3-Nitrophenylhydrazine hydrochloride
- CAS No.
- 636-95-3
- Chemical Name:
- 3-Nitrophenylhydrazine hydrochloride
- Synonyms
- 3-NitrophenylhydrazineHcl;M-NITROPHENYLHYDRAZINE HCL;3-Nitrophenylhydrazine Hcl 98%;M-Nitrophenylhydrazinium chloride;M-NITROPHENYLHYDRAZINE HYDROCHLORIDE;3-NITROPHENYLHYDRAZINE HYDROCHLORIDE;3-nitrophenylhydrazinium(1+) chloride;3-NITROPHENYLHYDRAZINE HYDROCHLORIDE 98%;3-NITROPHENYLHYDRAZINE HYDROCHLORIDE, 98 %;3-Nitrophenylhydrazine Hydrochloride, 97+%
- CBNumber:
- CB5284737
- Molecular Formula:
- C6H8ClN3O2
- Molecular Weight:
- 189.6
- MDL Number:
- MFCD00012939
- MOL File:
- 636-95-3.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 210 °C (dec.)(lit.) |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | DMSO, Methanol (Slightly) |
| form | Solid |
| color | Yellow to Dark Yellow |
| BRN | 3569013 |
| InChI | 1S/C6H7N3O2.ClH/c7-8-5-2-1-3-6(4-5)9(10)11;/h1-4,8H,7H2;1H |
| InChIKey | BKOYKMLGFFASBG-UHFFFAOYSA-N |
| SMILES | Cl.NNc1cccc(c1)[N+]([O-])=O |
| CAS DataBase Reference | 636-95-3(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 20/21/22-36/37/38 | |||||||||
| Safety Statements | 26-37/39-36 | |||||||||
| RIDADR | 2811 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 2928009090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
3-Nitrophenylhydrazine hydrochloride price More Price(40)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | N21804 | 3-Nitrophenylhydrazine hydrochloride 98% | 636-95-3 | 5g | $55.6 | 2026-04-30 | Buy |
| Sigma-Aldrich | N21804 | 3-Nitrophenylhydrazine hydrochloride 98% | 636-95-3 | 25g | $165 | 2026-04-30 | Buy |
| TCI Chemical | N0232 | 3-Nitrophenylhydrazine Hydrochloride >98.0%(T) | 636-95-3 | 5g | $52 | 2026-04-30 | Buy |
| TCI Chemical | N0232 | 3-Nitrophenylhydrazine Hydrochloride >98.0%(T) | 636-95-3 | 25g | $142 | 2026-04-30 | Buy |
| TRC | TRC-N545130-5G | 3-Nitrophenylhydrazine Hydrochloride | 636-95-3 | 5g | $73 | 2026-06-03 | Buy |
3-Nitrophenylhydrazine hydrochloride Chemical Properties, Uses, Production
Chemical Properties
YELLOW CRYSTALLINE POWDER
Uses
3-Nitrophenylhydrazine Hydrochloride acts as a reagent in the preparation of isosteviol-fused pyrazolines and pyrazoles as potential anticancer agents, preparation of pyrazolobenzothiazines as inhibitors of hepatitis C virus replication.
Synthesis
99-09-2
51516-96-2
Example 28: Synthesis of 3-methyl-1H-indol-6-amine 1. 3-Nitroaniline (27.6 g, 0.2 mol) was dissolved in a mixed solution of water (40 mL) and 37% hydrochloric acid (40 mL). 2. A solution of sodium nitrite (NaNO2, 13.8 g, 0.2 mol) in water (60 mL) was slowly added to the above solution at 0 °C. 3. Subsequently, a 37% hydrochloric acid (100 mL) solution of tin chloride dihydrate (SnCl2-2H2O, 135.5 g, 0.6 mol) was added, maintaining the reaction temperature at 0 °C. 4. After continuous stirring of the reaction mixture at 0 °C for 0.5 h, the insoluble solid was separated by filtration and washed with cold water to afford (3-nitrophenyl)hydrazine hydrochloride (27.6 g, 73% yield). Example 49: Synthesis of 6-amino-1H-indole-2-carbonitrile 1. 3-Nitroaniline (28 g, 0.20 mol) was dissolved in a mixture of water (40 mL) and 37% hydrochloric acid (40 mL). 2. A solution of sodium nitrite (NaNO2, 14 g, 0.20 mol) in water (60 mL) was slowly added to the above solution at 0 °C. 3. Subsequently, a 37% hydrochloric acid (100 mL) solution of tin chloride dihydrate (SnCl2-2H2O, 140 g, 0.60 mol) was added, maintaining the reaction temperature at 0 °C. 4. After continuous stirring of the reaction mixture at 0 °C for 0.5 h, the insoluble solid was separated by filtration and washed with cold water to afford (3-nitrophenyl)hydrazine hydrochloride (28 g, 73% yield).
References
[1] Patent: US2007/244159, 2007, A1. Location in patent: Page/Page column 110-111; 138
[2] Patent: US2012/309758, 2012, A1. Location in patent: Page/Page column 67
[3] Patent: US2015/231142, 2015, A1. Location in patent: Paragraph 0397; 1632; 1744
[4] Organic Preparations and Procedures International, 1991, vol. 23, # 3, p. 357 - 364
[5] Journal of Agricultural and Food Chemistry, 2014, vol. 62, # 2, p. 381 - 390
3-Nitrophenylhydrazine hydrochloride Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11777 | 60 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 |
View Latest Price from 3-Nitrophenylhydrazine hydrochloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2022-02-22 | 3-Nitrophenylhydrazine hydrochloride
636-95-3
|
1KG | 99.5% | 100 tons | Honest Joy Holdings Limited |
-
- 3-Nitrophenylhydrazine hydrochloride
636-95-3
- $0.00
- 99.5%
- Honest Joy Holdings Limited
3-Nitrophenylhydrazine hydrochloride Spectrum
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