4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE
- CAS No.
- 89720-77-4
- Chemical Name:
- 4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE
- Synonyms
- 4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE;Benzene, 4-bromo-1-(bromomethyl)-2-chloro-
- CBNumber:
- CB52603343
- Molecular Formula:
- C7H5Br2Cl
- Molecular Weight:
- 284.38
- MDL Number:
- MFCD15526905
- MOL File:
- 89720-77-4.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% | OR960144 | 1g | $32 |
| 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% | OR960144 | 5g | $111 |
| 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% | OR960144 | 10g | $184 |
| 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% | OR960144 | 25g | $362 |
| 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% | OR960144 | 1g | $32 |
| More product size | |||
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() GHS05,GHS08 |
|---|---|
| Signal word | Danger |
| Hazard statements | EUH208-H314-H334 |
| Precautionary statements | P280-P301+P330+P331-P303+P361+P353 |
| RIDADR | 3265 |
| HazardClass | 8 |
| PackingGroup | Ⅲ |
| HS Code | 2903998090 |
4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE price More Price(36)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | OR960144 | 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% | 89720-77-4 | 1g | $32 | 2026-06-04 | Buy |
| Apolloscientific | OR960144 | 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% | 89720-77-4 | 5g | $111 | 2026-06-04 | Buy |
| Apolloscientific | OR960144 | 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% | 89720-77-4 | 10g | $184 | 2026-06-04 | Buy |
| Apolloscientific | OR960144 | 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% | 89720-77-4 | 25g | $362 | 2026-06-04 | Buy |
| Apolloscientific | OR960144 | 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% | 89720-77-4 | 1g | $32 | 2026-06-04 | Buy |
4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE Chemical Properties,Uses,Production
Uses
4-Bromo-1-bromomethyl-2-chlorobenzene is used in the preparation of selective aldose reductase inhibitors.
Synthesis
185315-48-4
89720-77-4
To a solution of (4-bromo-2-chlorophenyl)methanol (2.80 g, 12.67 mmol) in dichloromethane (60.0 mL) was added sequentially carbon tetrabromide (4.41 g, 13.30 mmol) and triphenylphosphine (3.48 g, 13.30 mmol) under argon protection and at 0 °C. The reaction mixture was stirred at room temperature for 4 hours. After completion of the reaction, the mixture was concentrated under reduced pressure and the resulting crude product was purified by fast column chromatography (eluent: hexane solution of 10% ethyl acetate) to afford 2-chloro-4-bromobenzyl bromide as a colorless oil (3.59 g, 100% yield).1H NMR (400 MHz, CDCl3): δ 4.53 (s, 2H), 7.29 (d, J = 8.2 Hz. 1H), 7.39 (dd, J = 8.2, 1.9 Hz, 1H), 7.56 (d, J = 1.9 Hz, 1H).
References
[1] Patent: WO2004/74270, 2004, A2. Location in patent: Page 175
[2] Patent: WO2006/18725, 2006, A1. Location in patent: Page/Page column 235-236
[3] Patent: WO2008/18827, 2008, A1. Location in patent: Page/Page column 65-66
[4] Patent: WO2010/15652, 2010, A2. Location in patent: Page/Page column 68
[5] Tetrahedron Letters, 2016, vol. 57, # 3, p. 449 - 451
4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20120 | 58 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 | contact@fuxinpharm.com | China | 9976 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14303 | 58 |
| Finetech Industry Limited | +86-27-8746-5837 +86-18627785180 | info@finetechnology-ind.com | China | 9539 | 58 |
| Zhejiang J&C Biological Technology Co.,Limited | +1-2135480471 | sales@sarms4muscle.com | China | 10457 | 58 |
| Changzhou Anxuan Chemical Co., Ltd | +86-0519-89882563 +86-18961279162 | andy@anxuanchem.com | China | 4327 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +86-18949823763 | sales@tnjchem.com | China | 25356 | 58 |
View Lastest Price from 4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-07-09 | 4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE
89720-77-4
|
$1.00-101.00 | 1KG | 99% | Henan Fengda Chemical Co., Ltd |
-

- 4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE
89720-77-4
- $1.00-101.00
- 99%
- Henan Fengda Chemical Co., Ltd







