ChemicalBook >> CAS DataBase List >>4-Bromo-1-butyne

4-Bromo-1-butyne

CAS No.
38771-21-0
Chemical Name:
4-Bromo-1-butyne
Synonyms
4-broMobut-1-yne;4-bromobutyne;1-Bromo-3-butyne;4-Bromo-1-butyne;3-Butynyl Bromide;4-Bromo-1-butyne >4-BroMo-1-butyne 97%;4-bromobut-1-yne - [B86644];1-Butyne, 4-bromo- (6CI,9CI);4-Bromo-1-butyne,1-Bromo-3-butyne
CBNumber:
CB5500121
Molecular Formula:
C4H5Br
Molecular Weight:
132.99
MDL Number:
MFCD10000883
MOL File:
38771-21-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:53:35

4-Bromo-1-butyne Properties

Boiling point 110 °C
Density 1.417 g/mL at 25 °C
refractive index 1.481
Flash point 24 °C
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility Chloroform (Slightly), Methanol (Slightly)
form clear liquid
color Colorless to Light yellow to Light orange
Water Solubility Immiscible with water.
InChI InChI=1S/C4H5Br/c1-2-3-4-5/h1H,3-4H2
InChIKey XLYOGWXIKVUXCL-UHFFFAOYSA-N
SMILES C#CCCBr
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Skull and Crossbones (GHS06)
GHS02,GHS06
Signal word  Danger
Hazard statements  H226-H301-H317
Precautionary statements  P210-P280-P301+P310+P330-P302+P352
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  T
Risk Statements  10-25-43
Safety Statements  36/37-45
RIDADR  UN 1992 6.1(3) / PGIII
WGK Germany  3
HazardClass  3
PackingGroup  III
HS Code  29039990
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 3 Oral
Flam. Liq. 3
Skin Sens. 1
Limited Quantities 5.0 L (1.3 gallons) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
2
3 0

4-Bromo-1-butyne price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 675725 4-Bromo-1-butyne 97% 38771-21-0 5g $112 2026-04-30 Buy
TCI Chemical B3242 4-Bromo-1-butyne >97.0%(GC) 38771-21-0 5g $77 2026-04-30 Buy
TRC TRC-B682950-10G 4-Bromo-1-butyne 38771-21-0 10g $193 2026-06-03 Buy
Biosynth FB164813 4-Bromo-1-butyne 38771-21-0 25g $324.5 2026-06-04 Buy
Biosynth FB164813 4-Bromo-1-butyne 38771-21-0 50g $519 2026-06-04 Buy
Product number Packaging Price Buy
675725 5g $112 Buy
B3242 5g $77 Buy
TRC-B682950-10G 10g $193 Buy
FB164813 25g $324.5 Buy
FB164813 50g $519 Buy

4-Bromo-1-butyne Chemical Properties, Uses, Production

Chemical Properties

Yellow liquid

Uses

4-Bromo-1-butyne is used for pharmaceutical intermediates.

Uses

4-Bromo-1-butyne is used as a reactant in the synthesis of:

  • Macrocycles by cobalt-mediated [2+2+2] co-cyclotrimerization.
  • 2,4,5-trisubstituted oxazoles by a gold-catalyzed formal [3+2] cycloaddition.
  • Intramolecular 1,3-dipolar cycloaddition to synthesize 1,3,4-oxadiazoles.
  • Lactones bearing alkynes for reductive cyclization in the preparation of azulene derivatives.
  • Substituted α-pyrones by gold-catalyzed coupling reactions.

Synthesis

4-Bromo n-butyne can be obtained by reacting 3-butyn-1-ol with phosphorus tribromide.

927-74-2
38771-21-0
Synthesis of 4-Bromo-1-butyne from 3-Butyn-1-ol

4-Bromo-1-butyne Preparation Products And Raw materials

Raw materials

Preparation Products

Global Suppliers ( 176)
Supplier Tel Email Country ProdList Advantage
Anqing Jida Biotechnology Co., Ltd. 0556-5881618 18956990316 sales@jidapharm.com China 100 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11777 60
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9389 66
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 marketing@accelachem.com China 10972 64

View Latest Price from 4-Bromo-1-butyne manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-BROMO-1-BUTYNE pictures 2026-08-18 4-BROMO-1-BUTYNE
38771-21-0
1KG 98% 1000 KG Shaanxi Dideu New Materials Co. Ltd
4-BROMO-1-BUTYNE pictures 2025-04-04 4-BROMO-1-BUTYNE
38771-21-0
1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
4-Bromo-1-butyne pictures 2021-07-13 4-Bromo-1-butyne
38771-21-0
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
  • 4-Bromo-1-butyne pictures
  • 4-Bromo-1-butyne
    38771-21-0
  • $10.00-15.00
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd

4-Bromo-1-butyne Spectrum

4-BROMO-1-BUTYNE, 98%4-BROMO-1-BUTYNE, 98%4-BROMO-1-BUTYNE, 98%4-BROMO-1-BUTYNE, 98% 4-Bromo-1-butyne,1-Bromo-3-butyne 1-Bromo-3-butyne 3-Butynyl Bromide 4-BroMo-1-butyne 97% 4-Bromo-1-butyne > 4-Bromo-1-butyne, 97%, for synthesis 1-Butyne, 4-bromo- (6CI,9CI) 4-bromobutyne 4-bromobut-1-yne - [B86644] 4-broMobut-1-yne 4-Bromo-1-butyne 38771-21-0 HCCCH2CH2Br Acetylenes Functionalized Acetylenes