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Ethyl 5-bromothiophene-3-carboxylate

CAS No.
170355-38-1
Chemical Name:
Ethyl 5-bromothiophene-3-carboxylate
Synonyms
Ethyl 5-bromothiophen-3-carboxylate;Ethyl 5-bromothiophene-4-carboxylate;Ethyl 5-bromothiophene-3-carboxylate;Ethyl 5-bromothiophene-3-carboxylate 97+%;5-bromo-3-Thiophenecarboxylic acid ethyl...;PI-35048 ethyl 5-bromothiophene-3-carboxylate;5-bromo-3-Thiophenecarboxylic acid ethyl ester;5-BroMo-thiophene-3-carboxylic acid ethyl ester;3-Thiophenecarboxylic acid, 5-bromo-, ethyl ester;5-Bromothiophene-3-carboxylic acid ethyl ester, >=98%
CBNumber:
CB62514598
Molecular Formula:
C7H7BrO2S
Molecular Weight:
235.1
MDL Number:
MFCD14155650
MOL File:
170355-38-1.mol
MSDS File:
SDS
Last updated:2026-05-29 18:28:35

Ethyl 5-bromothiophene-3-carboxylate Properties

Boiling point 65-66 °C
Density 1.572±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form liquid
color Colourless to yellow
InChI InChI=1S/C7H7BrO2S/c1-2-10-7(9)5-3-6(8)11-4-5/h3-4H,2H2,1H3
InChIKey LUYMKCLOYODOEI-UHFFFAOYSA-N
SMILES C1SC(Br)=CC=1C(OCC)=O

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319
Precautionary statements  P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330
HS Code  2934999090

Ethyl 5-bromothiophene-3-carboxylate price More Price(42)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR46588 Ethyl 5-bromothiophene-3-carboxylate 97% 170355-38-1 1g $21 2026-06-04 Buy
Apolloscientific OR46588 Ethyl 5-bromothiophene-3-carboxylate 97% 170355-38-1 5g $77 2026-06-04 Buy
Apolloscientific OR46588 Ethyl 5-bromothiophene-3-carboxylate 97% 170355-38-1 10g $147 2026-06-04 Buy
Matrix Scientific 119493 Ethyl 5-bromothiophene-3-carboxylate 170355-38-1 1.00g $145 2026-05-18 Buy
Matrix Scientific 119493 Ethyl 5-bromothiophene-3-carboxylate 170355-38-1 5.00g $438 2026-05-18 Buy
Product number Packaging Price Buy
OR46588 1g $21 Buy
OR46588 5g $77 Buy
OR46588 10g $147 Buy
119493 1.00g $145 Buy
119493 5.00g $438 Buy

Ethyl 5-bromothiophene-3-carboxylate Chemical Properties, Uses, Production

Synthesis

20 g (147 mmol) of aluminum chloride are added portion-wise to a solution of 10 g (67 mmol) of ethyl thiophene-3-carboxylate in 160 ml of dichloro-methane, cooled to 0oC. The reaction medium is warmed to room temperature, and a solution of 4 ml (73 mmol) of bromine in 10 ml of dichloromethane is added. After reaction for 50 minutes at room temperature, the reaction medium is poured into a water + ice mixture and extracted with dichloromethane. The organic phase is dried over magnesium sulfate, filtered, and evaporated under vacuum. The residue obtained is purified by chromatography on a column of silica eluted with a 9/1 HEPTANE/ETHYL acetate mixture. 9 g (57percent) of ethyl 5-bromothiophene-3-carboxylate are obtained.

Uses

Ethyl 5-bromothiophene-3-carboxylate is an important organic reagent that can be used as a building block for the synthesis of many organic compounds. After hydrolysis, it can synthesize 5-Bromothiophene-3-carboxylic acid.

References

[1] Patent: WO2004/113331, 2004, A1. Location in patent: Page 39
[2] Patent: WO2007/145921, 2007, A1. Location in patent: Page/Page column 83-84

Ethyl 5-bromothiophene-3-carboxylate Preparation Products And Raw materials

Ethyl 5-bromothiophene-3-carboxylate Suppliers

Global Suppliers ( 98)
Supplier Tel Email Country ProdList Advantage
Shaanxi Dideu Medichem Co. Ltd 029-81024372 17792795018 1053@dideu.com China 9999 58
Shanghai Sinch Parmaceuticals Tech. Co. Ltd. +86-21-54098501 sales@sinch.com.cn China 11592 64
Nanjing Chemlin Chemical Co., Ltd 025-83697070 13770331960 info@chemlin.com.cn China 16306 64
SpringPharma Tech Co.,Ltd +86-25-68710855, +86-25-68710897 sales@springpharma.net China 1260 62
Shanghai Topbiochem Technology Co., Ltd +86-21-60341587 sales@topbiochem.com China 6166 58
Nanjing Norris-Pharm Technology Co., Ltd 13901585132 sales@norris-pharm.com China 8869 55
AstaTech (Chengdu) Pharma. Co., Ltd. 15928766785 15928766785 wupengcheng@astatech.cn China 1998 55
Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd. +86-28-85122536 85324413 market@astatech.cn China 8016 55
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Finetech Industry Limited 027-87465837 19945049750 sales@finetechnology-ind.com China 9331 58

View Latest Price from Ethyl 5-bromothiophene-3-carboxylate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ethyl 5-bromothiophene-3-carboxylate pictures 2026-06-30 Ethyl 5-bromothiophene-3-carboxylate
170355-38-1
1KG 99.0% 10000KGS Shaanxi Dideu New Materials Co. Ltd
Ethyl 5-bromothiophene-3-carboxylate pictures 2026-05-29 Ethyl 5-bromothiophene-3-carboxylate
170355-38-1
$1.50 1g 99.0% Min 100 Tons Shaanxi Didu New Materials Co. Ltd
Ethyl5-bromothiophene-3-carboxylate pictures 2025-09-24 Ethyl5-bromothiophene-3-carboxylate
170355-38-1
$1.10 1g 99.0% min 100 tons min Shaanxi Dideu Medichem Co. Ltd
Ethyl 5-bromothiophene-3-carboxylate 5-BroMo-thiophene-3-carboxylic acid ethyl ester 5-Bromothiophene-3-carboxylic acid ethyl ester, >=98% 5-bromo-3-Thiophenecarboxylic acid ethyl ester PI-35048 ethyl 5-bromothiophene-3-carboxylate Ethyl 5-bromothiophene-3-carboxylate 97+% 3-Thiophenecarboxylic acid, 5-bromo-, ethyl ester Ethyl 5-bromothiophene-4-carboxylate 5-bromo-3-Thiophenecarboxylic acid ethyl... 3-Thiophenecarboxylic acid, 5-bromo-, ethyl ester (9CI, ACI) 5-bromo-3-Thiophenecarboxylic acid ethyl ester (9CI ACI) Ethyl 5-bromothiophen-3-carboxylate 170355-38-1