1-Bromo-4-(bromomethyl)naphthalene
- CAS No.
- 79996-99-9
- Chemical Name:
- 1-Bromo-4-(bromomethyl)naphthalene
- Synonyms
- 1-Bromo-4-(bromomethyl)naphthalene;Naphthalene,1-bromo-4-(bromomethyl)-
- CBNumber:
- CB6153890
- Molecular Formula:
- C11H8Br2
- Molecular Weight:
- 299.99
- MDL Number:
- MFCD07363811
- MOL File:
- 79996-99-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
1-Bromo-4-(bromomethyl)naphthalene price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Activate Scientific | AS115008 | 1-Bromo-4-(bromomethyl)naphthalene 97% | 79996-99-9 | 1g | $64 | 2026-06-04 | Buy |
| Activate Scientific | AS115008 | 1-Bromo-4-(bromomethyl)naphthalene 97% | 79996-99-9 | 5g | $156 | 2026-06-04 | Buy |
| Activate Scientific | AS115008 | 1-Bromo-4-(bromomethyl)naphthalene 97% | 79996-99-9 | 25g | $546 | 2026-06-04 | Buy |
| Matrix Scientific | 092873 | 1-Bromo-4-(bromomethyl)naphthalene | 79996-99-9 | 1.00g | $189 | 2026-05-18 | Buy |
| Matrix Scientific | 092873 | 1-Bromo-4-(bromomethyl)naphthalene | 79996-99-9 | 5.00g | $504 | 2026-05-18 | Buy |
1-Bromo-4-(bromomethyl)naphthalene Chemical Properties, Uses, Production
Synthesis
6627-78-7
79996-99-9
General procedure for the synthesis of 1-bromo-4-bromomethylnaphthalene from 1-bromo-4-methylnaphthalene: 3.3 g (10.2 mmol, 1.5 eq.) of 4-bromo-1-methylnaphthalene was accurately weighed and added to 30 mL of ethyl acetate, followed by tetrabutylammonium bromide. The reaction mixture was stirred at reflux for 9 hours at 70 °C. The reaction progress was monitored by thin layer chromatography (TLC) and the reaction was terminated after confirming complete conversion of the feedstock. The reaction mixture was filtered and the filter cake was collected. The filter cake was stirred with 30 mL of ethyl acetate for 2 h at room temperature and filtered again to give 1.60 g of 1-bromo-4-(bromomethyl)naphthalene as a light yellow solid in 77.43% yield.
References
[1] European Journal of Organic Chemistry, 2006, # 10, p. 2329 - 2335
[2] Journal of Organic Chemistry, 1999, vol. 64, # 4, p. 1387 - 1390
[3] Advanced Synthesis and Catalysis, 2018, vol. 360, # 21, p. 4197 - 4204
[4] Patent: CN105906530, 2016, A. Location in patent: Paragraph 0091; 0092; 0093; 0094; 0095
[5] Organic Letters, 2008, vol. 10, # 14, p. 3105 - 3108
1-Bromo-4-(bromomethyl)naphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Shanghai Topbiochem Technology Co., Ltd | 021-58170097 | info@topbiochem.com | China | 9510 | 58 |
| Nanjing Norris-Pharm Technology Co., Ltd | 13901585132 | sales@norris-pharm.com | China | 8869 | 55 |
| Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. | 025-66113011 13913916777 | cfzhang@aikonchem.com | China | 19902 | 55 |
| 9ding chemical ( Shanghai) Limited | 4009209199 | sales@9dingchem.com | China | 18201 | 56 |
| Shanghai Aladdin Bio-Chem Technology Co.,LTD | 400-6206333 13167063860 | anhua.mao@aladdin-e.com | China | 29985 | 65 |
| Shanghai ShiXian Chemical Technology Co., Ltd. | 13764359345 | 990877971@qq.com | China | 1917 | 50 |
| Zhengzhou Alfachem Co., Ltd. | 0371-53765687 18937137882 | 3969243885@qq.com | China | 7734 | 55 |
