(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
- CAS No.
- 176980-36-2
- Chemical Name:
- (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
- Synonyms
- 3-(BOC-AMino)benzaldehyde;tert-butyl 3-formylphenylcarbamate;tert-butylN-(3-formylphenyl)carbamate;3-(tert-Butoxycarbonylamino)benzaldehyde;(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER;Carbamic acid, N-(3-formylphenyl)-, 1,1-dimethylethyl ester
- CBNumber:
- CB6153719
- Molecular Formula:
- C12H15NO3
- Molecular Weight:
- 221.25
- MDL Number:
- MFCD06660380
- MOL File:
- 176980-36-2.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 3-(BOC-Amino)benzaldehyde >95% | OR962658 | 250mg | $21 |
| 3-(BOC-Amino)benzaldehyde >95% | OR962658 | 1g | $24 |
| 3-(BOC-Amino)benzaldehyde >95% | OR962658 | 5g | $104 |
| 3-(BOC-Amino)benzaldehyde >95% | OR962658 | 25g | $294 |
| 3-(BOC-Amino)benzaldehyde >95% | OR962658 | 100g | $1117 |
| Melting point | 88℃ |
|---|---|
| Boiling point | 291℃ |
| Density | 1.163 |
| Flash point | 130℃ |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| pka | 13.50±0.70(Predicted) |
| form | solid |
| color | Beige |
| InChI | 1S/C12H15NO3/c1-12(2,3)16-11(15)13-10-6-4-5-9(7-10)8-14/h4-8H,1-3H3,(H,13,15) |
| InChIKey | JEUBPGIHGQWLAJ-UHFFFAOYSA-N |
| SMILES | O=CC1=CC(NC(OC(C)(C)C)=O)=CC=C1 |
| UNSPSC Code | 12352200 |
| NACRES | NA.21 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H332-H335 |
| Precautionary statements | P261-P280-P305+P351+P338 |
| RIDADR | UN2811 |
| HS Code | 2913000090 |
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
| Hazard Classifications | Acute Tox. 3 Oral |
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER price More Price(58)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | OR962658 | 3-(BOC-Amino)benzaldehyde >95% | 176980-36-2 | 250mg | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR962658 | 3-(BOC-Amino)benzaldehyde >95% | 176980-36-2 | 1g | $24 | 2026-06-04 | Buy |
| Apolloscientific | OR962658 | 3-(BOC-Amino)benzaldehyde >95% | 176980-36-2 | 5g | $104 | 2026-06-04 | Buy |
| Apolloscientific | OR962658 | 3-(BOC-Amino)benzaldehyde >95% | 176980-36-2 | 25g | $294 | 2026-06-04 | Buy |
| Apolloscientific | OR962658 | 3-(BOC-Amino)benzaldehyde >95% | 176980-36-2 | 100g | $1117 | 2026-06-04 | Buy |
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER Chemical Properties,Uses,Production
Synthesis
118684-31-4
176980-36-2
General procedure for the synthesis of tert-butyl (3-formylphenyl)-carbamate from tert-butyl (3-(hydroxymethyl)phenyl)carbamate: activated manganese dioxide (7.8 g, 90 mmol) was added to a solution of dichloromethane (50 mL) containing 3-(tert-butoxycarbonylamino)-benzyl alcohol (2.0 g, 9.0 mmol). The resulting suspension was stirred and reacted at room temperature for 16 hours. Upon completion of the reaction, the mixture was filtered through a diatomaceous earth pad and the filtrate was concentrated under reduced pressure to give 1.7 g (85% yield) of the target product. The product was characterized by 1H NMR (400 MHz, CDCl3): δ 9.97 (s, 1H), 7.92 (t, J = 1.8 Hz, 1H), 7.63 (dd, J = 8.0,1.1 Hz, 1H), 7.55 (ddd, J = 7.6,1.4,1.1 Hz, 1H), 7.44 (t, J = 7.6 Hz, 1H), and 1.53 (s, 9H).
References
[1] Chemistry - A European Journal, 2016, vol. 22, # 26, p. 8814 - 8822
[2] Angewandte Chemie - International Edition, 2017, vol. 56, # 49, p. 15746 - 15750
[3] Angew. Chem., 2017, vol. 129, p. 15952 - 15957,6
[4] Patent: WO2018/114965, 2018, A1. Location in patent: Page/Page column 27
[5] Chemistry of Materials, 2011, vol. 23, # 21, p. 4844 - 4856
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
(3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52704 | 58 |
| Zhejiang J&C Biological Technology Co.,Limited | +1-2135480471 +1-2135480471; | sales@sarms4muscle.com | China | 10457 | 58 |
| Nextpeptide Inc | +86-0571-81612335 +8613336028439 | sales@nextpeptide.com | China | 19908 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178; | peter68@ptchemgroup.com | China | 35425 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +86-571-86217390; +8618058761490 | info@gihichemicals.com | China | 49892 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| Suzhou ARTK Medchem Co., Ltd. | +8618118463618 | sales1@artkmedchem.com | China | 39021 | 58 |
View Lastest Price from (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2020-01-13 | (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
176980-36-2
|
$1.00 | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- (3-FORMYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
176980-36-2
- $1.00
- 99%
- Career Henan Chemical Co
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