3-(Difluoromethoxy)benzaldehyde
- CAS No.
- 85684-61-3
- Chemical Name:
- 3-(Difluoromethoxy)benzaldehyde
- Synonyms
- 3-(DIFLUOROMETHOXY)BENZALDEHYDE;Benzaldehyde,3-(difluoroMethoxy)-;3-(Difluoromethoxy)benzaldehyde98%;1-(Difluoromethoxy)-3-formylbenzene;3-(Difluoromethoxy)benzaldehyde 98%
- CBNumber:
- CB6164946
- Molecular Formula:
- C8H6F2O2
- Molecular Weight:
- 172.13
- MDL Number:
- MFCD00236222
- MOL File:
- 85684-61-3.mol
- MSDS File:
- SDS
| Boiling point | 80-90°C/0.3mm |
|---|---|
| Density | 1.300 |
| refractive index | n20/D 1.496(lit.) |
| Flash point | 107 °C |
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| form | liquid |
| color | Colourless to light yellow |
| Sensitive | Air Sensitive |
| CAS DataBase Reference | 85684-61-3(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 2913000090 | |||||||||
| NFPA 704 |
|
3-(Difluoromethoxy)benzaldehyde price More Price(44)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | FD64017 | 3-(Difluoromethoxy)benzaldehyde | 85684-61-3 | 10g | $900 | 2026-06-04 | Buy |
| Biosynth | FD64017 | 3-(Difluoromethoxy)benzaldehyde | 85684-61-3 | 5g | $900 | 2026-06-04 | Buy |
| Biosynth | FD64017 | 3-(Difluoromethoxy)benzaldehyde | 85684-61-3 | 2g | $900 | 2026-06-04 | Buy |
| Biosynth | FD64017 | 3-(Difluoromethoxy)benzaldehyde | 85684-61-3 | 25g | $900 | 2026-06-04 | Buy |
| Biosynth | FD64017 | 3-(Difluoromethoxy)benzaldehyde | 85684-61-3 | 1g | $900 | 2026-06-04 | Buy |
3-(Difluoromethoxy)benzaldehyde Chemical Properties,Uses,Production
Synthesis
1895-39-2
100-83-4
85684-61-3
A solution was prepared in DMF (75 mL) with sodium chlorodifluoroacetate (12.48 g, 82 mmol) and m-hydroxybenzaldehyde (5.00 g, 40.9 mmol). The solution was added dropwise to a solution of DMF (25 mL) containing potassium carbonate (8.49 g, 61.4 mmol) over a period of 3 hours, and the reaction temperature was maintained at 95 °C. After the dropwise addition, the reaction continued to be stirred at 95 °C for 2 hours. After completion of the reaction, the reaction mixture was cooled to room temperature. The reaction mixture was diluted with deionized water (100 mL) and subsequently extracted with ethyl acetate (4 x 50 mL). The organic phases were combined, washed with 10% (w/v) aqueous lithium chloride (3 x 25 mL), dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give the crude product. Purification by fast column chromatography (eluent: 15% ethyl acetate/hexane) afforded 3-(difluoromethoxy)benzaldehyde (2.50 g, 14.52 mmol, 36% yield) as a yellow oil. The nuclear magnetic resonance (NMR) spectrum of the product was consistent with the expected structure.
References
[1] Patent: WO2014/127042, 2014, A1. Location in patent: Paragraph 0471
3-(Difluoromethoxy)benzaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Ark Pharm, Inc. | 847-367-3680 | sales@arkpharminc.com | United States | 1669 | 56 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Shanghai Sinch Parmaceuticals Tech. Co. Ltd. | +86-21-54098501 | sales@sinch.com.cn | China | 11592 | 64 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Wuhan Arike Technology Co., Ltd. | 027- 51832457 94518350 | China | 746 | 62 |
View Lastest Price from 3-(Difluoromethoxy)benzaldehyde manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-10 | 3-(Difluoromethoxy)benzaldehyde
85684-61-3
|
$3.00 | 1KG | 98% | 200KG | Career Henan Chemical Co |
-
- 3-(Difluoromethoxy)benzaldehyde
85684-61-3
- $3.00
- 98%
- Career Henan Chemical Co
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