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Dibenzyl malonate

CAS No.
15014-25-2
Chemical Name:
Dibenzyl malonate
Synonyms
MALONIC ACID DIBENZYL ESTER;C17H16O4;NSC 101027;Dibenzylmalonat;Dibenzyl malonate;Dibenzylmalonateca;DibenzylMalonate>D**DIBENZYL MALONATE;Malonic acid dibenzyl;Dibenzyl propanedioate
CBNumber:
CB6222040
Molecular Formula:
C17H16O4
Molecular Weight:
284.31
MDL Number:
MFCD00004779
MOL File:
15014-25-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:54:04

Dibenzyl malonate Properties

Boiling point 188 °C/0.2 mmHg (lit.)
Density 1.137 g/mL at 25 °C (lit.)
refractive index n20/D 1.546(lit.)
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
pka 11.65±0.46(Predicted)
form clear liquid
Specific Gravity 1.17
color Colorless to Light yellow to Light orange
Water Solubility Sparingly soluble in water; miscible in all proportions with ether and alcohol.
BRN 1998264
InChI InChI=1S/C17H16O4/c18-16(20-12-14-7-3-1-4-8-14)11-17(19)21-13-15-9-5-2-6-10-15/h1-10H,11-13H2
InChIKey RYFCSKVXWRJEOB-UHFFFAOYSA-N
SMILES C(OCC1=CC=CC=C1)(=O)CC(OCC1=CC=CC=C1)=O
CAS DataBase Reference 15014-25-2(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
PPE Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Safety Statements  23-24/25
WGK Germany  3
HS Code  29171910
Storage Class 10 - Combustible liquids
NFPA 704
1
1 0

Dibenzyl malonate price More Price(52)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 160407 Dibenzyl malonate 15014-25-2 10g $84.2 2026-04-30 Buy
Sigma-Aldrich 160407 Dibenzyl malonate 15014-25-2 50g $267 2026-04-30 Buy
TCI Chemical M1080 Dibenzyl Malonate >95.0%(GC) 15014-25-2 25g $62 2026-04-30 Buy
TCI Chemical M1080 Dibenzyl Malonate >95.0%(GC) 15014-25-2 100g $155 2026-04-30 Buy
TRC TRC-D417885-50G Dibenzyl Malonate 15014-25-2 50g $409 2026-06-03 Buy
Product number Packaging Price Buy
160407 10g $84.2 Buy
160407 50g $267 Buy
M1080 25g $62 Buy
M1080 100g $155 Buy
TRC-D417885-50G 50g $409 Buy

Dibenzyl malonate Chemical Properties, Uses, Production

Preparation

DIBENZYL MALONATE can be prepared by esterification of phenylethanol and maleic anhydride in the presence of an acid or base catalyst.

Chemical Properties

CLEAR YELLOWISH LIQUID

Uses

Dibenzyl malonate was used in the preparation of tetraethyl 3,3-bis(benzyloxycarbonyl)propylene bisphosphonate. It was also used in the preparation of benzyl umbelliferone-3-carboxylate via Knoevenagel condensation with 2,4-dihydroxybezaldehyde.

General Description

Direct asymmetric reaction of dibenzyl malonate with N-tert-butoxycarbonyl aldimines in the presence of Yb(OTf)3 and iPr-pybox (pybox = pyridine bisoxazoline) complexes has been investigated.

Purification Methods

Dissolve the ester in toluene, wash it with aqueous NaHCO3, H2O, dry over MgSO4, filter, evaporate and distil it at high vacuum. [Ginsburg & Pappo J Am Chem Soc 75 1094 1953, Baker et al. J Org Chem 17 77 1952, Beilstein 6 IV 2270.]

Dibenzyl malonate Preparation Products And Raw materials

Raw materials

Preparation Products

Dibenzyl malonate Suppliers

Global Suppliers ( 187)
Supplier Tel Email Country ProdList Advantage
Alchemist-pharm chemical Technology Co. Ltd. 0371-67991738 13783628208 carl@alchemist-pharm.com China 43 58
Creasyn Finechem(Tianjin) Co., Ltd. 022-83946278 13820372920 sales@creasyn.com China 968 68
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Syntechem Co.,Ltd info@syntechem.com China 12973 57
Sinopharm Chemical Reagent Co,Ltd. 86-21-63210123 sj_scrc@sinopharm.com China 9791 79
Maya High Purity Chemicals +86 (573) 82222445 (0)18006601000 452520369 sales@maya-r.com China 11693 57

View Latest Price from Dibenzyl malonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Propanedioicacid,bis(phenylmethyl)ester pictures 2026-02-02 Propanedioicacid,bis(phenylmethyl)ester
15014-25-2
10mg 99%HPLC 2000tons Shaanxi Dideu Medichem Co. Ltd
DIBENZYL MALONATE pictures 2025-04-04 DIBENZYL MALONATE
15014-25-2
1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
DIBENZYL MALONATE pictures 2019-09-02 DIBENZYL MALONATE
15014-25-2
$1.00 1KG 98% 200kg Career Henan Chemical Co
Propanedioic acid, bis(phenylmethyl) ester Dibenzyl malonate, tech., 90% propanedioic acid dibenzyl ester MALONIC ACID DIBENZYL ESTER 2,5-Dimethyl-3-Hezine-Diol Dibenzylmalonateca Malonic acid dibenzyl ester~Propanedioic acid dibenzyl ester Propanedioicacid,bis(phenylmethyl Dibenzylmalonat D**DIBENZYL MALONATE Dibenzyl malonate,90%,tech. Propanedioic acid, 1,3-bis(phenylMethyl) ester NSC 101027 Malonic acid dibenzyl DibenzylMalonate> Dibenzyl propanedioate 2-{2,3-Bis[(E)-2-phenylvinyl]phenoxy}ethanol C17H16O4 Dibenzyl malonate 15014-25-2 CH2CO2CH2C6H52 CH2CO2C6H52 Organic Building Blocks Esters Carbonyl Compounds C12 to C63 Building Blocks Building Blocks C12 to C63 Carbonyl Compounds Chemical Synthesis Organic Building Blocks C12 to C63 Carbonyl Compounds Esters