Phenyl trifluoromethanesulfonate
- CAS No.
- 17763-67-6
- Chemical Name:
- Phenyl trifluoromethanesulfonate
- Synonyms
- PHENYL TRIFLATE;Phenol triflate;Phenol trifluoromethanesulfonate;PHENYL TRIFLUOROMETHANESULFONATE;Trifluoromethylsulfonyloxybenzene;Phenyl rifluoromehanesulfonae, 98%;PhenylTrifluoromethanesulfonate>Phenyl trifluoromethanesulfonate 98%;Trifluoromethanesulfonic acid phenyl ester;Methanesulfonic acid, 1,1,1-trifluoro-, phenyl ester
- CBNumber:
- CB5369083
- Molecular Formula:
- C7H5F3O3S
- Molecular Weight:
- 226.17
- MDL Number:
- MFCD00192399
- MOL File:
- 17763-67-6.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Boiling point | 99-100 °C/60 mmHg (lit.) |
|---|---|
| Density | 1.396 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 160 °F |
| storage temp. | Inert atmosphere,Room Temperature |
| form | clear liquid |
| color | Colorless to Almost colorless |
| InChI | InChI=1S/C7H5F3O3S/c8-7(9,10)14(11,12)13-6-4-2-1-3-5-6/h1-5H |
| InChIKey | GRJHONXDTNBDTC-UHFFFAOYSA-N |
| SMILES | C(F)(F)(F)S(OC1=CC=CC=C1)(=O)=O |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS06 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301+H311-H314 | |||||||||
| Precautionary statements | P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P361+P364 | |||||||||
| PPE | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | T | |||||||||
| Risk Statements | 36/37/38-34-24/25 | |||||||||
| Safety Statements | 26-36-45-36/37/39 | |||||||||
| RIDADR | UN 2927 6.1/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | 6.1, 8 | |||||||||
| HS Code | 29049090 | |||||||||
| Storage Class | 6.1A - Combustible acute toxic Cat. 1 and 2 very toxic hazardous materials |
|||||||||
| Hazard Classifications | Acute Tox. 3 Oral Skin Corr. 1B |
|||||||||
| Limited Quantities | 100ml (liquid) or 0.5 Kg (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (1g or 1ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
Phenyl trifluoromethanesulfonate price More Price(38)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 423939 | Phenyl trifluoromethanesulfonate 98% | 17763-67-6 | 5ml | $195 | 2026-04-30 | Buy |
| TCI Chemical | P1829 | Phenyl Trifluoromethanesulfonate >98.0%(GC) | 17763-67-6 | 1g | $72 | 2026-04-30 | Buy |
| TCI Chemical | P1829 | Phenyl Trifluoromethanesulfonate >98.0%(GC) | 17763-67-6 | 5g | $260 | 2026-04-30 | Buy |
| Apolloscientific | PC450234 | Phenyl trifluoromethanesulfonate 98% | 17763-67-6 | 1g | $21 | 2026-06-04 | Buy |
| Apolloscientific | PC450234 | Phenyl trifluoromethanesulfonate 98% | 17763-67-6 | 5g | $25 | 2026-06-04 | Buy |
Phenyl trifluoromethanesulfonate Chemical Properties, Uses, Production
Chemical Properties
Colorless Liquid.
Uses
Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:
As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.
As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.
Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.
As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran.
Preparation
Synthesis of Phenyl trifluoromethanesulfonate: The reaction of phenol (1.00 g, 10.6 mmol) with triflic anhydride as outlined in the general procedure provided phenyl trifluoromethanesulfonate as colorless oil (0.73 g, 30%).
1H NMR (400 MHz, CDCl3) δ 7.50 – 7.42 (m, 2H), 7.41 – 7.36 (m, 1H), 7.32 – 7.24 (m, 2H).
General Description
Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride.
Phenyl trifluoromethanesulfonate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Nanjing Habo Medical Technology Co., Ltd. | 13376080562 13376090521 | sales@habotech.com | China | 724 | 60 |
| Shanghai Longsheng chemical Co.,Ltd. | 58099637 13585536065 | sales@shlschem.com | China | 9880 | 59 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66113011 13913916777 | cfzhang@aikonchem.com | China | 19902 | 55 |
| Shanghai Jian Chao Chemical Technology Co., Ltd. | 150-2103-5486 18017383231 | 983544897@qq.com | China | 9335 | 55 |
View Latest Price from Phenyl trifluoromethanesulfonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-02-06 | PHENYL TRIFLUOROMETHANESULFONATE
17763-67-6
|
$3.00 | 1KG | 98% | 100KG | Career Henan Chemical Co |
-
- PHENYL TRIFLUOROMETHANESULFONATE
17763-67-6
- $3.00
- 98%
- Career Henan Chemical Co
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