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(-)-P-MENTHA-1,5-DIENE

(-)-P-MENTHA-1,5-DIENE Structure
(-)-P-MENTHA-1,5-DIENE structure
CAS No.
4221-98-1
Chemical Name:
(-)-P-MENTHA-1,5-DIENE
Synonyms
ALPHA-PHELLANDRENE;1-phellandrene;P-MENTHA-1,5-DIENE;(R)-α-Phellandrene;(-)-α-phellandrene;(-)-α-phellandrene;L-ALPHA-PHELLANDRENE;(R)-5-isopropyl-2-methylcyclohexa-1,3-diene;Carylene;65.0%(GC)
CBNumber:
CB6240491
Molecular Formula:
C10H16
Molecular Weight:
136.23
MDL Number:
MFCD00062988
MOL File:
4221-98-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 03:45:30
Product description Number Pack Size Price
(R)-(?)-α-Phellandrene ≥95.0% (sum of enantiomers, GC) 77429 1ml $102
(R)-(?)-α-Phellandrene ≥95.0% (sum of enantiomers, GC) 77429 5ml $158
(-)-α-Phellandrene >65.0%(GC) M0051 5mL $128
(-)-α-Phellandrene >65.0%(GC) M0051 25mL $354
(R)-±-Phellandrene EAA22198 5ml $162.25
More product size
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(-)-P-MENTHA-1,5-DIENE Properties

Boiling point 171-174 °C(lit.)
alpha D20 -217°
Density 0.844 g/mL at 20 °C(lit.)
vapor pressure 2.35hPa at 20℃
refractive index n20/D 1.475
Flash point 49 °C
storage temp. 2-8°C
solubility Benzene (Sparingly), Ethyl Acetate (Slightly)
form clear liquid
color Colorless to Light yellow to Light orange
Odor at 100.00 %. terpene spicy medicinal
Odor Type terpenic
optical activity [α]20/D 225±5°, c = 10% in diethyl ether
Water Solubility 4.37mg/L at 20℃
Merck 14,7200
BRN 2497824
Henry's Law Constant 3.4×10-4 mol/(m3Pa) at 25℃, Schuhfried et al. (2015)
Cosmetics Ingredients Functions PERFUMING
InChI 1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4-6,8,10H,7H2,1-3H3/t10-/m1/s1
InChIKey OGLDWXZKYODSOB-SNVBAGLBSA-N
SMILES CC(C)[C@H]1CC=C(C)C=C1
LogP 5.74 at 21.6℃
CAS DataBase Reference 4221-98-1(CAS DataBase Reference)
FDA UNII 56UV8X65K0
EPA Substance Registry System 1,3-Cyclohexadiene, 2-methyl-5-(1-methylethyl)-, (5R)- (4221-98-1)
UNSPSC Code 12352002
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)
GHS02
Signal word  Warning
Hazard statements  H226
Precautionary statements  P210
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Risk Statements  10
RIDADR  UN 2319 3/PG 3
WGK Germany  3
F  23
TSCA  TSCA listed
HS Code  2902.19.0050
HazardClass  3
PackingGroup  III
Storage Class 3 - Flammable liquids
Hazard Classifications Aquatic Acute 1
Aquatic Chronic 1
Asp. Tox. 1
Flam. Liq. 3
Skin Sens. 1B
REACH Registrations Active
NFPA 704
2
0 0

(-)-P-MENTHA-1,5-DIENE price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 77429 (R)-(?)-α-Phellandrene ≥95.0% (sum of enantiomers, GC) 4221-98-1 1ml $102 2026-04-30 Buy
Sigma-Aldrich 77429 (R)-(?)-α-Phellandrene ≥95.0% (sum of enantiomers, GC) 4221-98-1 5ml $158 2026-04-30 Buy
TCI Chemical M0051 (-)-α-Phellandrene >65.0%(GC) 4221-98-1 5mL $128 2026-04-30 Buy
TCI Chemical M0051 (-)-α-Phellandrene >65.0%(GC) 4221-98-1 25mL $354 2026-04-30 Buy
Biosynth EAA22198 (R)-±-Phellandrene 4221-98-1 5ml $162.25 2026-06-04 Buy
Product number Packaging Price Buy
77429 1ml $102 Buy
77429 5ml $158 Buy
M0051 5mL $128 Buy
M0051 25mL $354 Buy
EAA22198 5ml $162.25 Buy

(-)-P-MENTHA-1,5-DIENE Chemical Properties,Uses,Production

Chemical Properties

()-α-Phellandrene is a colorless liquid with a citrus odor and a slight peppery note. It is isolated, for example, from Eucalyptus dives oil. Pinenes are widespread, naturally occurring terpene hydrocarbons. The α- and β-forms occur in varying ratios in essential oils.

Uses

(R)-(-)-α-Phellandrene undergoes [4+2] cycloaddition with 2-naphthyl acetylenecarboxylate to form a chiral diene, which can act as a ligand for the rhodium-catalyzed asymmetric addition reactions. It may be used to synthesize (1S,5R)-5-(1-methylethyl)-2-methylidene-3-cyclohexen-1-yl hydroperoxide, which on reduction forms trans-yabunikkeol.

Definition

ChEBI: (-)-alpha-phellandrene is the (R)-(-)-stereoisomer of alpha-phellandrene. It is an enantiomer of a (+)-alpha-phellandrene.

General Description

(R)-(-)-α-Phellandrene is a monoterpene derivative.

Flammability and Explosibility

Flammable

Purification Methods

Purify it by gas chromatography on an Apiezon column. Also purify it by steam distillation (with 0.5% hydroquinone), then re-distil it through a 50 plate bubble cap column b 72-72.5o/22mm [Pines & Eschinazi J Am Chem Soc 77 6318 1955]. UV: max 263nm ( 3,345) in octane. [Read & Storey J Chem Soc 2770 1930, Beilstein 5 III 341, 5 IV 436.]

