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2-Bromo-6-chlorobenzyl bromide

CAS No.
75002-98-1
Chemical Name:
2-Bromo-6-chlorobenzyl bromide
Synonyms
-3-chlorobenzene;1-Bromo-2-(bromomethyl);2-bromo-6-chlorobromobenzyl;2-Bromo-6-chlorobenzyl bromide;2-Bromo-6-chlorobenzyl bromide 97%;1-BroMo-2-(broMoMethyl)-3-chlorobenzene;Benzene, 1-bromo-2-(bromomethyl)-3-chloro-;1-Bromo-2-(bromomethyl)-3-chlorobenzene, 2-Chloro-alpha,6-dibromotoluene
CBNumber:
CB6259907
Molecular Formula:
C7H5Br2Cl
Molecular Weight:
284.38
MDL Number:
MFCD04038394
MOL File:
Mol file
MSDS File:
SDS
Last updated:2026-09-12 18:54:08

2-Bromo-6-chlorobenzyl bromide Properties

Melting point 62-64°C
Boiling point 283.4±25.0 °C(Predicted)
Density 1.93g/ml
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
Appearance Light brown to off-white Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280
RIDADR  UN1759
HazardClass  8
HS Code  2903998090
Limited Quantities 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

2-Bromo-6-chlorobenzyl bromide price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Biosynth ADA00298 1-Bromo-2-(bromomethyl)-3-chlorobenzene 75002-98-1 5g $312.5 2026-06-04 Buy
Biosynth ADA00298 1-Bromo-2-(bromomethyl)-3-chlorobenzene 75002-98-1 50g $1250 2026-06-04 Buy
Apolloscientific OR40565 2-Bromo-6-chlorobenzyl bromide 98% 75002-98-1 250mg $21 2026-06-04 Buy
Apolloscientific OR40565 2-Bromo-6-chlorobenzyl bromide 98% 75002-98-1 1g $36 2026-06-04 Buy
Apolloscientific OR40565 2-Bromo-6-chlorobenzyl bromide 98% 75002-98-1 5g $113 2026-06-04 Buy
Product number Packaging Price Buy
ADA00298 5g $312.5 Buy
ADA00298 50g $1250 Buy
OR40565 250mg $21 Buy
OR40565 1g $36 Buy
OR40565 5g $113 Buy

2-Bromo-6-chlorobenzyl bromide Chemical Properties, Uses, Production

Synthesis

2-Bromo-6-chlorotoluene

62356-27-8

2-BROMO-6-CHLOROBENZYL BROMIDE

75002-98-1

General procedure for the synthesis of 2-bromo-6-chlorobenzyl bromide (compound [5-2]) from 2-bromo-6-chlorotoluene: 2-bromo-6-chlorotoluene (1.58 g) was dissolved in 15 mL of carbon tetrachloride, and N-bromosuccinimide (1.63 g) and 2,2'-azino-bis (isobutyronitrile) (125 mg) were added. The reaction mixture was heated to reflux for 24 hours. After completion of the reaction, the reaction was quenched with water and the mixture was extracted with chloroform. The organic layers were combined, dried over anhydrous sodium sulfate, filtered and the filtrate concentrated under reduced pressure. The resulting residue was purified by silica gel column chromatography to afford 2-bromo-6-chlorobenzyl bromide (2.16 g) as a white solid.1H-NMR (400 MHz, CDCl3) δ: 7.51 (1H, d, J = 8.1 Hz), 7.37 (1H, d, J = 8.1 Hz), 7.11 (1H, d, J = 8.1 Hz), 4.80 (2H, s) .

References

[1] Organic and Biomolecular Chemistry, 2012, vol. 10, # 31, p. 6404 - 6409
[2] Journal of Medicinal Chemistry, 1981, vol. 24, # 4, p. 382 - 389
[3] Patent: US4259349, 1981, A
[4] Journal of the American Chemical Society, 2008, vol. 130, # 45, p. 15157 - 15166
[5] Journal of the American Chemical Society, 2011, vol. 133, # 24, p. 9282 - 9285

2-Bromo-6-chlorobenzyl bromide Preparation Products And Raw materials

Global Suppliers ( 88)
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J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
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2-Bromo-6-chlorobenzyl bromide Spectrum

2-Bromo-6-chlorobenzyl bromide 97% 1-BroMo-2-(broMoMethyl)-3-chlorobenzene 1-Bromo-2-(bromomethyl)-3-chlorobenzene, 2-Chloro-alpha,6-dibromotoluene 1-Bromo-2-(bromomethyl) Benzene, 1-bromo-2-(bromomethyl)-3-chloro- 2-bromo-6-chlorobromobenzyl -3-chlorobenzene 2-Bromo-6-chlorobenzyl bromide 75002-98-1 C7H5Br2Cl