2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane
- CAS No.
- 29261-33-4
- Chemical Name:
- 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane
- Synonyms
- f4-tcnq;TCNQF4;2,3,5,6-Tetrafluoro-7,7',8,8'-tetracyanoquinodimethane;2,3,5,6-Tetraflu;2,3,5,6-Tetrafluoro-;2,3,5,6-Tetrafluoro-7,7,8,8-Te;TETRAFLUOROTETRACYANOQUINODIMETHANE;Tetrafluoro-7,7,8,8-tetracyanoquino;tcnqf4 (organic electronic material);2,3,5,6-TETRAFLUOROTETRACYANOQUINODIMETHANE
- CBNumber:
- CB5464946
- Molecular Formula:
- C12F4N4
- Molecular Weight:
- 276.15
- MDL Number:
- MFCD00042382
- MOL File:
- 29261-33-4.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane 97% | 376779 | 25mg | $118 |
| 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane 97% | 376779 | 100mg | $336 |
| Tetrafluorotetracyanoquinodimethane (purified by sublimation) [Organic Electronic Material] >98.0%(N) | T1131 | 100mg | $244 |
| Tetrafluorotetracyanoquinodimethane (purified by sublimation) [Organic Electronic Material] >98.0%(N) | T1131 | 1g | $1098 |
| 2,3,5,6-Tetrafluorotetracyanoquinodimethane >98% | PC6914 | 100mg | $21 |
| More product size | |||
| Melting point | 285-290 °C(lit.) |
|---|---|
| Boiling point | -89.6±40.0 °C(Predicted) |
| Density | 1.7075 (estimate) |
| storage temp. | Sealed in dry,Room Temperature |
| form | powder to crystal |
| color | Light yellow to Amber to Dark green |
| Water Solubility | insoluble |
| BRN | 2157887 |
| InChI | InChI=1S/C12F4N4/c13-9-7(5(1-17)2-18)10(14)12(16)8(11(9)15)6(3-19)4-20 |
| InChIKey | IXHWGNYCZPISET-UHFFFAOYSA-N |
| SMILES | C1(=C(C#N)C#N)C(F)=C(F)C(=C(C#N)C#N)C(F)=C1F |c:10,t:0| |
| CAS DataBase Reference | 29261-33-4(CAS DataBase Reference) |
| UNSPSC Code | 12352103 |
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301+H311+H331 | |||||||||
| Precautionary statements | P280-P301+P310+P330-P302+P352+P312-P304+P340+P311 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | Xn,T | |||||||||
| Risk Statements | 36/37/38-20/21/22-23/24/25 | |||||||||
| Safety Statements | 22-24/25-36/37/39-26-36/37 | |||||||||
| RIDADR | 2811 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Toxic | |||||||||
| HazardClass | 6.1(b) | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29269090 | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
|||||||||
| Hazard Classifications | Acute Tox. 3 Dermal Acute Tox. 3 Inhalation Acute Tox. 3 Oral |
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| Limited Quantities | 5.0 kg (11 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane price More Price(51)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 376779 | 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane 97% | 29261-33-4 | 25mg | $118 | 2026-04-30 | Buy |
| Sigma-Aldrich | 376779 | 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane 97% | 29261-33-4 | 100mg | $336 | 2026-04-30 | Buy |
| TCI Chemical | T1131 | Tetrafluorotetracyanoquinodimethane (purified by sublimation) [Organic Electronic Material] >98.0%(N) | 29261-33-4 | 100mg | $244 | 2026-04-30 | Buy |
| TCI Chemical | T1131 | Tetrafluorotetracyanoquinodimethane (purified by sublimation) [Organic Electronic Material] >98.0%(N) | 29261-33-4 | 1g | $1098 | 2026-04-30 | Buy |
| Apolloscientific | PC6914 | 2,3,5,6-Tetrafluorotetracyanoquinodimethane >98% | 29261-33-4 | 100mg | $21 | 2026-06-04 | Buy |
2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane Chemical Properties,Uses,Production
Classification
Fluorinated compounds, p-type dopant, Strong electron acceptor, Hole-injection materials, Hole-transport layer material, OLEDs, Polymer Solar Cells, Perovskite Solar Cells, OFETs.