Toxics Screening Level

The screening level is being set at the default of 0.1 μg/m3 with annual averaging.

(-)-P-MENTHA-1,5-DIENE Preparation Products And Raw materials

Raw materials

Preparation Products

(-)-P-MENTHA-1,5-DIENE Suppliers

Global( 122)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaanxi Dideu Medichem Co. Ltd 		+86-29-81139210 17389186172 1077@dideu.com China 3999 58
Hebei Zhuanglai Chemical Trading Co Ltd 		+86-16264648883 niki@zlchemi.com China 7240 58
Shanghai Zheyan Biotech Co., Ltd. 		18017610038 zheyansh@163.com CHINA 3618 58
BOC Sciences 		+1-631-485-4226 inquiry@bocsci.com United States 19935 58
Career Henan Chemica Co 		+86-0371-86658258 +86-13203830695 laboratory@coreychem.com China 30203 58
Finetech Industry Limited 		+86-27-8746-5837 +86-18627785180 info@finetechnology-ind.com China 9539 58
TargetMol Chemicals Inc. 		+1-781-999-5354; support@targetmol.com United States 38999 58
ZHEJIANG JIUZHOU CHEM CO., LTD 		+86-0576225566889 +86-13454675544 admin@jiuzhou-chem.com；jamie@jiuzhou-chem.com；alice@jiuzhou-chem.com China 12270 58
HANGZHOU LEAP CHEM CO., LTD. 		+86-571-87711850 +86-15355479329 market18@leapchem.com China 43303 58
Shanghai Acmec Biochemical Technology Co., Ltd. 		+86-18621343501 product@acmec-e.com China 33301 58
Supplier Advantage
Shaanxi Dideu Medichem Co. Ltd 		58
Hebei Zhuanglai Chemical Trading Co Ltd 		58
Shanghai Zheyan Biotech Co., Ltd. 		58
BOC Sciences 		58
Career Henan Chemica Co 		58
Finetech Industry Limited 		58
TargetMol Chemicals Inc. 		58
ZHEJIANG JIUZHOU CHEM CO., LTD 		58
HANGZHOU LEAP CHEM CO., LTD. 		58
Shanghai Acmec Biochemical Technology Co., Ltd. 		58

View Lastest Price from (-)-P-MENTHA-1,5-DIENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(-)-P-MENTHA-1,5-DIENE pictures 2026-08-07 (-)-P-MENTHA-1,5-DIENE
4221-98-1
 $20.00-80.00 1KG 99% 52000KG Shaanxi Dideu Medichem Co. Ltd
(-)-P-MENTHA-1,5-DIENE pictures 2025-05-23 (-)-P-MENTHA-1,5-DIENE
4221-98-1
 $50.00 1kg 99 5000 Hebei Zhuanglai Chemical Trading Co Ltd

4221-98-1((-)-P-MENTHA-1,5-DIENE)Related Search:

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L-P-MENTHA-1,8-DIENE,(s)-(-)-p-mentha-1,8-dien METHYL CYCLOHEXADIENE 1,3-CYCLOHEXADIENE ALPHA-PHELLANDRENE (-)-P-MENTHA-1,5-DIENE
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1,3-Cyclohexadiene, 2-methyl-5-(1-methylethyl)-, (5R)- (5R)-2-methyl-5-propan-2-ylcyclohexa-1,3-diene R-(-)-A-PHELLANDRENE WITH GC (R)-2-methyl-5-(1-methylethyl)-1,3-cyclohexadiene (-)-p-Mentha-1,5-diene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene PETUNIDIN CHLORIDE(SH) (R)-()-α-Phellandrene,()-p-Mentha-1,5-diene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene (-)-5-Isopropyl-2-methyl-1,3-cyclohexadiene (-)-p-Mentha-1,5-diene (R)-(-)-alpha-Phellandrene >=95.0% (sum of enantiomers, GC) 1,3-cyclohexadiene,2-methyl-5-(1-methylethyl)-,(R)- 2-methyl-5-(1-methylethyl)-3-cyclohexadien(theta)- 3-Cyclohexadiene,2-methyl-5-(1-methylethyl)-,(R)-1 p-mentha-1,5-diene,(R)-(-)- α-phellandrene,(-)- ALPHA-PHELLANDRENE (-)-2-METHYL-5-ISOPROPYL-1,3-CYCLOHEXADIENE R(-)-ALPHA-PHELLANDRENE (R)-5-ISOPROPYL-2-METHYL-1,3-CYCLOHEXADIENE (-)-P-MENTHA-1,5-DIENE PHELLANDRENE, R-(-)-ALPHA- 65.0%(GC) (-)-α-Phellandrene> (-)-alpha-Phellandrene (R)-α-Phellandrene Carylene (-)-5-Isopropyl-2-Methyl-1,3-Cyclohexadiene )-p-Mentha-1,5-diene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene PHELLANDRENE, R- (R)-(?)-α-Phellandrene (R)-±-Phellandrene (-)-P-MENTHA-1,5-DIENE (-)-α-phellandrene (-)-α-phellandrene (R)-5-isopropyl-2-methylcyclohexa-1,3-diene 1-phellandrene L-ALPHA-PHELLANDRENE P-MENTHA-1,5-DIENE (R)-a-Phellandrene (Technical Grade) 4221-98-1 221-98-1 Terpenes Monocyclic Monoterpenes Organic Building Blocks Chiral Building Blocks Asymmetric Synthesis Alkenes Biochemistry Monocyclic Monoterpenes Terpenes