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3,4-Dichlorobenzyl alcohol

CAS No.
1805-32-9
Chemical Name:
3,4-Dichlorobenzyl alcohol
Synonyms
RARECHEM AL BD 0536;3,4-Dichlorobenzyl a;Miconazole impurity 2;LABOTEST-BB LT02003790;Miconazole Impurity 17;3,4-DICHLORBENZYL ALCOHOL;3,4-DICHLOROBENZYL ALCOHOL;3,4-DICHLOROBENZENEALCOHOL;3,4-Dichlorobenzenemethanol;3,4-Dichlorobenzoyl alcohol
CBNumber:
CB6182382
Molecular Formula:
C7H6Cl2O
Molecular Weight:
177.03
MDL Number:
MFCD00004633
MOL File:
1805-32-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 02:10:32
Product description Number Pack Size Price
2,4-Dichlorobenzyl alcohol impurity C European Pharmacopoeia (EP) Reference Standard Y0001622 25 mg $161
3,4-Dichlorobenzyl alcohol for synthesis 8.41133 10g $69.7
2,4-Dichlorobenzyl alcohol impurity C European Pharmacopoeia (EP) Reference Standard Y0001622 y0001622 $147
3,4-Dichlorobenzyl Alcohol >98.0%(GC) D1748 25g $36
3,4-Dichlorobenzyl alcohol TRC-D439690-5G 5g $68
More product size

3,4-Dichlorobenzyl alcohol Properties

Melting point 35-38 °C(lit.)
Boiling point 148-151 °C(lit.)
Density 1.2970 (rough estimate)
refractive index 1.5570 (estimate)
Flash point >110°C
storage temp. 2-8°C
pka 13.70±0.10(Predicted)
form solid
color White to Almost white
BRN 2082362
InChI 1S/C7H6Cl2O/c8-6-2-1-5(4-10)3-7(6)9/h1-3,10H,4H2
InChIKey FVJIUQSKXOYFKG-UHFFFAOYSA-N
SMILES Clc1c(ccc(c1)CO)Cl
CAS DataBase Reference 1805-32-9(CAS DataBase Reference)
FDA UNII G2EM844U91
NIST Chemistry Reference 3,4-Dichlorobenzyl alcohol(1805-32-9)
UNSPSC Code 41116107
NACRES NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H315-H318-H335
Precautionary statements  P261-P264-P280-P301+P312-P302+P352-P305+P351+P338
target organs Respiratory system
Hazard Codes  T,Xi,Xn,N
Risk Statements  23/24/25-21/22-51/53-41-37/38-22
Safety Statements  27-28-36/37/39-45-36/37-61-26
RIDADR  UN 2811 6.1/PG 3
WGK Germany  3
Hazard Note  Irritant
HazardClass  6.1
PackingGroup  III
HS Code  29062900
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
NFPA 704
1
2 0

3,4-Dichlorobenzyl alcohol price More Price(62)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich Y0001622 2,4-Dichlorobenzyl alcohol impurity C European Pharmacopoeia (EP) Reference Standard 1805-32-9 25 mg $161 2026-04-30 Buy
Sigma-Aldrich 8.41133 3,4-Dichlorobenzyl alcohol for synthesis 1805-32-9 10g $69.7 2026-04-30 Buy
Sigma-Aldrich Y0001622 2,4-Dichlorobenzyl alcohol impurity C European Pharmacopoeia (EP) Reference Standard 1805-32-9 y0001622 $147 2024-03-01 Buy
TCI Chemical D1748 3,4-Dichlorobenzyl Alcohol >98.0%(GC) 1805-32-9 25g $36 2026-04-30 Buy
TRC TRC-D439690-5G 3,4-Dichlorobenzyl alcohol 1805-32-9 5g $68 2026-06-03 Buy
Product number Packaging Price Buy
Y0001622 25 mg $161 Buy
8.41133 10g $69.7 Buy
Y0001622 y0001622 $147 Buy
D1748 25g $36 Buy
TRC-D439690-5G 5g $68 Buy

3,4-Dichlorobenzyl alcohol Chemical Properties,Uses,Production

Chemical Properties

WHITE LOW MELTING SOLID

Uses

2,4-Dichlorobenzyl alcohol impurity C EP Reference standard, intended for use in laboratory tests only as specifically prescribed in the European Pharmacopoeia.

