitrobenzene: a mixture of 1-(methoxymethyl)-4-nitrobenzene (243 mg, 1 mmol) with 1% Pd/Ni bimetallic catalyst (73 mg, 30 wt%) in methanol (10 mL) was placed in an atmospheric pressure hydrogenation unit and stirred at room temperature and atmospheric pressure until hydrogen absorption ceased (about 90 min). Upon completion of the reaction, the catalyst was removed by means of a magnetic stirring bar and the solution was subsequently evaporated using a rotary evaporator to afford the target product, 4-methoxymethylaniline (1a), as a yellow oil (210 mg, 98% yield), which was sufficiently pure to be analyzed by 1H and 13C NMR. νmax by IR (KBr): 3372, 1623, 1519, 1233 cm1; 1H NMR (CDCl3, 400 MHz) δ: 7.26-7.20 (m, 2H), 7.06 (d, 2H, J = 11.0 Hz), 6.87 (d, 2H, J = 11.0 Hz), 6.69 (d, 2H, J = 11.0 Hz), 4.90 (s, 2H), 3.69 (s, 2H) 2.28 (s, 3H); 13C NMR (CDCl3, 100 MHz) δ: 156.8, 146.3, 129.7 (2C), 126.8, 115.0 (2C), 114.6 (2C), 70.1, 20.4. HRMS (ESI-TOF) m/z: [M + Na]+ calcd for C14H15NO, 236.1046; found, 236.1044.

References

[1] Tetrahedron, 2015, vol. 71, # 49, p. 9240 - 9244
[2] Synlett, 1998, # 9, p. 1028 - 1028
[3] Journal of the Chemical Society. Perkin Transactions 1, 2001, # 9, p. 955 - 977
[4] Chemistry - A European Journal, 2007, vol. 13, # 4, p. 1291 - 1299
[5] Journal of the Chemical Society, 1954, p. 4127,4132

4-(Methoxymethyl)aniline Preparation Products And Raw materials

Raw materials

4-Bromobenzyl methyl ether Benzene,1-(methoxymethyl)-4-nitro- Hydrogen Methanol

Preparation Products

4-isobutylaniline

4-(Methoxymethyl)aniline Suppliers

Global Suppliers ( 60)
Supplier Tel Email Country ProdList Advantage
Shaoyuan Technology (Shanghai) Co., Ltd. 021-50795510 4000665055 marketing@accelachem.com China 9831 58
Shanghai Sunway Pharmaceutical Technology Co., Ltd 13761987713 hxzheng@sunwaypharm.cn China 8663 57
Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd. +86-28-85122536 85324413 market@astatech.cn China 8016 55
ShangHai AmK Pharmaceutical Technology Co., Ltd. 微信 18019252918 18019252918 sale@amkchem.com China 14982 55
Shanghai Song Yuan Chemical Technology Co., Ltd. 010-1234567 18521000990 sonyuanchemical@163.com China 6467 50
Cool Pharm, Ltd 021-60455363 18019463053 sales@coolpharm.com China 8455 58
Accela ChemBio Inc. +1(858) 699-3322 marketing@accelachem.com United States 6022 65
Changzhou Anxuan Chemical, Co., Ltd. 13912302692 sales@anxuanchem.com China 4824 58
Changzhou Hopschain Chemical Co.,Ltd. 85528066 13775048983 sales@hopschem.com China 31548 55
Amadis Chemical Company Limited 571-89925085 sales@amadischem.com China 131885 58
Supplier Advantage
Shaoyuan Technology (Shanghai) Co., Ltd. 58
Shanghai Sunway Pharmaceutical Technology Co., Ltd 57
Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd. 55
ShangHai AmK Pharmaceutical Technology Co., Ltd. 55
Shanghai Song Yuan Chemical Technology Co., Ltd. 50
Cool Pharm, Ltd 58
Accela ChemBio Inc. 65
Changzhou Anxuan Chemical, Co., Ltd. 58
Changzhou Hopschain Chemical Co.,Ltd. 55
Amadis Chemical Company Limited 58

View Latest Price from 4-(Methoxymethyl)aniline manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-(METHOXYMETHYL)ANILINE pictures 2020-01-09 4-(METHOXYMETHYL)ANILINE
80936-82-9
 500g 98%; 99% 500g；1kg； 10kg; 25kg Career Henan Chemical Co

4-(Methoxymethyl)aniline Spectrum

4-(METHOXYMETHYL)ANILINE(80936-82-9)1HNMR

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AKOS MSC-0184 4-(Methoxymethyl)benzenamine Benzenamine,4-(methoxymethyl)- 4-(Methoxymethyl) 4-(Methoxymethyl)aniline 80936-82-9