ALLYL IODIDE
- CAS No.
- 556-56-9
- Chemical Name:
- ALLYL IODIDE
- Synonyms
- 3-IODOPROPENE;3-IODO-1-PROPENE;CH2CHCH2I;Allyljodid;Allyliodid;3-Jodpropen;3-Iodpropen;ALLYL IODIDE;3-iodo-propen;3-Jod-1-propen
- CBNumber:
- CB6186678
- Molecular Formula:
- C3H5I
- Molecular Weight:
- 167.98
- MDL Number:
- MFCD00001094
- MOL File:
- 556-56-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | -99 °C |
|---|---|
| Boiling point | 102103°C |
| Density | 1.837 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 65 °F |
| storage temp. | 2-8°C |
| solubility | alcohol: miscible(lit.) |
| form | Liquid |
| color | Clear yellow to orange, red or red-brown |
| Water Solubility | Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water. |
| Sensitive | Air & Light Sensitive |
| Merck | 14,294 |
| BRN | 1697594 |
| Henry's Law Constant | 3.8×10-3 mol/(m3Pa) at 25℃, Hilal et al. (2008) |
| Dielectric constant | 6.1(19℃) |
| InChI | 1S/C3H5I/c1-2-3-4/h2H,1,3H2 |
| InChIKey | HFEHLDPGIKPNKL-UHFFFAOYSA-N |
| SMILES | ICC=C |
| CAS DataBase Reference | 556-56-9(CAS DataBase Reference) |
| FDA UNII | 46830QOA4D |
| EPA Substance Registry System | 1-Propene, 3-iodo- (556-56-9) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS05,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H300-H314-H225 | |||||||||
| Precautionary statements | P501-P270-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P303+P361+P353-P301+P330+P331-P363-P301+P310+P330-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405 | |||||||||
| PPE | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | C,T,F | |||||||||
| Risk Statements | 10-34-11 | |||||||||
| Safety Statements | 7-26-45-16 | |||||||||
| RIDADR | UN 1723 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | UD0450000 | |||||||||
| F | 8-13 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29033990 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Acute Tox. 2 Oral Eye Dam. 1 Flam. Liq. 2 Skin Corr. 1B |
|||||||||
| Limited Quantities | 1.0 L (0.3 gallon) (liquid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
ALLYL IODIDE price More Price(28)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 238325 | Allyl iodide 98% | 556-56-9 | 25g | $136 | 2026-04-30 | Buy |
| Sigma-Aldrich | 238325 | Allyl iodide 98% | 556-56-9 | 100g | $256 | 2026-04-30 | Buy |
| TCI Chemical | I0070 | Allyl Iodide (stabilized with Copper chip) >98.0%(GC) | 556-56-9 | 5g | $97 | 2026-04-30 | Buy |
| TCI Chemical | I0070 | Allyl Iodide (stabilized with Copper chip) >98.0%(GC) | 556-56-9 | 25g | $383 | 2026-04-30 | Buy |
| TRC | TRC-I119230-2.5G | 3-Iodoprop-1-ene | 556-56-9 | 2.5g | $84 | 2026-06-03 | Buy |
ALLYL IODIDE Chemical Properties, Uses, Production
Chemical Properties
clear orange, red or red-brown liquid
Uses
Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.
Synthesis Reference(s)
Synthetic Communications, 20, p. 41, 1990 DOI: 10.1080/00397919008054613
General Description
A yellow liquid with a pungent odor. Denser than water and insoluble in water. Hence sinks in water. Vapors are heavier than air. Flash point is less than 75°F. Very irritating to skin, eyes and mucous membranes. Poisonous by ingestion and inhalation. Used to make other chemicals.
Air & Water Reactions
Highly flammable. Darkens on exposure to light and air liberating Iodine [Merck 11th ed. 1989]. Insoluble in water.
Reactivity Profile
ALLYL IODIDE is moderately reactive. Incompatible with strong oxidizing and reducing agents. Also, incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
Health Hazard
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety Profile
Poison by inhalation and ingestion. Mutation data reported. A powerful irritant. A flammable liquid. Incompatible with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits hghly toxic fumes of I-. See also ALLYL COMPOUNDS and IODIDES.
Purification Methods
Purify allyl iodide in a dark room by washing with aqueous Na2SO3 to remove free iodine, then dry with MgSO4 and distil at 43o/90 mm or at atmospheric pressure to give a very pale yellow liquid. (This material, dissolved in hexane, can be stored in a light-protected tight container at -5o for up to three months before free iodine could be detected, by its colour in the solution.) Store it away from light. [Sibbett & Noyes J Am Chem Soc 75 761 1953, Beilstein 1 H 202, 1 I 84, 1 II 172, 1 III 714, 1 IV 761.]
ALLYL IODIDE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Anhui Enbang Biological Technology Co., Ltd. | 0551-68936860-8515 15357955825 | 15357955825@163.com | China | 82 | 55 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Beijing Donghualituo Techonlogy Development Co.,Ltd. | 010-88425576 | sales@dhltchem.com | China | 793 | 59 |
| New Energy Chemicals | 0515-82159099 13770142076 | info@njuchem.com | China | 251 | 65 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Beijing dtftchem Technology Co., Ltd. | 010-60275820 13031183356 | elainezt@sina.com | China | 1386 | 62 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 |
View Latest Price from ALLYL IODIDE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-13 | ALLYL IODIDE
556-56-9
|
$1.00 | 1KG | 98%-99.9% | 200kg | Career Henan Chemical Co |
-
- ALLYL IODIDE
556-56-9
- $1.00
- 98%-99.9%
- Career Henan Chemical Co
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