2,4,6-TRI-TERT-BUTYLANILINE
- CAS No.
- 961-38-6
- Chemical Name:
- 2,4,6-TRI-TERT-BUTYLANILINE
- Synonyms
- 2,4,6-tri-t-Butylaniline;AKOS BC-0696;TIMTEC-BB SBB000998;2,4,6-Tri-tert-butyL;Aniline, tri-tert-butyl-;2,4,6-T-tert-butylaniline;2,4,6-TRI-TERT-BUTYLANILINE;2,4,6-Tris(tert-butyl)aniline;Aniline, 2,4,6-tri-tert-butyl-;2,4,6-Tri-tert-butylphenylamine
- CBNumber:
- CB5228207
- Molecular Formula:
- C18H31N
- Molecular Weight:
- 261.45
- MDL Number:
- MFCD00011645
- MOL File:
- 961-38-6.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 2,4,6-Tri-tert-butylaniline 99% | 223050 | 1g | $48 |
| 2,4,6-Tri-tert-butylaniline 99% | 223050 | 5g | $228 |
| 2,4,6-Tri-tert-butylaniline >98.0%(GC)(T) | T1694 | 1g | $46 |
| 2,4,6-Tri-tert-butylaniline >98.0%(GC)(T) | T1694 | 5g | $130 |
| 2,4,6-TRI-TERT-BUTYLPHENYLAMINE 95% | 67100 | 5G | $79 |
| More product size | |||
| Melting point | 145-147 °C(lit.) |
|---|---|
| Boiling point | 302.0±21.0 °C(Predicted) |
| Density | 0.896±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| pka | 3.30±0.10(Predicted) |
| form | powder to crystal |
| color | White to Light yellow |
| Water Solubility | Insoluble in water. |
| Sensitive | Light Sensitive |
| BRN | 2272612 |
| InChI | InChI=1S/C18H31N/c1-16(2,3)12-10-13(17(4,5)6)15(19)14(11-12)18(7,8)9/h10-11H,19H2,1-9H3 |
| InChIKey | REJGDSCBQPJPQT-UHFFFAOYSA-N |
| SMILES | C1(N)=C(C(C)(C)C)C=C(C(C)(C)C)C=C1C(C)(C)C |
| CAS DataBase Reference | 961-38-6(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-37/39 | |||||||||
| RIDADR | 2811 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 2921490090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
2,4,6-TRI-TERT-BUTYLANILINE price More Price(51)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 223050 | 2,4,6-Tri-tert-butylaniline 99% | 961-38-6 | 1g | $48 | 2026-04-30 | Buy |
| Sigma-Aldrich | 223050 | 2,4,6-Tri-tert-butylaniline 99% | 961-38-6 | 5g | $228 | 2026-04-30 | Buy |
| TCI Chemical | T1694 | 2,4,6-Tri-tert-butylaniline >98.0%(GC)(T) | 961-38-6 | 1g | $46 | 2026-04-30 | Buy |
| TCI Chemical | T1694 | 2,4,6-Tri-tert-butylaniline >98.0%(GC)(T) | 961-38-6 | 5g | $130 | 2026-04-30 | Buy |
| AstaTech | 67100 | 2,4,6-TRI-TERT-BUTYLPHENYLAMINE 95% | 961-38-6 | 5G | $79 | 2026-04-30 | Buy |
2,4,6-TRI-TERT-BUTYLANILINE Chemical Properties,Uses,Production
Chemical Properties
White to off-white powder
Uses
2,4,6-Tri-tert-butylnitrobenzene (bulky amine) is used in the synthesis of monomeric iminophosphorane
Uses
2,4,6-Tri-tert-butylnitrobenzene (bulky amine) was used in the synthesis of monomeric iminophosphorane.
Definition
ChEBI: 2,4,6-tri-tert-butylaniline is an alkylbenzene.
Synthesis
4074-25-3
961-38-6
The general procedure for the synthesis of 2,4,6-tri-tert-butylaniline from 2,4,6-tri-tert-butylnitrobenzene was as follows: in a 4 mL glass reaction flask equipped with a septum cap and a magnetic stirring bar, Co-Co3O4Chit-700 catalyst (10 mg, 3.4 mol/kg Co), nitroaromatic hydrocarbons (0.5 mmol, 1.0 equiv), triethylamine ( 35 μL, 0.25 mmol, 0.5 equiv), and EtOH/H2O (3:1, 2 mL) mixed solvent. The reaction vial was placed in a 300 mL autoclave and pressurized to 40 bar after five displacements with hydrogen. The reaction mixture was stirred at 110 °C until the reaction was complete. At the end of the reaction, it was cooled to room temperature and the pressure in the autoclave was slowly released. The crude reaction mixture was filtered through a cotton fitted pipette and the filtrate was concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: ethyl acetate), and pure 2,4,6-tri-tert-butylaniline derivatives were obtained after removing the solvent under reduced pressure. Using the catalyst of the present invention, efficient preparation of the target aniline derivatives from the corresponding nitroaromatics can be realized.
References
[1] ChemSusChem, 2017, vol. 10, # 15, p. 3035 - 3039
[2] Patent: WO2018/114777, 2018, A1. Location in patent: Page/Page column 31-32
[3] Journal of the American Chemical Society, 1991, vol. 113, # 22, p. 8437 - 8443
[4] Journal of the American Chemical Society, 1982, vol. 104, # 25, p. 7191 - 7195
[5] Chemistry - A European Journal, 2017, vol. 23, # 59, p. 14738 - 14742
2,4,6-TRI-TERT-BUTYLANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14014 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21586 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29815 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9996 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52704 | 58 |
| CD Chemical Group Limited | +8615986615575 | info@codchem.com | China | 17259 | 58 |
View Lastest Price from 2,4,6-TRI-TERT-BUTYLANILINE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | 2,4,6-TRI-TERT-BUTYLANILINE
961-38-6
|
$8.00 | 1kg | 99% | 10MT | Career Henan Chemical Co |
-
- 2,4,6-TRI-TERT-BUTYLANILINE
961-38-6
- $8.00
- 99%
- Career Henan Chemical Co
