1-(Bromomethyl)naphthalene
- CAS No.
- 3163-27-7
- Chemical Name:
- 1-(Bromomethyl)naphthalene
- Synonyms
- 1-BROMOMETHYL NAPHTHALENE;CL015;1-(Bromomethyl)napht;1-Naphtylmethyl bromide;(1-Naphtyl)bromomethane;1-Naphthylmethyl bromide;1-(Bromomthy)Naphthalene;1-(Bromomethyl)phthalene;1-(Brommethyl)naphthalen;1-(Bromomethy)naphthalene
- CBNumber:
- CB3337682
- Molecular Formula:
- C11H9Br
- Molecular Weight:
- 221.09
- MDL Number:
- MFCD00010804
- MOL File:
- 3163-27-7.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 52-55°C |
|---|---|
| Boiling point | 213°C/100mmHg |
| Density | 1.44 |
| refractive index | 1.6600 |
| storage temp. | Inert atmosphere,2-8°C |
| form | Powder |
| color | Off-white |
| Water Solubility | Slightly soluble in water. |
| λmax | 292nm(Cyclohexane)(lit.) |
| CAS DataBase Reference | 3163-27-7(CAS DataBase Reference) |
| NIST Chemistry Reference | 1-(Bromomethyl)naphthalene(3163-27-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H318-H290-H314 | |||||||||
| Precautionary statements | P234-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501-P260h-P301+P330+P331-P303+P361+P353-P305+P351+P338-P501a | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22-36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| RIDADR | 3261 | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29036990 | |||||||||
| NFPA 704 |
|
1-(Bromomethyl)naphthalene price More Price(49)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | B4563 | 1-(Bromomethyl)naphthalene >98.0%(GC) | 3163-27-7 | 5g | $43 | 2026-04-30 | Buy |
| TCI Chemical | B4563 | 1-(Bromomethyl)naphthalene >98.0%(GC) | 3163-27-7 | 25g | $209 | 2026-04-30 | Buy |
| Usbiological | 228545 | 1-(Bromomethyl)naphthalene, ≥95% 95% | 3163-27-7 | 5g | $193 | 2026-06-03 | Buy |
| Usbiological | 228545 | 1-(Bromomethyl)naphthalene, ≥95% 95% | 3163-27-7 | 25g | $273 | 2026-06-03 | Buy |
| Usbiological | 228545 | 1-(Bromomethyl)naphthalene, ≥95% 95% | 3163-27-7 | 100g | $588 | 2026-06-03 | Buy |
1-(Bromomethyl)naphthalene Chemical Properties, Uses, Production
Chemical Properties
Off-white powder
Uses
It is employed as a intermediate for organic synthesis and pharmaceutical.
Synthesis
4780-79-4
3163-27-7
The general procedure for the synthesis of 1-bromomethylnaphthalene from 1-naphthalenemethanol: Ethyl α,α-diacetoacetate (0.41 mmol, 1.2 eq.), 1-naphthalenemethanol (0.34 mmol, 1.0 eq.), and triphenylphosphine (0.68 mmol, 2.0 eq.) were added to 3 mL of dichloroethane (DCE) at room temperature and the reaction took place in air. The progress of the reaction was monitored by thin layer chromatography (TLC) during the reaction. Upon completion of the reaction, the reaction was quenched by the addition of 3 mL of water, followed by extraction with ethyl acetate (3 x 3 mL). The organic phases were combined, washed with saturated saline, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography, and the eluent was petroleum ether or a mixed solvent of petroleum ether and ethyl acetate, and the target product 1-bromomethyl naphthalene was finally obtained.
References
[1] Synthetic Communications, 2010, vol. 40, # 11, p. 1646 - 1649
[2] Organic Letters, 2003, vol. 5, # 8, p. 1167 - 1169
[3] Tetrahedron Letters, 2014, vol. 55, # 1, p. 90 - 93
[4] Canadian Journal of Chemistry, 1981, vol. 59, p. 2629 - 2641
[5] Tetrahedron, 2003, vol. 59, # 52, p. 10453 - 10463
1-(Bromomethyl)naphthalene Preparation Products And Raw materials
Raw materials
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Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Beijing dtftchem Technology Co., Ltd. | 010-60275820 13031183356 | elainezt@sina.com | China | 1386 | 62 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11777 | 60 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Shijiazhuang Outejia Chemical Co. LTD | 0311-87795622 | sales@adonghui.com | China | 54 | 64 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
View Latest Price from 1-(Bromomethyl)naphthalene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-07-08 | 1-(Bromomethyl)naphthalene
3163-27-7
|
$1.00 | 1Kg | 98% | 20T | Shaanxi Dideu Medichem Co. Ltd | |
 |
2021-07-13 | 1-(Bromomthy)Naphthalene
3163-27-7
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
 |
2021-07-09 | 1-(Bromomthy)Naphthalene
3163-27-7
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-
- 1-(Bromomethyl)naphthalene
3163-27-7
- $1.00
- 98%
- Shaanxi Dideu Medichem Co. Ltd
-
- 1-(Bromomthy)Naphthalene
3163-27-7
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- 1-(Bromomthy)Naphthalene
3163-27-7
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
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