1-Hexyne
- CAS No.
- 693-02-7
- Chemical Name:
- 1-Hexyne
- Synonyms
- Hex-1-yne;Hexyne;1-Hexine;Butylacetylene;1-Hexin;1-HEXYNE;5-Hexyne;HEXYNE(1-);1-Hexyne98%;1-Hexyne>
- CBNumber:
- CB6746670
- Molecular Formula:
- C6H10
- Molecular Weight:
- 82.14
- MDL Number:
- MFCD00009504
- MOL File:
- 693-02-7.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | -132 °C |
|---|---|
| Boiling point | 71-72 °C(lit.) |
| Density | 0.715 g/mL at 25 °C(lit.) |
| vapor pressure | 253 mm Hg ( 37.7 °C) |
| refractive index |
n |
| Flash point | −6 °F |
| storage temp. | Store at +2°C to +8°C. |
| solubility | 0.36g/l (experimental) |
| form | Liquid |
| Specific Gravity | 0.715 |
| color | Clear colorless |
| Water Solubility | Miscible with organic solvents. Immiscible with water. |
| BRN | 635687 |
| Henry's Law Constant | 2.6×10-4 mol/(m3Pa) at 25℃, Brockbank (2013) |
| Stability | Stable. Incompatible with strong oxidizing agents. Highly flammable - readily forms explosive mixtures with air. |
| InChI | 1S/C6H10/c1-3-5-6-4-2/h1H,4-6H2,2H3 |
| InChIKey | CGHIBGNXEGJPQZ-UHFFFAOYSA-N |
| SMILES | CCCCC#C |
| CAS DataBase Reference | 693-02-7(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | 5FZF2F38F5 |
| NIST Chemistry Reference | 1-Hexyne(693-02-7) |
| EPA Substance Registry System | 1-Hexyne (693-02-7) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H315-H319-H304-H225 | |||||||||
| Precautionary statements | P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P331-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P301+P310-P403+P235-P405 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | F,Xn,Xi | |||||||||
| Risk Statements | 11-36/37/38-65 | |||||||||
| Safety Statements | 16-26-36-62-9-33-7/9 | |||||||||
| RIDADR | UN 3295 3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | MQ9691000 | |||||||||
| F | 10-23 | |||||||||
| Autoignition Temperature | 263 °C | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29012980 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Asp. Tox. 1 Eye Irrit. 2 Flam. Liq. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| Limited Quantities | 1.0 L (0.3 gallon) (liquid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
1-Hexyne price More Price(46)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 8.20643 | 1-Hexyne for synthesis | 693-02-7 | 25mL | $64.1 | 2026-04-30 | Buy |
| Sigma-Aldrich | 8.20643 | 1-Hexyne for synthesis | 693-02-7 | 100mL | $194 | 2026-04-30 | Buy |
| Sigma-Aldrich | 244422 | 1-Hexyne 97% | 693-02-7 | 25ml | $55.9 | 2026-04-30 | Buy |
| Sigma-Aldrich | 244422 | 1-Hexyne 97% | 693-02-7 | 100ml | $168 | 2026-04-30 | Buy |
| TCI Chemical | H0140 | 1-Hexyne >97.0%(GC) | 693-02-7 | 25mL | $35 | 2026-04-30 | Buy |
1-Hexyne Chemical Properties, Uses, Production
Chemical Properties
colourless liquid
Uses
1-Hexyne is used in the preparation of tricyclic isoindolinone scaffold by undergoing hydrozirconation and ring-closing metathesis. It is used to prepare trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate by reacting with thianthrene cation radical tetrafluoroborate.
Definition
ChEBI: 1-hexyne is a terminal acetylenic compound that is hexane carrying a triple bond at position 1. It is a terminal acetylenic compound, an alkyne and a volatile organic compound.
General Description
1-Hexyne reacted with thianthrene cation radical tetrafluoroborate to form trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate.
Hazard
Probably flammable.
Purification Methods
Distil it from NaBH4 to remove peroxides. Stand over sodium for 24hours, then fractionally distil it under reduced pressure. Also dry it by repeated vacuum transfer into freshly activated 4A molecular sieves, followed by vacuum transfer onto Na/K alloy and stirring for 1hour before fractionally distilling. [Beilstein 1 IV 1006.]
1-Hexyne Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| China DongFan Chemical Co.,LTD | 86-0571-85151182 | China | 5681 | 66 | |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11674 | 57 |
View Latest Price from 1-Hexyne manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2021-07-02 | 1-Hexyne 97%
693-02-7
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
 |
2020-01-08 | 1-Hexyne
693-02-7
|
$1.00 | 1KG | 98%HPLC | 10 tons/month | Career Henan Chemical Co |
-
- 1-Hexyne 97%
693-02-7
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- 1-Hexyne
693-02-7
- $1.00
- 98%HPLC
- Career Henan Chemical Co