Applications
F4TCNQ is one of the most widely used and most effective p-type dopants due to its strong electron-accepting ability and the extended π system. It has a deep LUMO level (-5.2 eV) which is energetically in the vicinity of the HOMO level of many organic semiconductors. Doping is facilitated by charge transfer from the HOMO level of the host to the LUMO of the dopant molecule. Pin devices with F4TCNQ doped 4,4',4''-tris(3-methylphenylphenylamino)triphenylamine (m-MTDATA) serving as the p-doped HTL show high luminance and efficiency at extremely low operating voltages: For instance, a luminance of 1000 cd/m2 is reached at a voltage of 2.9 V.
It has been reported that by controlling the doping concentration, the PCE of the PCDTBT:F4TCNQ solar cells increased from 6.41% to 7.94%, mainly due to improving the photocurrent with a F4TCNQ weight ratio of the blend lower than 0.5% [2]. F4TCNQ is also used as the p-type dopant for graphenes.
Description
F4TCNQ isone of the most widely used and most effective p-type dopants due to its strong electron-accepting ability and the extendedπsystem. It has a deep LUMO level (-5.2 eV) which is energetically in the vicinity of theHOMO level of many organic semiconductors. Doping is facilitated by charge transfer from the HOMO level of the host to the LUMO of the dopant molecule.Pin devices with F4TCNQ doped 4,4',4''-tris(3-methylphenylphenylamino)triphenylamine (m-MTDATA) serving as the p-doped HTL show high luminance and efficiency at extremely low operating voltages: For instance, a luminance of 1000 cd/m2 isreached at a voltage of 2.9 V .
Chemical Properties
Yellow-greenish or orange-brown powder
Uses
F4-TCNQ is the p-type dopant for hole-only devices and field effect transistors with organic hole transport layers (HTL). It is used in the preparation of a bilayer structure of F4-TCNQ and pentacene to study improved thermoelectric performance of organic thin films.
General Description
2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ) is a dopant used in the fabrication of organic semiconductors. It can tune the electronic properties as its lowest unoccupied molecular orbital is at a desirable energy level required to oxidize a wide range of semiconductors.
2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Jilin Uland Tech Co.,Ltd. | +86-16643553268 | yolanda@uldtech.com | China | 298 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 | info@spring-chem.com | China | 2068 | 57 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14026 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21585 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29812 | 58 |
| Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd. | 0431-80514535 13634302652 | Extension@chemextension.com | CHINA | 967 | 58 |
| Beijing Yanhua Jilian Opto-Electronic Technology Co., Ltd. | (+86)13146479469 | CHINA | 315 | 58 | |
| CONIER CHEM AND PHARMA LIMITED | sales@conier.com | China | 49979 | 58 | |
| career henan chemical co | +86-0371-86658258 | factory@coreychem.com | China | 29792 | 58 |
View Lastest Price from 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-04-04 | 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane
29261-33-4
|
1KG | 98% | 1ton | Henan Aochuang Chemical Co.,Ltd. | ||
 |
2025-04-04 | 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane
29261-33-4
|
1KG | 98% | 1ton | Henan Aochuang Chemical Co.,Ltd. | ||
 |
2019-07-26 | 2,2'-(perfluorocyclohexa-2,5-diene-1,4-diylidene)dimalononitrile
29261-33-4
|
10ASSAYS | 99.9% | 20 | Beijing Yanhua Jilian Opto-Electronic Technology Co., Ltd. |
-
- 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane
29261-33-4
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane
29261-33-4
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- 2,2'-(perfluorocyclohexa-2,5-diene-1,4-diylidene)dimalononitrile
29261-33-4
- $0.00
- 99.9%
- Beijing Yanhua Jilian Opto-Electronic Technology Co., Ltd.
