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(3-Formyl-phenyl)-carbamic acid tert-butyl ester

(3-Formyl-phenyl)-carbamic acid tert-butyl ester Structure
(3-Formyl-phenyl)-carbamic acid tert-butyl ester structure
CAS No.
176980-36-2
Chemical Name:
(3-Formyl-phenyl)-carbamic acid tert-butyl ester
Synonyms
3-(BOC-AMino)benzaldehyde;tert-butyl 3-formylphenylcarbamate;tert-butylN-(3-formylphenyl)carbamate;3-(tert-Butoxycarbonylamino)benzaldehyde;(3-Formyl-phenyl)-carbamic acid tert-butyl ester;Carbamic acid, N-(3-formylphenyl)-, 1,1-dimethylethyl ester
CBNumber:
CB6153719
Molecular Formula:
C12H15NO3
Molecular Weight:
221.25
MDL Number:
MFCD06660380
MOL File:
176980-36-2.mol
MSDS File:
SDS
Last updated:2026-09-12 18:53:56
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(3-Formyl-phenyl)-carbamic acid tert-butyl ester Properties

Melting point 88℃
Boiling point 291℃
Density 1.163
Flash point 130℃
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka 13.50±0.70(Predicted)
form solid
color Beige
InChI 1S/C12H15NO3/c1-12(2,3)16-11(15)13-10-6-4-5-9(7-10)8-14/h4-8H,1-3H3,(H,13,15)
InChIKey JEUBPGIHGQWLAJ-UHFFFAOYSA-N
SMILES O=CC1=CC(NC(OC(C)(C)C)=O)=CC=C1
UNSPSC Code 12352200
NACRES NA.21

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H332-H335
Precautionary statements  P261-P280-P305+P351+P338
RIDADR  UN2811
HS Code  2913000090
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Oral

(3-Formyl-phenyl)-carbamic acid tert-butyl ester price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR962658 3-(BOC-Amino)benzaldehyde >95% 176980-36-2 250mg $21 2026-06-04 Buy
Apolloscientific OR962658 3-(BOC-Amino)benzaldehyde >95% 176980-36-2 1g $24 2026-06-04 Buy
Apolloscientific OR962658 3-(BOC-Amino)benzaldehyde >95% 176980-36-2 5g $104 2026-06-04 Buy
Apolloscientific OR962658 3-(BOC-Amino)benzaldehyde >95% 176980-36-2 25g $294 2026-06-04 Buy
Apolloscientific OR962658 3-(BOC-Amino)benzaldehyde >95% 176980-36-2 100g $1117 2026-06-04 Buy
Product number Packaging Price Buy
OR962658 250mg $21 Buy
OR962658 1g $24 Buy
OR962658 5g $104 Buy
OR962658 25g $294 Buy
OR962658 100g $1117 Buy

(3-Formyl-phenyl)-carbamic acid tert-butyl ester Chemical Properties, Uses, Production

Synthesis

BOC-3-AMINOBENZYLALCOHOL

118684-31-4

(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER

176980-36-2

General procedure for the synthesis of tert-butyl (3-formylphenyl)-carbamate from tert-butyl (3-(hydroxymethyl)phenyl)carbamate: activated manganese dioxide (7.8 g, 90 mmol) was added to a solution of dichloromethane (50 mL) containing 3-(tert-butoxycarbonylamino)-benzyl alcohol (2.0 g, 9.0 mmol). The resulting suspension was stirred and reacted at room temperature for 16 hours. Upon completion of the reaction, the mixture was filtered through a diatomaceous earth pad and the filtrate was concentrated under reduced pressure to give 1.7 g (85% yield) of the target product. The product was characterized by 1H NMR (400 MHz, CDCl3): δ 9.97 (s, 1H), 7.92 (t, J = 1.8 Hz, 1H), 7.63 (dd, J = 8.0,1.1 Hz, 1H), 7.55 (ddd, J = 7.6,1.4,1.1 Hz, 1H), 7.44 (t, J = 7.6 Hz, 1H), and 1.53 (s, 9H).

References

[1] Chemistry - A European Journal, 2016, vol. 22, # 26, p. 8814 - 8822
[2] Angewandte Chemie - International Edition, 2017, vol. 56, # 49, p. 15746 - 15750
[3] Angew. Chem., 2017, vol. 129, p. 15952 - 15957,6
[4] Patent: WO2018/114965, 2018, A1. Location in patent: Page/Page column 27
[5] Chemistry of Materials, 2011, vol. 23, # 21, p. 4844 - 4856

(3-Formyl-phenyl)-carbamic acid tert-butyl ester Preparation Products And Raw materials

Raw materials

Boc-3-aminobenzylalcohol Oxalyl chloride Dichloromethane Manganese dioxide

Preparation Products

(3-Formyl-phenyl)-carbamic acid tert-butyl ester Suppliers

Global Suppliers ( 86)
Supplier Tel Email Country ProdList Advantage
Adamas Reagent, Ltd. 400-6009262 15618770481 yhx@titansci.com China 14098 59
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 marketing@accelachem.com China 10972 64
Shanghai Sphchem Co., Ltd. 021-56491756 13512199871 2819742715@qq.com China 3994 55
Chengdu Forest Science and Technology Development Co., Ltd. 18030648795 18030648795 sales@cdforestchem.com China 1996 58
Shanghai Topbiochem Technology Co., Ltd 021-58170097 info@topbiochem.com China 9510 58
Nanjing Norris-Pharm Technology Co., Ltd 13901585132 sales@norris-pharm.com China 8869 55
9ding chemical ( Shanghai) Limited 4009209199 sales@9dingchem.com China 18201 56
SynAsst Chemical. 021-60343070 China 12731 55
Shanghai Raise Chemical Technology Co.,Ltd 15026594951 rs@raise-chem.com China 4905 55
Shanghai Raise Chemical Technology Co.,Ltd +86-021-50935922 China 7854 55
Supplier Advantage
Adamas Reagent, Ltd. 59
Accela ChemBio Co.,Ltd. 64
Shanghai Sphchem Co., Ltd. 55
Chengdu Forest Science and Technology Development Co., Ltd. 58
Shanghai Topbiochem Technology Co., Ltd 58
Nanjing Norris-Pharm Technology Co., Ltd 55
9ding chemical ( Shanghai) Limited 56
SynAsst Chemical. 55
Shanghai Raise Chemical Technology Co.,Ltd 55
Shanghai Raise Chemical Technology Co.,Ltd 55

View Latest Price from (3-Formyl-phenyl)-carbamic acid tert-butyl ester manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER pictures 2020-01-13 (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
176980-36-2
 $1.00 1KG 99% 100KG Career Henan Chemical Co

(3-Formyl-phenyl)-carbamic acid tert-butyl ester Spectrum

(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER(176980-36-2)1HNMR

176980-36-2 ((3-Formyl-phenyl)-carbamic acid tert-butyl ester) Related Search:

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tert-butyl 3-formylphenylcarbamate tert-butylN-(3-formylphenyl)carbamate 3-(tert-Butoxycarbonylamino)benzaldehyde Carbamic acid, N-(3-formylphenyl)-, 1,1-dimethylethyl ester 3-(BOC-AMino)benzaldehyde (3-Formyl-phenyl)-carbamic acid tert-butyl ester 176980-36-2