ChemicalBook >> CAS DataBase List >>2-Chloro-4-nitroaniline

2-Chloro-4-nitroaniline

CAS No.
121-87-9
Chemical Name:
2-Chloro-4-nitroaniline
Synonyms
ORTHO CHLORO PARA NITRO ANILINE;OCPNA;ocpn;OR015002;oro-4-nitroaniL;Chloro-4-nitroanil;2-Chloro-4-nitroanil;2-Chlor-4-nitroanilin;o-chloro-nitroaniline;4-Chloro-nitroaniline
CBNumber:
CB6134260
Molecular Formula:
C6H5ClN2O2
Molecular Weight:
172.57
MDL Number:
MFCD00007665
MOL File:
121-87-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-04 16:00:12

2-Chloro-4-nitroaniline Properties

Melting point 107 °C
Boiling point 320℃
Density 1.5000
bulk density 850kg/m3
refractive index 1.6460 (estimate)
Flash point 205 °C
storage temp. Store below +30°C.
solubility 0.23g/l
pka -1.05±0.10(Predicted)
form powder to crystal
color Light yellow to Yellow to Orange
PH 7 (0.23g/l, H2O, 20℃)
Water Solubility 0.23 g/L (20 ºC)
BRN 638657
Henry's Law Constant 1.0×103 mol/(m3Pa) at 25℃, Altschuh et al. (1999)
Stability Stable. Incompatible with strong oxidizing agents, strong bases, strong acids.
InChI 1S/C6H5ClN2O2/c7-5-3-4(9(10)11)1-2-6(5)8/h1-3H,8H2
InChIKey LOCWBQIWHWIRGN-UHFFFAOYSA-N
SMILES Nc1ccc(cc1Cl)[N+]([O-])=O
CAS DataBase Reference 121-87-9(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII XSA3ZX337B
NIST Chemistry Reference Benzenamine, 2-chloro-4-nitro-(121-87-9)
EPA Substance Registry System 2-Chloro-4-nitroaniline (121-87-9)
UNSPSC Code 12352116
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H411
Precautionary statements  P273-P301+P312+P330
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn,N
Risk Statements  22-51/53
Safety Statements  22-24-61
RIDADR  UN 2237 (CHLORONITROANILINES)
WGK Germany  2
RTECS  BX1400000
Autoignition Temperature 971 °F
TSCA  TSCA listed
HS Code  2921 42 00
HazardClass  6.1
PackingGroup  III
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 4 Oral
Aquatic Chronic 2
Hazardous Substances Data 121-87-9(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 6430 mg/kg
REACH Registrations Active
Limited Quantities 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
0
2 0

2-Chloro-4-nitroaniline price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 101656 2-Chloro-4-nitroaniline 99% 121-87-9 50g $56.5 2026-04-30 Buy
TCI Chemical C0214 2-Chloro-4-nitroaniline >98.0%(GC) 121-87-9 25g $43 2026-04-30 Buy
Apolloscientific OR015002 2-Chloro-4-nitroaniline 98% 121-87-9 5g $21 2026-06-04 Buy
Apolloscientific OR015002 2-Chloro-4-nitroaniline 98% 121-87-9 25g $55 2026-06-04 Buy
Activate Scientific AS32941 2-Chloro-4-nitroaniline 98% 121-87-9 5g $23 2026-06-04 Buy
Product number Packaging Price Buy
101656 50g $56.5 Buy
C0214 25g $43 Buy
OR015002 5g $21 Buy
OR015002 25g $55 Buy
AS32941 5g $23 Buy

2-Chloro-4-nitroaniline Chemical Properties, Uses, Production

Chemical Properties

yellow crystalline powder

Uses

Intermediate in manufacture of dyes.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 5039, 1986 DOI: 10.1021/jo00375a062

General Description

Yellow crystalline powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

2-Chloro-4-nitroaniline can react with oxidizing materials.

Hazard

Toxic by ingestion and inhalation.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

99-54-7
121-87-9
Synthesis of 2-Chloro-4-nitroaniline from 3,4-Dichloronitrobenzene
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2-chloro-4-nitro-anilin 2-chloro-4-nitro-benzenamin 2-CHLORO-4-NITROBENZAMINE 2-Chlor-4-nitroanilin 2-Chloro-4-nitroaniline, 98+% 2-Chloro-4-nitroaniline,99% 2-Chloro-4-nitroanil 2-Chloro-4-nitroaniline2-Chloro-4-nitroaniline 2-CHLORO-4-NITROANILINE FOR SYNTHESIS Chloro-4-nitroanil 2-Chloro-4-nitroanyline 2-Chloro-4-nitroaniline, 97+% 2-Chloro-4-nitroaniline≥ 98% (GC) o-Chloro-p-nitroaniline 2-chloro-4-nitro-Benzenamine 1-Amino-2-chloro-4-nitrobenzene 4-CHLORO-2-NITROANILINE, 1000MG, NEAT 2-CHLORO-4-NITROANILINE WET 97% orthoChloro-p-Nitroaniline o-chloro-nitroaniline 2-/-4-CHLORONITROANILIN p-Nitro-o-chloroaniline 2-chloro-4-nitrobenzeneamine Benzenamine,2-chloro-4-nitro- LABOTEST-BB LT00030789 2-Chloro-4-nitrobenzenamine 2-CHLORO-4-NITRO-PHENYLAMINE 2-CHLORO-4-NITROANILINE 4-NITRO-2-CHLOROANILINE ocpn O-CHLORO-P-NITRO ANILINE 1-AMINO-2-CHLORO-4-NITROBENZENE 2-Chloro-4-nitroaniline > oro-4-nitroaniL 2-Chloro-4-nitroaniline 121-87-9 OR015002 4-Chloro-nitroaniline Ortho Chloro Para Nitro Aniline (OCPNA)/2-Chloro-4-nitroaniline C11452800 2-Chloro-4-nitroaniline Flufenamic Acid Impurity 26 OCPNA ORTHO CHLORO PARA NITRO ANILINE 121-87-9 ClC6H3NO2NH2 Organic Nonlinear Optical Materials Organic Building Blocks Nitrogen Compounds Building Blocks Amines C2 to C6 Functional Materials Organic Nonlinear Optical Materials pharmacetical Intermediates of Dyes and Pigments