Synthesis

3,4-Dichlorobenzaldehyde

6287-38-3

3,4-Dichlorobenzyl alcohol

1805-32-9

The general procedure for the synthesis of 3,4-dichlorobenzyl alcohol from 3,4-dichlorobenzaldehyde was as follows: 3,4-dichlorobenzaldehyde (1 mmol) was dissolved in 10 mL of methanol (ethanol was used in the case of ketone substrates) and the solution was cooled to 0°C. Subsequently, NaBH4 (3 mmol) was added to the reaction system in batches with continuous stirring until the reaction was complete, and the progress of the reaction was monitored by TLC (unfolding agent ratio of 9:1 heptane/ethyl acetate). Upon completion of the reaction, the reaction was quenched with 0.1N NaOH solution (10 mL), followed by three extractions with ethyl acetate. The organic phases were combined, washed with saturated saline and dried with anhydrous Na2SO4. The solvent was removed by concentration under reduced pressure and the yellow oily crude product obtained was purified by flash column chromatography.

Purification Methods

Crystallise the alcohol from EtOH (m 32-34o) or water (m 38o, needles). Its solubility at 20o is 1g in 1250mL of H2O. [Beilstein 6 H 445, 6 III 1558, 6 IV 2598.]

References

[1] European Journal of Medicinal Chemistry, 2016, vol. 108, p. 564 - 576
[2] Synthetic Communications, 2002, vol. 32, # 2, p. 219 - 223
[3] Bulletin of the Korean Chemical Society, 2015, vol. 36, # 6, p. 1676 - 1680
[4] Phytochemistry, 1999, vol. 51, # 5, p. 621 - 627
[5] Journal of Medicinal Chemistry, 1999, vol. 42, # 6, p. 1007 - 1017

3,4-Dichlorobenzyl alcohol Preparation Products And Raw materials

Global( 193)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
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View Lastest Price from 3,4-Dichlorobenzyl alcohol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3,4-Dichlorobenzyl alcohol pictures 2025-04-04 3,4-Dichlorobenzyl alcohol
1805-32-9
1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.
3,4-Dichlorobenzyl alcohol pictures 2019-07-14 3,4-Dichlorobenzyl alcohol
1805-32-9
$1.00 1KG 99% 25kg Career Henan Chemical Co
3 4-DICHLOROBENZYL ALCOHOL 98% 3,4-DICHLOROBENZENEALCOHOL 3,4-DICHLOROBENZYL ALCOHOL 98+% 3,4-Dichlorobenzenemethanol (3,4-Dichlorophenyl)methanol Benzenemethanol, 3,4-dichloro- Benzyl alcohol, 3,4-dichloro- RARECHEM AL BD 0536 3,4-DICHLOROBENZYL ALCOHOL 3,4-DICHLORBENZYL ALCOHOL 3,4-dichloro-1-(hydroxymethyl)-benzene 3,4-Dichlorobenzyl a 2,4-Dichlorobenzyl alcohol impurity C 3,4-Dichlorobenzoyl alcohol LABOTEST-BB LT02003790 2,4-Dichlorobenzyl alcohol EP Impurity C 3,4-DichlorobenzylAlcohol> 2,4-Dichlorobenzyl alcohol impurity C CRS 3,4-DICHLOROBENZYL ALCOHOL FOR SYNTHESIS Miconazole Impurity 17 Miconazole impurity 2 3,4-Dichlorobenzyl alcohol,98% min 1805-32-9 1085-32-9 Benzhydrols, Benzyl & Special Alcohols