Diethyl allylmalonate
- CAS No.
- 2049-80-1
- Chemical Name:
- Diethyl allylmalonate
- Synonyms
- NSC 8777;Diethyl allyl;ETHYL ALLYLMALONATE;Diethyl allylmalote;ALLYLDIETHYLMALONATE;DIETHYL ALLYLMALONATE;Diethyl allyimalonate;DIETHYL 2-ALLYLMALONATE;Diethyl allylmalonate,97%;Allylmalonic acid diethyl
- CBNumber:
- CB9177941
- Molecular Formula:
- C10H16O4
- Molecular Weight:
- 200.23
- MDL Number:
- MFCD00009155
- MOL File:
- 2049-80-1.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Diethyl allylmalonate 95% | 446114 | 25ml | $48.2 |
| Diethyl Allylmalonate >98.0%(GC) | A0231 | 25g | $85 |
| Diethyl Allylmalonate >98.0%(GC) | A0231 | 500g | $944 |
| Diethyl allylmalonate | D443728 | 1g | $55 |
| Diethyl allylmalonate | M279 | 5g | $64 |
| More product size | |||
| Boiling point | 222-223 °C(lit.) |
|---|---|
| Density | 1.015 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 160 °F |
| storage temp. | Store below +30°C. |
| form | Liquid |
| pka | 12.63±0.46(Predicted) |
| color | Clear colorless to slightly yellow |
| Water Solubility | Not miscible or difficult to mix with water. |
| BRN | 1709466 |
| LogP | 1.990 (est) |
| CAS DataBase Reference | 2049-80-1(CAS DataBase Reference) |
| FDA UNII | M5ETZ38HUJ |
| NIST Chemistry Reference | Propanedioic acid, 2-propenyl-, diethyl ester(2049-80-1) |
| EPA Substance Registry System | Propanedioic acid, 2-propenyl-, diethyl ester (2049-80-1) |
| UNSPSC Code | 12162002 |
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H335-H227-H315-H319 | |||||||||
| Precautionary statements | P210-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P370+P378-P403+P235-P501-P210e-P261-P280a-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36-37/39 | |||||||||
| RIDADR | NA 1993 / PGIII | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | TSCA listed | |||||||||
| HS Code | 29171990 | |||||||||
| NFPA 704 |
|
Diethyl allylmalonate price More Price(19)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 446114 | Diethyl allylmalonate 95% | 2049-80-1 | 25ml | $48.2 | 2023-01-07 | Buy |
| TCI Chemical | A0231 | Diethyl Allylmalonate >98.0%(GC) | 2049-80-1 | 25g | $85 | 2025-07-31 | Buy |
| TCI Chemical | A0231 | Diethyl Allylmalonate >98.0%(GC) | 2049-80-1 | 500g | $944 | 2025-07-31 | Buy |
| TRC | D443728 | Diethyl allylmalonate | 2049-80-1 | 1g | $55 | 2021-12-16 | Buy |
| AK Scientific | M279 | Diethyl allylmalonate | 2049-80-1 | 5g | $64 | 2021-12-16 | Buy |
Diethyl allylmalonate Chemical Properties,Uses,Production
Chemical Properties
clear colorless to slightly yellow liquid
Uses
Diethyl allylmalonate is an important intermediates in syntheses of vitamins B1 and B6, barbiturates, non-steroidal anti-inflammatory agents, other numerous pharmaceuticals, agrochemicals and flavors and fragrances compounds.
Preparation
Diethyl allyl malonate is obtained by reacting diethyl malonate with allyl bromide.
Under nitrogen atmosphere, to a 500 mL three-neck round bottom flask was added diethyl malonate (20 g), anhydrous potassium carbonate (43 g) and anhydrous CH3CN (200 mL). The reaction mixture was stirred at room temperature for 10 minutes, then allyl bromide (23 g) was slowly added to the reaction mixture at room temperature. The reaction mixture was heated to 80°C for 24 hours. The reaction mixture was cooled to room temperature and filtered through a bed of celite. The celite bed was washed with acetonitrile (100 mL) and the combined filtrates were concentrated to give diethyl allylmalonate (24 g) as a colorless liquid.
Synthesis Reference(s)
Chemistry Letters, 17, p. 291, 1988
The Journal of Organic Chemistry, 28, p. 504, 1963 DOI: 10.1021/jo01037a058
Diethyl allylmalonate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Yanxi Chemical Co., Ltd. | +8618531123677 | faithe@yan-xi.com | China | 5853 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29839 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49977 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 +8613506123987 | marketing1@neostarunited.com | China | 8830 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Wuxi Rejoys chemical Technology Co., Ltd. | 0510-86103381 | sales@rejoyschem.com | CHINA | 976 | 58 |
View Lastest Price from Diethyl allylmalonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-06-20 | Diethyl allylmalonate
2049-80-1
|
US $0.00-0.00 / kg | 1kg | 99.50% | 100tons | Hebei Yanxi Chemical Co., Ltd. | |
 |
2025-06-20 | Diethyl allylmalonate
2049-80-1
|
US $50.00-30.00 / kg | 1kg | 99% | 10 tons | Hebei Yanxi Chemical Co., Ltd. | |
 |
2025-04-04 | Diethyl allylmalonate
2049-80-1
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. |
-
- Diethyl allylmalonate
2049-80-1
- US $0.00-0.00 / kg
- 99.50%
- Hebei Yanxi Chemical Co., Ltd.
-
- Diethyl allylmalonate
2049-80-1
- US $50.00-30.00 / kg
- 99%
- Hebei Yanxi Chemical Co., Ltd.
-
- Diethyl allylmalonate
2049-80-1
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
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