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4-Bromo-1-bromomethyl-2-chloro-benzene

4-Bromo-1-bromomethyl-2-chloro-benzene Structure
4-Bromo-1-bromomethyl-2-chloro-benzene structure
CAS No.
89720-77-4
Chemical Name:
4-Bromo-1-bromomethyl-2-chloro-benzene
Synonyms
4-Bromo-1-bromomethyl-2-chloro-benzene;Benzene, 4-bromo-1-(bromomethyl)-2-chloro-
CBNumber:
CB52603343
Molecular Formula:
C7H5Br2Cl
Molecular Weight:
284.38
MDL Number:
MFCD15526905
MOL File:
89720-77-4.mol
MSDS File:
SDS
Last updated:2026-09-12 18:53:25
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4-Bromo-1-bromomethyl-2-chloro-benzene Properties

storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form liquid
color Colourless

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Health Hazard (GHS08)
GHS05,GHS08
Signal word  Danger
Hazard statements  EUH208-H314-H334
Precautionary statements  P280-P301+P330+P331-P303+P361+P353
RIDADR  3265
HazardClass  8
PackingGroup  Ⅲ
HS Code  2903998090

4-Bromo-1-bromomethyl-2-chloro-benzene price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR960144 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% 89720-77-4 1g $32 2026-06-04 Buy
Apolloscientific OR960144 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% 89720-77-4 5g $111 2026-06-04 Buy
Apolloscientific OR960144 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% 89720-77-4 10g $184 2026-06-04 Buy
Apolloscientific OR960144 4-Bromo-1-(bromomethyl)-2-chlorobenzene 95% 89720-77-4 25g $362 2026-06-04 Buy
Activate Scientific AS16505 4-Bromo-(1-bromomethyl)-2-chlorobenzene 96% 89720-77-4 1g $59 2026-06-04 Buy
Product number Packaging Price Buy
OR960144 1g $32 Buy
OR960144 5g $111 Buy
OR960144 10g $184 Buy
OR960144 25g $362 Buy
AS16505 1g $59 Buy

4-Bromo-1-bromomethyl-2-chloro-benzene Chemical Properties, Uses, Production

Uses

4-Bromo-1-bromomethyl-2-chlorobenzene is used in the preparation of selective aldose reductase inhibitors.

Synthesis

(4-Bromo-2-chlorophenyl)methanol

185315-48-4

4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE

89720-77-4

To a solution of (4-bromo-2-chlorophenyl)methanol (2.80 g, 12.67 mmol) in dichloromethane (60.0 mL) was added sequentially carbon tetrabromide (4.41 g, 13.30 mmol) and triphenylphosphine (3.48 g, 13.30 mmol) under argon protection and at 0 °C. The reaction mixture was stirred at room temperature for 4 hours. After completion of the reaction, the mixture was concentrated under reduced pressure and the resulting crude product was purified by fast column chromatography (eluent: hexane solution of 10% ethyl acetate) to afford 2-chloro-4-bromobenzyl bromide as a colorless oil (3.59 g, 100% yield).1H NMR (400 MHz, CDCl3): δ 4.53 (s, 2H), 7.29 (d, J = 8.2 Hz. 1H), 7.39 (dd, J = 8.2, 1.9 Hz, 1H), 7.56 (d, J = 1.9 Hz, 1H).

References

[1] Patent: WO2004/74270, 2004, A2. Location in patent: Page 175
[2] Patent: WO2006/18725, 2006, A1. Location in patent: Page/Page column 235-236
[3] Patent: WO2008/18827, 2008, A1. Location in patent: Page/Page column 65-66
[4] Patent: WO2010/15652, 2010, A2. Location in patent: Page/Page column 68
[5] Tetrahedron Letters, 2016, vol. 57, # 3, p. 449 - 451

4-Bromo-1-bromomethyl-2-chloro-benzene synthesis

89794-02-5
89720-77-4
Synthesis of 4-Bromo-1-bromomethyl-2-chloro-benzene from 4-Bromo-2-chlorotoluene

4-Bromo-1-bromomethyl-2-chloro-benzene Preparation Products And Raw materials

Raw materials

2-Chloro-4-bromobenzaldehyde 4-Bromo-2-chlorobenzoic acid (4-Bromo-2-chlorophenyl)methanol Triphenylphosphine 4-Bromo-2-chlorobenzoic acid methyl ester
4-Bromo-2-chlorotoluene Dichloromethane Carbon tetrabromide POTASSIUM CYANIDE

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Preparation Products

Methyl 2-(4-broMo-2-chlorophenyl)acetate 2-(4-bromo-2-chlorophenyl)acetic acid

4-Bromo-1-bromomethyl-2-chloro-benzene Suppliers

Global Suppliers ( 86)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Adamas Reagent, Ltd. 400-6009262 15618770481 yhx@titansci.com China 14098 59
Chemsky (shanghai) International Co.,Ltd 021-50135380 shchemsky@sina.com China 15350 60
S.Z. PhyStandard Bio-Tech. Co., Ltd. 0755-83725681-603 China 4484 50
9ding chemical ( Shanghai) Limited 4009209199 sales@9dingchem.com China 18201 56
SHANGHAI FORTUNE CHEMICAL TECHNOLOGY CO., LTD 13816107857 sales@fortunechem-sh.com China 981 58
Amatek Scientific Co. Ltd. 0512-56316828 4008675858 sales@amateksci.com China 9848 55
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Finetech Industry Limited 027-87465837 19945049750 sales@finetechnology-ind.com China 9331 58
ShangHai AmK Pharmaceutical Technology Co., Ltd. 微信 18019252918 18019252918 sale@amkchem.com China 14982 55
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Adamas Reagent, Ltd. 59
Chemsky (shanghai) International Co.,Ltd 60
S.Z. PhyStandard Bio-Tech. Co., Ltd. 50
9ding chemical ( Shanghai) Limited 56
SHANGHAI FORTUNE CHEMICAL TECHNOLOGY CO., LTD 58
Amatek Scientific Co. Ltd. 55
Bide Pharmatech Ltd. 60
Finetech Industry Limited 58
ShangHai AmK Pharmaceutical Technology Co., Ltd. 55

View Latest Price from 4-Bromo-1-bromomethyl-2-chloro-benzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE pictures 2026-09-02 4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE
89720-77-4
 $1.00-101.00 1KG 99% Henan Fengda Chemical Co., Ltd

4-Bromo-1-bromomethyl-2-chloro-benzene Spectrum

4-BROMO-1-BROMOMETHYL-2-CHLORO-BENZENE(89720-77-4)1HNMR

89720-77-4 (4-Bromo-1-bromomethyl-2-chloro-benzene) Related Search:

4-bromo-2-(bromomethyl)-1-chlorobenzene 3-Bromo-2-chlorobeznyl bromide 2-Chlorobenzyl bromide 1-bromo-2-(bromomethyl)-3,5-dichloro-benzene 2,6-Dichlorobenzyl bromide
5-bromo-2-(bromomethyl)-1,3-dichlorobenzene

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Benzene, 4-bromo-1-(bromomethyl)-2-chloro- 4-Bromo-1-bromomethyl-2-chloro-benzene 89720-77-4 89720-77-0 Aromatics Intermediates